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Journals / Gazi Üniversitesi Fen Bilimleri Dergisi Part C: Tasarım ve Teknoloji / 2026 / Cilt: 3 Sayı: 2

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BİYODİZELİN YAN ÜRÜNÜ GLİSERİNİN DEĞERLENDİRİLMESİ İÇİN MALZEME TASARIMI

Nebahat Değirmenbaşı
Nezahat Boz
Pages
477–482
Publication Date
2015-02-10
DOI
—
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AI Summary & Key Takeaways

AI Insight
⚡ TL;DR(Too Long; Didn't Read)

Purity and chemical structure of obtained glycerol carbonate was confirmed by using 1H-NMR spectrometry

📌 3 Key Takeaways

🎯
Objective & Hypothesis:In this study, transesterification of glycerol which is the byproduct of biodiesel with dimethyl carbonate (DMC) to glycerol carbonate was investigated.
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Key Findings & Data:Solid basic catalyst which is 35% KOH loaded to alumina was synthesized using the impregnation method.
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Conclusion & Impact:Purity and chemical structure of obtained glycerol carbonate was confirmed by using 1H-NMR spectrometry
🔬Design:Makale
📍Scope:Comprehensive Sample
⚙️Variables:Alümina · transesterleşme · gliserin ve gliserin karbonat

Abstract

In this study, transesterification of glycerol which is the byproduct of biodiesel with dimethyl carbonate (DMC) to glycerol carbonate was investigated. Solid basic catalyst which is 35% KOH loaded to alumina was synthesized using the impregnation method. The effects of DMC/glycerol ratio and temperature (55-85°C) on glycerol carbonate yield were studied. The highest yield of glycerol carbonate of 92% was obtained by 3 h of reaction time at 85°C with a DMC/glycerol molar ratio of 2, and using 3 wt.% catalyst. Purity and chemical structure of obtained glycerol carbonate was confirmed by using 1H-NMR spectrometry

Özet

Bu çalışmada reaksiyon girdisi olarak biyodizel yan ürünü gliserinin dimetil karbonat (DMC) ile transesterleşme reaksiyonu sonunda gliserin karbonata dönüşümü araştırıldı. %35 KOH içeren alümina destekli katı bazik katalizör emdirme yöntemi kullanılarak sentezlendi. Reaksiyonda DMC/gliserin oranı ve sıcaklığın (55-85°C) gliserin karbonat verimine etkileri çalışıldı. DMC/gliserin oranının 2/1, sıcaklığın 85°C olduğu, %3 katalizör miktarı ve 3 saat sonunda %92 gliserin karbonat verimi elde edildi. Elde edilen gliserin karbonatın saflığı ve kimyasal yapısı 1 H-NMR spektrometresi ile doğrulandı.

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Cite This Article

Değirmenbaşı, N., Boz, N. (2015). -. Gazi Üniversitesi Fen Bilimleri Dergisi Part C: Tasarım ve Teknoloji, Cilt: 3 Sayı: 2, 477–482. https://ajindex.com/articles/1399705

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References (20)

  1. Rokicki, G., Rakoczy, P., Parzuchowski, P. ve Sobiecki M., “Hyperbranched aliphatic polyethers obtained from environmentally benign monomer: glycerol carbonate”, Green Chemistry, Cilt 7, 529-539, 2005.
  2. Naik, P.U., Laetitia, P., Karima, R., Michel, P. ve Laurent P., “Imidazolium-2-Carboxylate as an Efficient, Expeditious and Eco-Friendly Organocatalyst for Glycerol Carbonate Synthesis”, Advanced Synthesis and Catalysis, Cilt 35, 1753-1756, 2009.
  3. Kim, S.C., Kim, Y.H., Lee, H., Yoon, D.Y. ve Song, B.K., “Lipase-catalyzed synthesis of glycerol carbonate from renewable glycerol and dimethyl carbonate through transesterification”, Journal of Molecular Catalysis B: Enzymatic, Cilt 49, 75-78, 2007.
  4. Ilham, Z. ve Saka, S., “Production of biodiesel with glycerol carbonate by noncatalytic supercritical dimethyl carbonate”, Lipid Technology, Cilt 23, 10-13, 2011.
  5. Ochoa-Gómez, J.R., Gómez-Jiménez-Aberasturi, O., Maestro-Madurga, B., Pesquera-Rodríguez, A., Ramírez-López, C., Lorenzo-Ibarreta, L., Torrecilla-Soria, J. ve Villarán-Velasco, M.C., “Synthesis of glycerol carbonate from glycerol and dimethyl carbonate by transesterification: Catalyst screening and reaction optimization”, Applied Catalysis A: General, Cilt 366, 315-324, 2009.
  6. Gamcharussrivichai, C., Nunthasanti, P., Tanachai, S. ve Bunyakiat, K. “Biodiesel production through transesterification over natural calciums”, Fuel Processing Technology, Cilt 91, 1409-1415, 2010.
  7. Bai, R., Wang, S., Mei, F., Li, T. ve Li, G., “Synthesis of glycerol carbonate from glycerol and dimethyl carbonate catalyzed by KF modified Hydroxyapatite”, Journal of Industrial and Engineering Chemistry, Cilt 17, 777-781, 2011.
  8. Takagaki, A., Iwatani, K., Nishimura, S. ve Ebitani, K., “Synthesis of glycerol carbonate from glycerol and dialkyl carbonates using hydrotalcite as a reusable heterogeneous base catalyst”, Green Chemistry, Cilt 12, 578-581, 2010.
  9. Alvarez, M.G., Pliskova, M., Segarra, A.M., Medina, F. ve Figueras, F., “Synthesis of glycerol carbonate by transesterification of glycerol in a continuous system using supported hydrotalcites as catalysts”, Applied Catalysis B: Environmental, Cilt 113-114, 212-220, 2012.
  10. Saiyong, P., Liping, Z., Renfeng, N., Shuixin, X.I.A, Ping, C. ve Zhaoyin, H., “Transesterification of glycerol with dimethyl carbonate to glycerol carbonate over Na-based zeolites”, Chinese Journal of Catalysis, Cilt 33, 1772-1777, 2012.
  11. Algoufi, Y.T. ve Hameed, B.H., “Synthesis of glycerol carbonate by transesterification of glycerol with dimethyl carbonate over K-zeolite derived from coal fly ash”, Fuel Processing Technology, Cilt 126, 5, 2014.
  12. Du, M., Li, Q., Dong, W., Geng, T. ve Jiang, Y., “Synthesis of glycerol carbonate from glycerol and dimethyl carbonate catalyzed by K2CO3/MgO”, Research on Chemical Intermediates, Cilt 38, 1069-1077, 2012.
  13. Simanjuntak, F.S.H., Widyaya, V.T., Kim, C.S., Ahn, B.S, Kim, Y.J. ve Lee, H., “Synthesis of glycerol carbonate from glycerol and dimethyl carbonate using magnesium-lanthanum mixed oxide catalyst”, Chemical Engineering Science, Cilt 94, 265-270, 2013.
  14. Degirmenbasi, N. ve Ozgun, B., “Quinaldinium chlorochromate supparted on alumina: A new and efficient reagent fro the oxidation of alcohols”, Monatshefte Fur Chemie, Cilt 134, 1565-1569, 2003.
  15. Liu, Z., Wang, J., Kang, M., Yin, N., Wang, X., Tan, Y. and Zhu, Y., “Synthesis of glycerol carbonate by transesterification of glycerol and dimethyl carbonate over KF/γ-Al2O3 catalyst”, Journal of the Brazilian Chemical Society, Cilt 25, 152-160, 2014.
  16. Bai, R., Wang, Y., Wang, S., Mei, F., Li, T. ve Li, G., Synthesis of glycerol carbonate from glycerol and dimethyl carbonate catalyzed by NaOH/γ-Al2O3, Fuel Processing Technology, Cilt 106, 209-214, 2013.
  17. Boz, N. ve Sunal, O., “Kanola Yağından Çinko Oksit-destekli Katalizör Varlığında Biyodizel Üretimi”, Journal of the Faculty of Engineering & Architecture of Gazi University, Cilt 24, No 3, 389-395, 2009.
  18. Degirmenbasi, N., Boz, N. ve Kalyon, D.M., “Biofuel Production via Transesterification using Sepiolite-supported Alkaline Catalysts, Applied Catalysis B: Environmental, Cilt 150, 147-156, 2014.
  19. Xie, W. ve Li, H., “Alumina-supported potassium iodide as a heterogeneous catalyst for biodiesel production from soybean oil”, Journal of Molecular Catalysis A: Chemical, Cilt 255, 1-9, 2006.
  20. Condon, J.B., “Surface Area and Porosity Determinations by Physisorption: Measurements and Theory”, Elsevier, Amsterdam, 59, 2006.