Journals / Gazi University Journal of Science Part A: Engineering and Innovation / 2026 / Volume: 8 Issue: 1

The Dependence of The Nickel Concentration of ZnO Thin Films for Gas Sensors Applications

İrmak Karaduman Er(Çankırı Karatekin Üniversitesi)0000-0003-3786-3865
Aytunç Ateş(ANKARA YILDIRIM BEYAZIT UNIVERSITY)0000-0002-5802-9207
Pages
—
Publication Date
2021-03-29
DOI
—
🏛️Bibliographic metadata and full text access for this article are provided via DergiPark.
DergiPark Record ↗
✨

AI Summary & Key Takeaways

AI Insight
⚡ TL;DR(Too Long; Didn't Read)

It was concluded that the Ni dopant enhanced the properties of ZnO films for gas sensor applications by changing the microstructure, morphology, and bandgap of ZnO material.

📌 3 Key Takeaways

🎯
Objective & Hypothesis:Undoped ZnO and Ni-doped ZnO thin films were synthesized on glass substrate using the SILAR method.
📊
Key Findings & Data:The aim of this work is the analysis of NO gases using Zn1-xNixO sensors concentrations in the range from 100 ppb to 25 ppm.
💡
Conclusion & Impact:It was concluded that the Ni dopant enhanced the properties of ZnO films for gas sensor applications by changing the microstructure, morphology, and bandgap of ZnO material.
🔬Design:Research Article
📍Scope:Comprehensive Sample
⚙️Variables:Gas Sensor · ZnO · Low Temperature Range

Abstract

Undoped ZnO and Ni-doped ZnO thin films were synthesized on glass substrate using the SILAR method. The aim of this work is the analysis of NO gases using Zn1-xNixO sensors concentrations in the range from 100 ppb to 25 ppm. The gas sensing properties of the films for low NO gas concentrations were carefully investigated within a temperature range from 35 to 135ºC. The gas measurement results revealed that the doping process was strongly affected by the response of Ni-doped ZnO thin films. The Zn0.75Ni0.25O sensor exhibited higher sensitivity, faster response, and recovery times for NO gas at low (100 ppb) concentration. It was concluded that the Ni dopant enhanced the properties of ZnO films for gas sensor applications by changing the microstructure, morphology, and bandgap of ZnO material.

🔖

Cite This Article

Soltabayev, B., Er, İ. K., Yıldırım, M. A., Ateş, A., Acar, S. (2021). The Dependence of The Nickel Concentration of ZnO Thin Films for Gas Sensors Applications. Gazi University Journal of Science Part A: Engineering and Innovation, Volume: 8 Issue: 1. https://ajindex.com/articles/1398650

📄 Full Text PDF Viewer

📄

PDF görüntüleyici hazırlanıyor...

References (24)

  1. Akaltun, Y., & Çayır, T. (2015). Fabrication and characterization of NiO thin films prepared by SILAR method. Journal of Alloys and Compounds, 625, 144-148. doi:10.1016/j.jallcom.2014.10.194
  2. Chen, Z., Lin, Z., Xu, M., Hong, Y., Li, N., Fu, P., & Chen, Z., (2016). Effect of gas sensing properties by Sn-Rh codoped ZnO nanosheets. Electronic Materials Letters, 12(3), 343-349. doi:10.1007/s13391-016-6053-x
  3. Cheng, C., Xu, G., Zhang, H., & Luo, Y. (2008). Hydrothermal synthesis Ni-doped ZnO nanorods with room-temperature ferromagnetism. Materials Letters, 62(10-11), 1617-1620. doi:10.1016/j.matlet.2007.09.035
  4. Çorlu, T., Karaduman, I., Yıldırım, M. A., Ateş, A., & Acar, S. (2017). Effect of Doping Materials on the Low-Level NO Gas Sensing Properties of ZnO Thin Films. Journal of Electronic Materials, 46(7), 3995-4002. doi:10.1007/s11664-017-5503-z
  5. Çorlu, T., Karaduman, I., Galioglu, S., Akata, B., Yıldırım, M. A., Ates, A., & Acar, S. (2018). Low level NO gas sensing properties of Cu doped ZnO thin films prepared by SILAR method. Materials Letters, 212, 292-295. doi:10.1016/j.matlet.2017.10.121
  6. Ganesh Sankar, R., Durgadevi, E., Navaneethan, M., Patil, V. L., Ponnusamy, S., Muthamizhchelvan, C., Kawasaki, S., Patil, P. S., & Hayakawa, Y. (2017). Controlled synthesis of Ni-doped ZnO hexagonal microdiscs and their gas sensing properties at low temperature. Chemical Physics Letters, 689, 92-99. doi:10.1016/j.cplett.2017.09.057
  7. Gao, H., Wei, D., Lin, P., Liu, C., Sun, P., Shimanoe, K., Yamazoe, N., & Lu, G. (2017). The design of excellent xylene gas sensor using Sn-doped NiO hierarchical nanostructure. Sensors and Actuators B: Chemical, 253, 1152-1162. doi:10.1016/j.snb.2017.06.177. doi:10.1016/j.snb.2017.06.177
  8. Gu, C., Guan, W., Liu, X., Gao, L., Wang, L., Shim J-J., & Huang J., (2017). Controlled synthesis of porous Ni-doped SnO2 microstructures and their enhanced gas sensing properties. Journal of Alloys and Compounds, 692, 855-864. doi:10.1016/j.jallcom.2016.09.103
  9. Karaduman, I., Çorlu, T., Yıldırım, M. A., Ateş, A., & Acar, S. (2017). Hydrogen Gas Sensing Characteristics of Nanostructured NiO Thin Films Synthesized by SILAR Method. Journal of Electronic Materials, 46(7), 4017-4023. doi:10.1007/s11664-017-5400-5
  10. Karaduman Er, I. (2021). Development of ZnO sensors via succession ionic layer adsorption and reaction (SILAR) method for ppb level NO gas sensing. Research on Engineering Structures & Materials. doi:10.17515/resm2020.212ma0901
  11. Keskenler, E. F., Doğan, S., Turgut, G., & Gürbulak, B., (2012). Evaluation of Structural and Optical Properties of Mn-Doped ZnO Thin Films Synthesized by Sol-Gel Technique. Metallurgical and Materials Transactions A, 43(13), 5088-5095. doi:10.1007/s11661-012-1365-4
  12. Kumar Rana, A., Bankar, P., Kumar, Y., More, M. A., Late, D. J., & Shirage, P. M. (2016). Synthesis of Ni doped ZnO nanostructures by low temperature wet chemical method and their enhanced field emission properties. RSC Advances, 6(106), 104318-104324. doi:10.1039/C6RA21190A
  13. Moon, H. G., Jang, H. W., Kim, J-S., Park, H.-H., & Yoon S-J. (2010). Size effects in the CO sensing properties of nanostructured TiO2 thin films fabricated by colloidal templating. Electronic Materials Letters, 6(1), 31-34. doi:10.3365/eml.2010.03.031
  14. Lin, Z., Li, N., Chen, Z., & Fu, P. (2017). The effect of Ni doping concentration on the gas sensing properties of Ni doped SnO2. Sensors and Actuators B: Chemical, 239, 501-510. doi:10.1016/j.snb.2016.08.053
  15. Nwanya, A. C., Deshmukh, P. R., Osuji, R. U., Maaza, M., Lokhande, C. D., & Ezema F. I. (2015). Synthesis, characterization and gas-sensing properties of SILAR deposited ZnO-CdO nano-composite thin film. Sensors and Actuators B: Chemical, 206, 671-678. doi:10.1016/j.snb.2014.09.111
  16. Rambu, A. P., Ursu, L., Iftimie, N., Nica, V., Dobromir, M., & Iacomi, F. (2013). Study on Ni-doped ZnO films as gas sensors. Applied Surface Science, 280, 598-604. doi:10.1016/j.apsusc.2013.05.033
  17. Salunkhe, R. R., & Lokhande, C. D. (2008). Effect of film thickness on liquefied petroleum gas (LPG) sensing properties of SILAR deposited CdO thin films. Sensors and Actuators B: Chemical, 129(1), 345-351. doi:10.1016/j.snb.2007.08.035
  18. Shen, J., Guo, S., Chen, C., Sun, L., Wen, S., Chen, Y., & Ruan, S. (2017). Synthesis of Ni-doped α-MoO3 nanolamella and their improved gas sensing properties. Sensors and Actuators B: Chemical, 252, 757-763. doi:10.1016/j.snb.2017.06.040
  19. Sun, G-J., Kyung Lee, J., Lee, W. I., Prakash Dwivedi, R., Lee, C., & Ko, T. (2017). Ethanol sensing properties and dominant sensing mechanism of NiO-decorated SnO2 nanorod sensors. Electronic Materials Letters, 13(3), 260-269. doi:10.1007/s13391-017-1719-6
  20. Wang, B., Yuan, Y., Wang, C., Huang, J., Li, X., Zhang, H., Xia, F., & Xiao, J. (2017). Effects of Ni addition on the response of La2CuO4 sensing electrode for NO sensor. Sensors and Actuators B: Chemical, 252, 37-43. doi:10.1016/j.snb.2017.05.123
  21. Wang, L., Zhou, T., Zhang, R., Lou, Z., Deng, J., & Zhang T., (2016). Comparison of toluene sensing performances of zinc stannate with different morphology-based gas sensors. Sensors and Actuators B: Chemical, 227, 448-455. doi:10.1016/j.snb.2015.12.097
  22. Wang, X., Zhao, M., Liu, F., Jia, J., Li, X., & Cao, L. (2013). C2H2 gas sensor based on Ni-doped ZnO electrospun nanofibers. Ceramics International, 39(3), 2883-2887. doi:10.1016/j.ceramint.2012.09.062
  23. Wang, Y., Wang, Y., Cao, J., Kong, F., Xia, H., Zhang, J., Zhu, B., Wan, S., & Wu, S. (2008). Low-temperature H2S sensors based on Ag-doped α-Fe2O3 nanoparticles. Sensors and Actuators B: Chemical, 131(1), 183-189. doi:10.1016/j.snb.2007.11.002
  24. Yıldırım, M. A., Yıldırım, S. T., Cavanmirza, I., & Ateş, A. (2016). Chemically synthesis and characterization of MnS thin films by SILAR method. Chemical Physics Letters, 647, 73-78. doi:10.1016/j.cplett.2016.01.048