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Journals / Afyon Kocatepe Üniversitesi Fen ve Mühendislik Bilimleri Dergisi / 2026 / Cilt: 23 Sayı: 5

A Dispersive Liquid-Liquid Micro Extraction-Gas Chromatography-Mass Spectrometric Method for The Determination of 4-Nonylphenol in Water Samples

Su Örneklerinde 4-Nonylfenolün Tayini için Dispersif Sıvı-Sıvı Mikroekstraksiyon-Gaz Kromatografisi-Kütle Spektrometrik Bir Yöntem

Sabahattin Deniz(MARMARA ÜNİVERSİTESİ)0000-0002-8153-2417
Pages
1103–1111
Publication Date
2023-10-30
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AI Summary & Key Takeaways

AI Insight
⚡ TL;DR(Too Long; Didn't Read)

Analyte recovery rates ranged from 96% to 103%, having a relative standard deviation below 3%.The applied procedure was effectively evaluated for its suitability in examining tap water and river water samples.

📌 3 Key Takeaways

🎯
Objective & Hypothesis:In this study an environmentally-friendly, uncomplicated, and responsive method involving dispersive liquid-liquid microextraction (DLLME) was presented for the isolation and analysis of 4-nonylphenol in aquatic environments.
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Key Findings & Data:The extraction process employed the undecanol–water dispersive liquid-liquid system to isolate 4-nonylphenol.
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Conclusion & Impact:Analyte recovery rates ranged from 96% to 103%, having a relative standard deviation below 3%.The applied procedure was effectively evaluated for its suitability in examining tap water and river water samples.
🔬Design:Araştırma Makalesi
📍Scope:Comprehensive Sample
⚙️Variables:4-Nonilfenol · GC-MS · Sıvı-sıvı mikroekstraksiyon

Abstract

In this study an environmentally-friendly, uncomplicated, and responsive method involving dispersive liquid-liquid microextraction (DLLME) was presented for the isolation and analysis of 4-nonylphenol in aquatic environments. The extraction process employed the undecanol–water dispersive liquid-liquid system to isolate 4-nonylphenol. Essential variables impacting the efficiency of microextraction, such as the quantities of 1-undecanol and acetonitrile, as well as the ionic strength of the aqueous solution, were fine-tuned. Furthermore, the chromatographic parameters of the Gas Chromatography-Mass Spectrometer (GC-MS) were optimized for precise analysis, and the analysis of 4-nonylphenol was conducted using a linear calibration curve spanning 2-1000 µg/L, achieving a rapid 6-minute retention time. The method exhibited a detection limit of 0.05 µg/L and a preconcentration factor of 188. Analyte recovery rates ranged from 96% to 103%, having a relative standard deviation below 3%.The applied procedure was effectively evaluated for its suitability in examining tap water and river water samples.

Özet

Bu çalışmada çevre dostu, basit ve oldukça hassas bir teknik olan dağılma sıvı-sıvı mikroekstraksiyon (DLLME) yöntemi, sucul ortamlarda 4-nonylfenolün ayırma ve analizi için geliştirilmiştir. Ekstraksiyon işlemi, 1-undekanol-su dağılma sıvı-sıvı sistemi kullanılarak 4-nonylfenolün izolasyonunu içermiştir. 1 undekanol ve asetonitril miktarı ile sulu çözeltinin iyonik şiddeti gibi mikroekstraksiyon verimliliğini etkileyen temel değişkenler hassas bir şekilde ayarlanmıştır. Ayrıca, Gaz Kromatografisi-Kütle Spektrometresi (GC-MS) cihazının kromatografik parametreleri de hassas analiz için optimize edilmiş ve 4-nonylfenol analizi 2-1000 µg/L aralığında lineer kalibrasyon eğrisi kullanılarak gerçekleştirilmiştir, bu sayede hızlı bir 6 dakikalık alıkonma süresi elde edilmiştir. Yöntem, 0.05 µg/L tespit limiti ve 188 ön zenginleştirme faktörüne sahiptir. Analit geri kazanım oranları %96 ile %103 aralığındadır ve göreceli standart sapma %3'ün altındadır. Geliştirilen prosedür, musluk suyu ve nehir suyu örneklerinin incelenmesi için etkili bir şekilde değerlendirilmiştir.

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Cite This Article

Deniz, S. (2023). A Dispersive Liquid-Liquid Micro Extraction-Gas Chromatography-Mass Spectrometric Method for The Determination of 4-Nonylphenol in Water Samples. Afyon Kocatepe Üniversitesi Fen ve Mühendislik Bilimleri Dergisi, Cilt: 23 Sayı: 5, 1103–1111. https://doi.org/10.35414/akufemubid.1341412

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