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Journals / Afyon Kocatepe Üniversitesi Fen ve Mühendislik Bilimleri Dergisi / 2026 / Cilt: 24 Sayı: 4

Synthesis and Characterization of Novel Selenium N,S-heterocyclic carbene compounds

Yeni Selenyum N,S-heterosiklik Karben Bileşiklerinin Sentezi ve Karakterizasyonu

Deniz Demir Atlı(MANISA CELAL BAYAR UNIVERSITY)0000-0001-8442-4916
Pages
947–954
Publication Date
2024-08-20
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AI Summary & Key Takeaways

AI Insight
⚡ TL;DR(Too Long; Didn't Read)

Also, molecular weights of the selenium adducts were validated by LC-MS/MS analysis.

📌 3 Key Takeaways

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Objective & Hypothesis:Two novel benzothiazolium salts, N-(4-methoxybenzyl)benzothiazolium chloride (1a) and N-(4-tert-butylbenzyl)benzothiazolium bromide (1b), were prepared by using benzothiazole and related benzyl halides.
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Key Findings & Data:Selenourea N,S-heterocyclic-based derivatives (2a and 2b) were obtained by the reaction of the salts with selenium in the presence of KOBut base. 1H NMR, 13C NMR and elemental analysis were used for characterization of the synthesized compounds.
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Conclusion & Impact:Also, molecular weights of the selenium adducts were validated by LC-MS/MS analysis.
🔬Design:Araştırma Makalesi
📍Scope:Comprehensive Sample
⚙️Variables:Benzotiyazolyum · S-heterosiklik karben · Selenyum

Abstract

Two novel benzothiazolium salts, N-(4-methoxybenzyl)benzothiazolium chloride (1a) and N-(4-tert-butylbenzyl)benzothiazolium bromide (1b), were prepared by using benzothiazole and related benzyl halides. Selenourea N,S-heterocyclic-based derivatives (2a and 2b) were obtained by the reaction of the salts with selenium in the presence of KOBut base. 1H NMR, 13C NMR and elemental analysis were used for characterization of the synthesized compounds. Also, molecular weights of the selenium adducts were validated by LC-MS/MS analysis.

Özet

Benzotiyazol ve ilgili benzil halojenürler kullanılarak iki yeni benzotiyazolyum tuzu N-(4-metoksibenzil)benzotiyazolyum klorür (1a) ve N-(4-tert-bütilbenzil)benzotiyazolyum bromür (1b) hazırlandı. Selenoüre N,S-heterosiklik bazlı türevler (2a ve 2b), tuzların KOBut bazı varlığında selenyum ile reaksiyonu sonucu elde edildi. Sentezlenen bileşiklerin karakterizasyonu için 1H NMR, 13C NMR ve elementel analiz kullanıldı.. Ayrıca, selenyum katılma ürünlerinin molekül ağırlıkları LC-MS/MS analizi ile doğrulandı.

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Cite This Article

Atlı, D. D. (2024). Synthesis and Characterization of Novel Selenium N,S-heterocyclic carbene compounds. Afyon Kocatepe Üniversitesi Fen ve Mühendislik Bilimleri Dergisi, Cilt: 24 Sayı: 4, 947–954. https://doi.org/10.35414/akufemubid.1429062

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