Journals / Sigma Mühendislik ve Fen Bilimleri Dergisi / 2026 / Volume: 38 Issue: 2

THERMODYNAMICS OF A CHALCONE-BASED POLYMER BY INVERSE GAS CHROMATOGRAPHY METHOD

Ayşegül Ç. Adıgüzel(Bursa Technical University, Department of Chemistry)0000-0003-4765-1102
Burak Korkmaz(Istanbul Technical University, Department of Chemistry)0000-0002-2530-1761
Fatih Çakar(Yildiz Technical University, Department of Chemistry)0000-0001-6192-1370
Özlem Cankurtaran(Yildiz Technical University, Department of Chemistry)0000-0002-8383-1170
Yeşim Hepuzer Gürsel(5Istanbul Technical University, Department of Chemistry)0000-0003-4523-345X
Bahire Filiz Şenkal(Istanbul Technical University, Department of Chemistry)0000-0002-1616-6828
Ferdane Karaman(Yildiz Technical University, Department of Chemistry)
Pages
—
Publication Date
2021-06-01
DOI
—
🏛️Bibliographic metadata and full text access for this article are provided via DergiPark.
DergiPark Record ↗
✨

AI Summary & Key Takeaways

AI Insight
⚡ TL;DR(Too Long; Didn't Read)

The obtained results were discussed.

📌 3 Key Takeaways

🎯
Objective & Hypothesis:In this study, an inverse gas chromatography (IGC) study of thermodynamic interactions of a chalcone modified poly (styrene) based polymer (PVBC-DMAC) with some solvents was presented.
📊
Key Findings & Data:For this purpose, the retention data of carefully selected polar and non-polar solvents on PVBC-DMAC was obtained by IGC instrument at temperatures between 358.2 K and 383.2 K.
💡
Conclusion & Impact:The obtained results were discussed.
🔬Design:Research Article
📍Scope:Comprehensive Sample
⚙️Variables:Inverse gas chromatography · thermodynamics · poly (styrene) based polymer

Abstract

In this study, an inverse gas chromatography (IGC) study of thermodynamic interactions of a chalcone modified poly (styrene) based polymer (PVBC-DMAC) with some solvents was presented. For this purpose, the retention data of carefully selected polar and non-polar solvents on PVBC-DMAC was obtained by IGC instrument at temperatures between 358.2 K and 383.2 K. Then, the polymer-solvent interaction parameters for Flory-Huggins theory, X12 and the equation of state theory, X12*, the effective exchange energy parameters, Xeff, the weight fraction activity coefficient, 1, and also the partial molar heat of mixing at infinite dilution of solvent, ∆H1, the molar heat of vaporization of solvent, ∆Hv, and the partial molar heat of sorption of solvent, ∆H1s were calculated. The obtained results were discussed.

🔖

Cite This Article

Adıgüzel, A. Ç., Korkmaz, B., Çakar, F., Cankurtaran, Ö., Gürsel, Y. H., Şenkal, B. F., Karaman, F. (2021). THERMODYNAMICS OF A CHALCONE-BASED POLYMER BY INVERSE GAS CHROMATOGRAPHY METHOD. Sigma Mühendislik ve Fen Bilimleri Dergisi, Volume: 38 Issue: 2. https://ajindex.com/articles/1344832

📄 Full Text PDF Viewer

📄

PDF görüntüleyici hazırlanıyor...

References (29)

  1. Tazuke, S., (1982), Developments in Polymer Photochemistry, Applied Science Publishers, London, Vol.3.
  2. Reichmanis, E., Nalamasu, O., Houhihan, F.M., and Novembre, A.E., (1999), Radiation chemistry of polymeric materials: novel chemistry and applications for microlithography, Polym. Int.48,1053.
  3. Sakai, Y., Ueda, M. T. Fukuda, M. Matsuda, (1999), Synthesis and properties of a second‐order nonlinear optical side‐chain polyimide, J. Polym. Sci. PartA: Polym. Chem. 37, 1321.
  4. Kawatsuki, N., Sai, I., Yamamota, T. (1999), Linearly polarized ultraviolet photoreaction of photocrosslinkable polymers comprising thep-phenylenediacrylate group and photoalignment control of liquid crystals on the resultant film, J. Polym. Sci. PartA: Polym. Chem., 37, 4000-4006.
  5. Ohe, Y., Kume, M., Demachi, Y., Taguchi, T., Ichimura, K., (1999), Application of a novel photopolymer to a holographic head‐up display, Polym. Adv. Technol. 10,9,544.
  6. Erddalane, A., Fouassier, J. P., Morlet‐Savary, F., Takimoto, Y., (1996), Efficiency and excited state processes in a three‐component system, based on thioxanthene derived dye/amine/additive, usable in photopolymer plates, J. Polym. Sci. Part A: Polm. Chem.,34,4, 633.
  7. Kontogeorgis, G., von Solms, N., (2015), Thermodynamics of Polymer Solutions. Handbook of Surface and Colloid Chemistry, Fourth Edition, 199.
  8. Galdámez, J. R., Kernion, S. J., Duda, J. L., Danner, R. P., (2008), Determination of thermodynamic and transport properties of a polystyrene-co-acrylonitrile copolymer by infinite and finite concentration IGC, Polymer, 49(12), 2873–2879.
  9. Polymer Thermodynamics by Gas Chromatography, (1990), Volume 4, R. Vîlcu M. Leca, eBook ISBN: 9780444597434, Elsevier Science, 1st July 1990.
  10. Voelkel, A., Strzemiecka, B., Adamska, K., Milczewska, K., (2009), Inverse gas chromatography as a source of physiochemical data, J. Chromatogr. A, 1216, 1551.
  11. Smidsord, O., Guillet, J. E., (1969), Study of Polymer Solute Interactions by gas chromatography, Macromolecules, 2, 272.
  12. Milczewska, K., Voelkel, A., Piędzia, K., (2014), Interactions in PEG/Aerosil® and PLA/Aerosil® composites described by IGC-determined Flory–Huggins χ 23 parameter, J Polym Res., 21,1.
  13. Dritsas, G., Karatasos, K., Panayiotou, C., (2009), Investigation of thermodynamic properties of hyperbranched aliphatic polyesters by inverse gas chromatography, J Chromatogr A, 216, 8979.
  14. Cakar, F., Cankurtaran, O., Karaman, F., (2012), Relaxation and miscibility of the blends of a poly (Ether Imide) (Ultem™) and a phenol-a-based copolyester (Ardel™) by inverse gas chromatography, Chromatographia, 75,1157.
  15. Özdemir, E., Coşkun, M., Açlikses, A., (1991), Estimation of thermodynamic parameters of polystyrene-n_hydrocarbons systems using inverse gas chromatography, Macromol Rep, 28, 129.
  16. Guillet, J. E., Purnel, J. H., (1973), Advances in Analytical Chemistry and Instrumentation Gas Chromatography, Wiley, New York, NY, USA.
  17. Papadopoulou, S.K., Dritsas, G., Karapanagiotis, I., Zuburtikudis, I., Panayiotou, C., (2010) Surface characterization of poly(2,2,3,3,3-pentafluoropropyl methacrylate) by inverse gas chromatography and contact angle measurements, Eur. Polym. J,. 46, 2, 202.
  18. Adamska, K., Voelkel, A., (2006), Hansen solubility parameters for polyethylene glycols by inverse gas chromatography, J. Chromatogr. A, 1132,1-2, 260.
  19. Nastasovi´c, A.E., Onjia, S.K., Milonji´c, S.M., Jovanovi´c, (2005), Surface characterization of polymers by inverse gas chromatography, J. Polym. Sci., B: Polym.Phys., 43, 2524.
  20. Dritsas, G.S., Karatasos, K., Panayiotou, C., Investigation of thermodynamic properties of hyperbranched poly(ester amide) by inverse gas chromatography, (2008), J. Polym. Sci., B: Polym. Phys. 46, 20, 2166.
  21. Papadopoulou, S.K., Karapanagiotis, I., Zuburtikudis, I. Panayiotou, C., (2010), Thermodynamic characterization of poly(2,2,3,3,3-pentafluoropropyl methacrylate), J. Polym.Sci., B: Polym. Phys., 48,16, 1826.
  22. Al-Saigh, Z.Y., Munk, P., (1984), Study of polymer-polymer interaction coefficients in polymer blends using inverse gas chromatography, Macromolecules, 17, 803.
  23. Price, G.J., Guillet, J.E., Purnell, J.H., (1986), Measurements of solubility parameters by gas-liquid chromatography, J. Chromatogr., 369,273.
  24. Mohammadi-Jam, S., Waters, K.E., (2014), Inverse gas chromatography applications: A review, Advances in Colloid and Interface Science, 212, 21.
  25. Adiguzel, A. Ç., Çakar, F., Şenkal, B. F., et al., (2019), Determination of Glass Transition Temperature And Surface Properties of Novel Chalcone Modified Poly(Styrene) Based Polymer, Thermal Science, 23, 1,193.
  26. Çakar, F., Cankurtaran, O., (2005), Determination of secondary transitions and thermodynamic interaction parameters of poly (ether imide) by inverse gas chromatography, Polymer Bulletin, 55, 95.
  27. Yazıcı, Ö., Ocak, H., Çakar, F., Cankurtaran, O., Bilgin Eran, B., Karaman, F., (2008), Synthesis and thermodynamical interactions of (S)-5-(2- methylbutoxy)-2-[[[4-hexyloxyphenyl]Imino]methyl]-Phenol liquid crystal with some solvents, al with some solvents, Optoelectronics And Advanced Materials-Rapid Communications,2,6, 366.
  28. Guillet, J.E., (1973), New Developments in Gas Chromatography, Wiley-Interscience, New York, 187.
  29. Littlewood, BA., Gas chromatography, 1st ed. New York: Academic Press McGraw-Hill; 1970.