Dergiler / Communications Faculty of Sciences University of Ankara Series B Chemistry and Chemical Engineering / 1988 / Cilt: 34 - Sayı: 01.02

THE REACTİONS OF TRICHLORO-AND TRİBROMOBENZENES WITH HYDROXIDE ION AND PREPARATION OF DIHALOPHENOLS

Sayfa
44–46
DOI
—

Abstract

Trichloro and tribromobenzenes form dichloro-and dibromophenols with excess KOH in DMSO and water. The reactions are of bimolecular addition-elimination Sjç Ar type where a hydroxide ion displaces a halogen atom. Due to the deaetivation effect of hydroxide group, bound to the ring, no other hydroxide displacement was observed.