Dergiler / Journal of Scientific Reports-A / 2009 / Sayı: 020
BAZI HOFMANN-Td-TİPİ KLATRATLARIN TİTREŞİM SPEKTROSKOPİSİ İLE İNCELENMESİ: Ni(1,9-DİAMİNONONAN)M(CN)4.2G (M = Cd VEYA Hg, G = 1,3-DİKLOROBENZEN)
- Sayı
- 2009 · Sayı: 020
- Sayfa
- 1–6
- DOI
- —
Özet
Ni(1,9-diaminononan)M(CN)4.2G (M = Cd veya Hg, 1,9-diaminononan = danon, G = 1,3-diklorobenzen) genel formülüne sahip Hofmann-Td-tipi klatratlar toz halde hazırlanmakta ve bunların infrared ve Raman spektrumları sırasıyla (4000–200) cm-1 ve (2850–1650) cm-1 aralıklarında incelenmektedir. Spektrum sonuçları bu bileşiklerin yapısal olarak Hofmann-Td-tipi klatratlara benzediğini ortaya koymaktadır.
Abstract
New Hofmann-Td-type clathrates in the general form of Ni(1,9-diaminononane)M(CN)4.2G (M = Cd or Hg, 1,9-diaminononane = danon, G = 1,3-dichlorobenzene) have been prepared in powder form and their FT-IR and Raman spectra have been reported in the range of (4000–200) cm-1 and (2850–1650) cm-1, respectively. The spectral results suggest that these compounds are similar in structure to the Hofmann-Td-type clathrates.New Hofmann-Td-type clathrates in the general form of Ni(1,9-diaminononane)M(CN)4.2G (M = Cd or Hg, 1,9-diaminononane = danon, G = 1,3-dichlorobenzene) have been prepared in powder form and their FT-IR and Raman spectra have been reported in the range of (4000–200) cm-1 and (2850–1650) cm-1, respectively. The spectral results suggest that these compounds are similar in structure to the Hofmann-Td-type clathrates.