Dergiler / Turkish Journal of Physics / 1998 / Cilt: 22 - Sayı: 8
The Influence of Solvents on Formation of the Molecular Geometry of [{Fe(salphen)}2O]
- Sayfa
- 797–802
- DOI
- —
Özet
The crystal structure and magnetic properties of the complex (I)=[\{Fe(salphen)\}2\-O]\cdot(C4\-H8SO) and (II)=[\{Fe(salphen)\}2O]\cdot(C4H8O2)\- (salphen H2=N,N'-o-phenylenebis\-(salicylidene-imine)) were recently reported [1, 2]. This complex crystallized with the solvents of dimethyl sulfoxide and dioxane. In this paper, we investigate the influence of the solvents on the formation of the molecular geometry and study the orbital mechanism of the magnetic super-exchange interactions of this complex.
Abstract
The crystal structure and magnetic properties of the complex (I)=[\{Fe(salphen)\}2\-O]\cdot(C4\-H8SO) and (II)=[\{Fe(salphen)\}2O]\cdot(C4H8O2)\- (salphen H2=N,N'-o-phenylenebis\-(salicylidene-imine)) were recently reported [1, 2]. This complex crystallized with the solvents of dimethyl sulfoxide and dioxane. In this paper, we investigate the influence of the solvents on the formation of the molecular geometry and study the orbital mechanism of the magnetic super-exchange interactions of this complex.