Dergiler / Turkish Journal of Chemistry / 2000 / Cilt: 24 - Sayı: 4
X-Ray Powder Diffraction and IR Study of Calcium Borophosphate CaBPO5
- Sayfa
- 381–388
- DOI
- —
Özet
In this study, CaBPO5 was synthesized by different solid state reactions than reported before and its X-ray powder diffraction and IR data were reported. In one of these solid state reactions BPO4 was used as a phosphating agent. The examination of the X-ray powder diffraction data showed that this compound crystallized in a hexagonal system and the refined unit cell parameters were a = 6.684, c = 6.616(2) \AA, with Z=3 as reported before. From the observed reflections, the space group was determined as P3121, and its density was found to be 3.15 g/cc. The X-ray powder diffraction and IR data, which were in agreement with the reported crystal structure, are given the first time in this work.
Abstract
In this study, CaBPO5 was synthesized by different solid state reactions than reported before and its X-ray powder diffraction and IR data were reported. In one of these solid state reactions BPO4 was used as a phosphating agent. The examination of the X-ray powder diffraction data showed that this compound crystallized in a hexagonal system and the refined unit cell parameters were a = 6.684, c = 6.616(2) \AA, with Z=3 as reported before. From the observed reflections, the space group was determined as P3121, and its density was found to be 3.15 g/cc. The X-ray powder diffraction and IR data, which were in agreement with the reported crystal structure, are given the first time in this work.