Dergiler / Turkish Journal of Chemistry / 2002 / Cilt: 26 - Sayı: 2

A New Synthesis of Bromobenzotropones: Oxidation of 8-Bromo-5 H -Benzo[a]cycloheptene

Sayfa
143–152
DOI
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Özet

The oxidation of 8-bromo-5H-benzo[a]cycloheptene with some oxidation reagents was studied. 2,3- and 4,5-benzotropone derivatives were obtained. The structures of the bromobenzotropones were determined by 1H- and 13C-NMR data.

Abstract

The oxidation of 8-bromo-5H-benzo[a]cycloheptene with some oxidation reagents was studied. 2,3- and 4,5-benzotropone derivatives were obtained. The structures of the bromobenzotropones were determined by 1H- and 13C-NMR data.

Anahtar kelimeler: Tropone, benzotropone, bromobenzotropone, selenium dioxide and chromium trioxide oxidation.