Dergiler / Turkish Journal of Chemistry / 1999 / Cilt: 23 - Sayı: 3

Complexation of Benzoate Ligand With the Divalent d10 Acceptors at Different Temperatures

Sayfa
243–248
DOI
—

Özet

The complex formation between zinc(II), cadmium(II), mercury(II) and benzoate ions was studied potentiometrically with glass electrode at different temperatures. The measurements have been performed in a perchlorate medium of the unit ionic strength at 25, 30, 35 and 40°C. The stability constants of the complexes were found in the order of increasing softness i.e. Zn(II) < -Cd(II)

Abstract

The complex formation between zinc(II), cadmium(II), mercury(II) and benzoate ions was studied potentiometrically with glass electrode at different temperatures. The measurements have been performed in a perchlorate medium of the unit ionic strength at 25, 30, 35 and 40°C. The stability constants of the complexes were found in the order of increasing softness i.e. Zn(II) < -Cd(II)

Anahtar kelimeler: benzoate complexes; zinc compound; cadmium compound; mercury compound; thermoydnamics.