Ferulic Acid Substituted Zn(II) Phthalocyanine: Synthesis, Characterization and Investigation of Photophysical and Photochemical Properties

Abstract

In this study, novel peripherally ferulic acid tetra-substituted Zn(II) phthalocyanine wassynthesized for the first time. The synthesized phthalocyanine was characterized by elemental analysis,infrared spectroscopy, UV-Vis spectrophotometry, 1H-NMR spectroscopy, and MALDI-TOF MS techniques.The photophysical, photochemical and aggregation properties of this phthalocyanine were also investigatedin DMSO and DMF solvents. The aggregation studies showed that the synthesized Zn(II) phthalocyaninedoes not aggregate in DMSO and DMF. Fluorescence quantum yield (ΦF: 0.23 in DMSO and 0.17 in DMF),singlet oxygen quantum yield (ΦΔ:0.57 in DMSO and 0.45 in DMF) and photodegradation quantum yield(Φd:1.08x10-5 in DMSO and 4.44x10-5 in DMF) were also determined. These results show that thesynthesized phthalocyanine has potential use in photodynamic therapy.