Characteristics and source apportionment of VOCs in the suburban area of Beijing, China

Özet

The measurement of volatile organic compounds (VOCs) was conducted during November 2014 in thesuburban area of Beijing, China, covering the period of the Asia-Pacific Economic Cooperation (APEC)meeting period. The VOCs characteristics and source apportionment were analyzed. The average massconcentrations of VOCs were 27.6 ± 19.7 mg/m3 during the sampling period, and aromatics and alkaneswere the most abundant VOCs species in atmospheric environment in Beijing which were 12.2 ± 10.3 mg/m3 and 11.3 ± 7.5 mg/m3, respectively. The hourly variation of VOCs was found, with the highest concentrationoccurring at 8:00 to 9:30 and lowest at 12:30 to 14:00. The sampling period was divided intotwo periods: period Ⅰ represent the period without emission-reduction measures, and period Ⅱ representthe period with reduction measures. The VOCs concentrations during the period Ⅱ was 31.0% lower thanperiod Ⅰ. The Maximum Incremental Reactivity (MIR) method was applied to analysis the ozone formationpotential (OFP). The OFP of VOCs from period Ⅰ was 1.6 times higher than period Ⅱ, and themajority of VOCs species were alkenes and aromatics. Positive matrix factorization was applied to estimatecontributions of potential VOCs sources. The vehicle exhaust emission was the major source ofVOCs during the two periods, and the contribution to VOCs was 5.7% lower during period Ⅱ than period Ⅰdue to the emission-reduction of vehicle operation