Dergiler / Communications Faculty of Sciences University of Ankara Series B Chemistry and Chemical Engineering / 1985 / Cilt: 31

REACTION OF DIHALOCARBENE WITH SODIUM SALTS OF SOME ACTIVE METHYLENE COMPOUNDS

Sayfa
1–1
DOI
—

Abstract

Reaction of dichloro-or dibromocarbene with the sodium salts of ethybcetoacetate la, acetyl- acetone Ib, benzy ley anide Ic and cyclohexanone Id leads to formation the sodium salts of 1,3- diethyl-1, 3-diacetyl propene-1, 3- dicarboxylate ila, 1, 1, 3, 3-tetra-acetyl propene-1 11b, 1,3- dicyano-1, 3-diphenyl propene-1 He and (cyclohexyliden-2'-one)-2-methyl cyclohexanone Hd, respeetively. The strueture of the produets was established from speetra as well as analytical data.