Dergiler / Turkish Journal of Chemistry / 2004 / Cilt: 28 - Sayı: 6
Bromination of Tricyclo[7.2.1.02,7]dodeca-2,4,6,10-tetraene Derivatives: Electronic and Neighboring Group Effects on Bromination
- Sayfa
- 715–724
- DOI
- —
Özet
The bromination reaction of tricyclo[7.2.1.02,7]dodeca-2,4,6,10-tetraene derivatives was studied. The bromination of 9 gave only rearranged products 12 and 13, while the bromination of 8 with molecular bromine formed both rearranged 12 and non-rearranged products 15 and 16. The possible role of a substituent in the rearrangements was examined. All compounds were characterized properly, in particular by NMR spectra and chemical transformation.
Abstract
The bromination reaction of tricyclo[7.2.1.02,7]dodeca-2,4,6,10-tetraene derivatives was studied. The bromination of 9 gave only rearranged products 12 and 13, while the bromination of 8 with molecular bromine formed both rearranged 12 and non-rearranged products 15 and 16. The possible role of a substituent in the rearrangements was examined. All compounds were characterized properly, in particular by NMR spectra and chemical transformation.