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Dergiler / Turkish Journal of Chemistry / 2011 / Cilt: 35 - Sayı: 3

One pot synthesis of pyridophenanthroline and pyrrolophenanthroline derivatives by regioselective reaction between 1,7-phenanthroline and dialkyl acetylenedicarboxylate: new fused heterocyclic compounds

Malek Taher MAGHSOODLOU,Reza HEYDARI,Sayyed Mostafa Habibi KHORASSANI

Sayfa
405–412
DOI
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Özet

1,7-Phenanthroline reacts with dialkyl acetylenedicarboxylate in a regioselective manner to give new macromolecules such as tetramethyl- 6aH-pyrido[1,2-i][1,7]phenanthroline-7,8,9,10-tetracarboxylate and trialkyl pyrrolo[1,2-i][1,7]phenanthroline-7,8,9-tricarboxylate derivatives.

Abstract

1,7-Phenanthroline reacts with dialkyl acetylenedicarboxylate in a regioselective manner to give new macromolecules such as tetramethyl- 6aH-pyrido[1,2-i][1,7]phenanthroline-7,8,9,10-tetracarboxylate and trialkyl pyrrolo[1,2-i][1,7]phenanthroline-7,8,9-tricarboxylate derivatives.

Anahtar kelimeler: 1, 7-Phenanthroline, tetramethyl-6aH-pyrido[1, 2-i][1, 7] phenanthroline-7, 8, 9, 10-tetracarboxylate, trialkyl pyrrolo[1, 2-i] [1, 7]phenanthroline-7, 8, 9-tricarboxylate derivatives, regioselective cycloaddition reaction