Dergiler / Turkish Journal of Chemistry / 2010 / Cilt: 34 - Sayı: 2
Synthesis and characterization of non-symmetric tetradentate complexes of Zn(II), Co(II), and Cu(II)
- Sayfa
- 263–268
- DOI
- —
Özet
The non-symmetrical tetradentate Schiff-base H2L was obtained using the half-unit N-(1-hydroxy-2-acetophenone)-1-amino- 2-phenyleneimine (HL) with 2-hydroxyl-1-naphthaldehyde. ZnL, CoL, and CuL complexes were prepared and characterized by 1H-NMR, IR, electronic, and atomic absorption spectra. The single crystal X-ray structure of CuL was determined. Crystal data for CuL are triclinic space group P-1, a = 8.3933 (17) Å, b = 11.197 (2) Å, c = 13.381 (3) Å, a = 95.29 (3)°, b = 94.37 (3)°, g = 95.82 (3)°, and z = 2.
Abstract
The non-symmetrical tetradentate Schiff-base H2L was obtained using the half-unit N-(1-hydroxy-2-acetophenone)-1-amino- 2-phenyleneimine (HL) with 2-hydroxyl-1-naphthaldehyde. ZnL, CoL, and CuL complexes were prepared and characterized by 1H-NMR, IR, electronic, and atomic absorption spectra. The single crystal X-ray structure of CuL was determined. Crystal data for CuL are triclinic space group P-1, a = 8.3933 (17) Å, b = 11.197 (2) Å, c = 13.381 (3) Å, a = 95.29 (3)°, b = 94.37 (3)°, g = 95.82 (3)°, and z = 2.