Dergiler / Turkish Journal of Chemistry / 2014 / Cilt: 38 - Sayı: 6
Novel metal-free and metallophthalocyanines containing four 21-membered pentathiadiaza macrocycles: synthesis, characterization, and study of aggregation properties
- Sayfa
- 1073–1082
- DOI
- —
Özet
Metal-free phthalocyanine 3 and its metallophthalocyanine derivatives 4, 5, and 6 (M = Zn, Co, and Ni) substituted with four 21-membered pentathiadiaza macrocycles were synthesized and their structures identified by elemental analysis, IR, 1H NMR, mass, and UV-Vis spectroscopy techniques. The aggregation properties of phthalocyanines 4, 5, and 6 were investigated in different solvents and at different concentrations of dimethylformamide.
Abstract
Metal-free phthalocyanine 3 and its metallophthalocyanine derivatives 4, 5, and 6 (M = Zn, Co, and Ni) substituted with four 21-membered pentathiadiaza macrocycles were synthesized and their structures identified by elemental analysis, IR, 1H NMR, mass, and UV-Vis spectroscopy techniques. The aggregation properties of phthalocyanines 4, 5, and 6 were investigated in different solvents and at different concentrations of dimethylformamide.