Dergiler / Turkish Journal of Chemistry / 2015 / Cilt: 39 - Sayı: 1

Preparation of visible light sensitive nano-sized N-TiO2 photocatalysts and their photocatalytic activity under visible light

Sayfa
159–168
DOI
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Özet

This study aimed to develop a photocatalyst that responds to visible light. For the preparation of visible light sensitive photocatalysts, N was doped into TiO2 (N-TiO2). To inhibit the recombination of excited electrons and holes, transition metals (M = Pt, Cu, Fe, Cr) were loaded on the N-TiO2. N-TiO2 nanotubes were also synthesized by a hydrothermal treatment of the prepared N-TiO2 in a strong basic environment. The prepared photocatalysts were characterized by XRD, FESEM, HRTEM, XPS, and UV/VIS spectrophotometer, and their photocatalytic activity was tested by the photodecomposition of liquid-phase methylene blue and gas-phase acetone.

Abstract

This study aimed to develop a photocatalyst that responds to visible light. For the preparation of visible light sensitive photocatalysts, N was doped into TiO2 (N-TiO2). To inhibit the recombination of excited electrons and holes, transition metals (M = Pt, Cu, Fe, Cr) were loaded on the N-TiO2. N-TiO2 nanotubes were also synthesized by a hydrothermal treatment of the prepared N-TiO2 in a strong basic environment. The prepared photocatalysts were characterized by XRD, FESEM, HRTEM, XPS, and UV/VIS spectrophotometer, and their photocatalytic activity was tested by the photodecomposition of liquid-phase methylene blue and gas-phase acetone.

Anahtar kelimeler: Visible light sensitive TiO2, N-doping, transition metal loading, N-TiO2 nanotubes