Dergiler / Gazi University Journal of Science Part A: Engineering and Innovation / 2023 / Cilt: 10 Sayı: 3

Optimization of Green Synthesis Parameters of Silver Nanoparticles with Factorial Design for Dye Removal

Sayfa
327–340
Yayın Tarihi
2023-09-29
DOI
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Additionally, reaction rate kinetics were estimated, and dye removal showed a slightly higher R-square of pseudo second-order than NP production, which fits the pseudo first-order reaction model.

📌 3 Maddede Bu Makale

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Amaç & Hipotez:In this study production of silver nanoparticles (AgNPs) from collard greens were optimized by the design of experiments (DOE).
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Temel Bulgular & Veri:A 24 full factorial design was employed to evaluate the effects on two responses.
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Sonuç & Katkı:Additionally, reaction rate kinetics were estimated, and dye removal showed a slightly higher R-square of pseudo second-order than NP production, which fits the pseudo first-order reaction model.
🔬Tür:Modelleme & Sayısal Simülasyon
📍Kapsam:Genişletilmiş Akademik Örneklem
⚙️Değişkenler:Silver Nanoparticles · Factorial Design · Green Synthesis

Abstract

In this study production of silver nanoparticles (AgNPs) from collard greens were optimized by the design of experiments (DOE). A 24 full factorial design was employed to evaluate the effects on two responses. The optimized values for AgNP production were 1:7 leaf to water, 1:4 extract to AgNO3, 5 molar AgNO3, and a leaf size of <1 mm. For dye removal efficiency, the optimized values were changed to 1:15 of leaf to water and 1:10 of extract to AgNO3, while the other two parameters remained the same. SEM (scanning electron microscopy) showed that optimizing the process for dye removal led to smaller AgNP production with increased surface area, resulting in higher absorbency. ANOVA (analysis of variance) tables were used to interpret each parameter's main and effects on interaction. Additionally, reaction rate kinetics were estimated, and dye removal showed a slightly higher R-square of pseudo second-order than NP production, which fits the pseudo first-order reaction model.

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Bu Makaleye Atıf Yap

BAYIK, G. D., BAYKAL, B. (2023). Optimization of Green Synthesis Parameters of Silver Nanoparticles with Factorial Design for Dye Removal. Gazi University Journal of Science Part A: Engineering and Innovation, Cilt: 10 Sayı: 3, 327–340. https://ajindex.com/articles/966133

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Kaynakça (7)

  1. Abdelghany, T. M., Al-Rajhi, A. M. H., Al Abboud, M. A., Alawlaqi, M. M., Ganash Magdah, A., Helmy, E. A. M., & Mabrouk, A. S. (2018). Recent Advances in Green Synthesis of Silver Nanoparticles and Their Applications: About Future Directions. A Review. BioNanoScience, 8(1), 5-16. doi:10.1007/s12668-017-0413-3
  2. Akter, M., Rahman, Md. M., Ullah, A. K. M. A., Sikder, Md. T., Hosokawa, T., Saito, T., & Kurasaki, M. (2018). Brassica rapa var. japonica Leaf Extract Mediated Green Synthesis of Crystalline Silver Nanoparticles and Evaluation of Their Stability, Cytotoxicity and Antibacterial Activity. Journal of Inorganic and Organometallic Polymers and Materials, 28(4), 1483-1493. doi:10.1007/s10904-018-0818-7
  3. Bala, A., & Rani, G. (2020). A review on phytosynthesis, affecting factors and characterization techniques of silver nanoparticles designed by green approach. International Nano Letters, 10(3), 159-176. doi:10.1007/s40089-020-00309-7
  4. Bhargavi, R. J., Maheshwari, U., & Gupta, S. (2015). Synthesis and use of alumina nanoparticles as an adsorbent for the removal of Zn(II) and CBG dye from wastewater. International Journal of Industrial Chemistry, 6(1), 31-41. doi:10.1007/s40090-014-0029-1
  5. Çimen, B., Şengül, S., Ergüt, M., & Özer, A. (2019). Green Synthesis and Characterization of CuO Nanoparticles: Telon Blue AGLF and Methylene Blue Adsorption. Sinop University Journal of Natural Sciences, 4(1), 1-20. doi:10.33484/sinopfbd.315643 David, L., & Moldovan, B. (2020). Green Synthesis of Biogenic Silver Nanoparticles for Efficient Catalytic Removal of Harmful Organic Dyes. Nanomaterials, 10(2), 202. doi:10.3390/nano10020202 Golli, R., Thummaneni, C., Pabbathi, D. D., Srungarapu, T., Jayasri, G., & Vangalapati, M. (2023). Silver nanoparticles synthesized by Brassica oleracea (Broccoli) acting as antifungal agent against Candida albicans. In: M. Seenuvasan, & D. M. Sangeetha (Eds.), Proceedings of the Second Global Conference on Recent Advances in Sustainable Materials 2022. Materials Today: Proceedings, (vol. 80, part 2, pp. 1495-1500). doi:10.1016/j.matpr.2023.01.284 Imanzadeh, G., & Hadi, R. (2018).
  6. Brassica Oleraceae, A Versatile Plant For Green Synthesis of Silver Nanoparticles. Iranian Chemical Communication, 6(1), 70-77.
  7. Iravani, S. (2011). Green synthesis of metal nanoparticles using plants. Green Chemistry, 13(10), 2638-2650. doi:10.1039/C1GC15386B Jeevanandam, J., Chan, Y. S., & Danquah, M. K. (2016). Biosynthesis of metal and metal oxide nanoparticles. ChemB