Dergiler / Aquatic Sciences and Engineering / 2023 / Cilt: 38 - Sayı: 1

Green Synthesized Nanoceria Applied as a Fenton-Like Catalyst for Degrading Methylene Blue

Sayfa
74–80
Yayın Tarihi
2023-01-24
DOI
—
🏛️Bu makalenin bibliyografik verileri ve tam metin bağlantısı DergiPark üzerinden sağlanmıştır.
DergiPark Kaydı ↗
✨

Yapay Zeka Hızlı Bakış & Çıkarımlar

AI Insight
⚡ TL;DR(1 Cümlede Hızlı Çıkarım)

According to the possible reaction kinetics discussed within the study, the reaction rate was calculated at 1.49 × 10-2 min -1, thus enabling a faster reaction for a better evaluation of the reaction mechanism compared to other degradation processes that have been previously investigated.

📌 3 Maddede Bu Makale

🎯
Amaç & Hipotez:Nanomaterials are preferred for scientific studies due to their spectral properties and perfect surface appearance.
📊
Temel Bulgular & Veri:The study proposes this new nanoparticle (with the aid of H2 O2 and UV combinations) as an alternative to iron in Fenton-type reactions for enabling MB degradation.
💡
Sonuç & Katkı:According to the possible reaction kinetics discussed within the study, the reaction rate was calculated at 1.49 × 10-2 min -1, thus enabling a faster reaction for a better evaluation of the reaction mechanism compared to other degradation processes that have been previously investigated.
🔬Tür:Araştırma Makalesi
📍Kapsam:Genişletilmiş Akademik Örneklem
⚙️Değişkenler:Hydroxyl radicals · nanoceria · Thymbra spicata

Abstract

Nanomaterials are preferred for scientific studies due to their spectral properties and perfect surface appearance. This study aims to introduce a novel, environmentally friendly, photocatalytic method for degrading methylene blue (MB) in aqueous solutions. With this purpose in mind, the study synthesizes nanoceria particles and coats them with zahter (Thymbra spicata; zahter-coated nanoceria, ZCNC) following the main outlines of green chemistry as characterized by SEM and FTIR analyses. The study proposes this new nanoparticle (with the aid of H2 O2 and UV combinations) as an alternative to iron in Fenton-type reactions for enabling MB degradation. The maximum efficiency was observed through the ternary combination of zahter-coated nanoceria, UV light, and H2 O2 at 63% concentration. The degradation of the MB solution was achieved by installing a small amount of ZCNC (0.1g), after which the absorbance values were measured at 664 nm. According to the possible reaction kinetics discussed within the study, the reaction rate was calculated at 1.49 × 10-2 min -1, thus enabling a faster reaction for a better evaluation of the reaction mechanism compared to other degradation processes that have been previously investigated.

🔖

Bu Makaleye Atıf Yap

ÖZYURT, D., OLGUN, F. A. O., DEMİRATA, B., APAR, R. (2023). Green Synthesized Nanoceria Applied as a Fenton-Like Catalyst for Degrading Methylene Blue. Aquatic Sciences and Engineering, Cilt: 38 - Sayı: 1, 74–80. https://ajindex.com/articles/878454

📄 Tam Metin PDF Okuyucu

📄

PDF görüntüleyici hazırlanıyor...

Kaynakça (15)

  1. Aguedach, A., Brosillon, S., Morvan, J., Lhadi, E.K., 2005. Photocatalytic degradation of azo-dyes reactive black 5 and reactive yellow 145 in water over a newly deposited titaniumdioxide. Appl. Catal. B. 57 55-62.
  2. Aleboyeh, A., Kasiri, M.B., Aleboyeh, H., 2012. Influence of dyeing auxiliaries on AB74 dye degradation by UV/H2O2 process, J. Environ. Manag. 113, 426-431.
  3. Anastas P.T., Warner, J.C., 1998. Green Chemistry: Theory and Practice; Oxford University Press,
  4. London. Babuponnusami, A., Muthukumar, K., 2014. A review on Fenton and improvements to the Fenton process for wastewater treatment. J. Environ. Chem. Engin. 2, 557-572.
  5. Chan, S.H.S., Wu, T.Y., Juan, J.C., The C.Y., 2011. Recent developments of metal oxide semiconductors as photocatalysts in advanced oxidation processes (AOPs) for treatment of dye waste-water, J. Chem. Technol. Biotechnol. 86, 1130-1158.
  6. Channei, D., Inceesungvorn, B., Wetchakun, N., 2014. Photocatalytic degradation of methyl orange by CeO2 and Fe-doped CeO2 films under visible light, Sci. Rep. 4, 1-7.
  7. Choe, E., Min, D. B., 2006. Chemistry and Reactions of Reactive Oxygen Species in Foods, J. Food Sci. 70, 142-159.
  8. Corma, A., Atienzar, P., Garcia, H., Chane-Ching, J.Y., 2004. Hierarchically Mesostructured Doped CeO2 with Potential for Solar-Cell Use. Nature Mater. 3, 394-397.
  9. Dong X., Lin Y., Ren G., Ma Y., Zhao L., 2021. Catalytic Degradation of Methylene Blue by Fenton-like Oxidation of Ce-doped MOF. Colloids and Surfaces A 608 125-578.
  10. Foo, K.Y., Hameed, B.H., 2012. Preparation, characterization and evaluation of adsorptive properties of orange peel based activated carbon via microwave induced K2CO3 activation, Bioresour. Technol. 104, 679-686.
  11. Ghaedi, M., Golestani Nasab, A., Khodadoust, S., Rajabi, M., Azizian, S., 2014. Application of activated carbon as adsorbents for efficient removal of methylene blue: Kinetics and equilibrium study, J. Ind. Eng. Chem. 20, 2317-2324.
  12. Ghaedi, M., Mazaheri, H., Khodadoust, S., Hajati, S., Purkait, M.K., 2015. Application of central composite design for simultaneous removal of methylene blue and Pb(2+) ions by walnut wood activated carbon, Spectrochim. Acta A Mol. Biomol. Spectrosc. 135, 479-490.
  13. Ghaly, A., Ananthashankar, R., Al-Hattab, M.K., Ramakrishnan, V., 2014.
  14. Production, Characterization and Treatment of Textile Effluents: A Critical Review, J. Chem. Eng. Process Technol. 5, 1-18.
  15. Gogoi, A., Sarma, K.C., 2017. Synthesis of the novel P—cyclodextrin supported CeO2 nanoparticles for th