The spectroscopic and the potentiometric results were compared with thecalculated results.
📌 3 Maddede Bu Makale
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Amaç & Hipotez:The electrophilic carbon atoms of aldehydes can be targets of nucleophilic attack byamines.
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Temel Bulgular & Veri:This type of compound is known as a Schiff base.In this study some Schiff bases were synthesized from 2-quinoline aldehyde and someaniline derivatives and the molecules were characterized with spectroscopic methods.
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Sonuç & Katkı:The spectroscopic and the potentiometric results were compared with thecalculated results.
🔬Tür:Araştırma Makalesi
📍Kapsam:Genişletilmiş Akademik Örneklem
⚙️Değişkenler:Schiff base · theoretical studies · experimental studies
Abstract
The electrophilic carbon atoms of aldehydes can be targets of nucleophilic attack byamines. The end result of this reaction is a compound in which the C=O double bond isreplaced by a C=N double bond. This type of compound is known as a Schiff base.In this study some Schiff bases were synthesized from 2-quinoline aldehyde and someaniline derivatives and the molecules were characterized with spectroscopic methods. ThepKa values of the molecules calculated with potentiometric methods and DFT calculatedmethods. The spectroscopic and the potentiometric results were compared with thecalculated results.
ELMALI, D., KASIM, İ., AYTEKİN, T., BERBER, H. (2015). THEORETICAL AND EXPERIMENTAL STUDIES OF SOME SCHIFF BASE. Journal of the Turkish Chemical Society Section A: Chemistry, Cilt: 2 - Sayı: 2, 27–29. https://ajindex.com/articles/781760
Esmaielzadeh, S., Azimian, L., Shekoohi, K., Mohammadi, K., Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, Volume 133, 10 December 2014, Pages 579–590