KaydedilenlerDerginizi ekleyin

Dergiler / Journal of the Turkish Chemical Society Section A: Chemistry / 2016 / Cilt: 3 - Sayı: 2

CONVENTIONAL AND MICROWAVE-ASSISTED SYNTHESIS AND CHARACTERIZATION of Ru(III)/Cu(II) COMPLEXES CONTAINING DICARBOXYLIC ACID GROUPS

Emel YILDIZ
Burak AY
Sayfa
103–116
Yayın Tarihi
2016-05-06
DOI
—
🏛️Bu makalenin bibliyografik verileri ve tam metin bağlantısı DergiPark üzerinden sağlanmıştır.
DergiPark Kaydı ↗
✨

Yapay Zeka Hızlı Bakış & Çıkarımlar

AI Insight
⚡ TL;DR(1 Cümlede Hızlı Çıkarım)

The metal complexes of Cu(II) and Ru(III) were easily synthesized upon exposure to microwave irradiation.

📌 3 Maddede Bu Makale

🎯
Amaç & Hipotez:Abstract: In this study, microwave-assisted and conventional syntheses of Ru(III) and Cu(II) complexes with 2,4-pyridinedicarboxylic acid (L1), 3,5-pyridinedicarboxylic acid (L2), and 3,5-pyrazoledicarboxylic acid (L3) have been studied.
📊
Temel Bulgular & Veri:A comparative study of microwave and conventional methods was performed to determine their differences in terms of reaction time, the amount of solvent, and reaction yield.
💡
Sonuç & Katkı:The metal complexes of Cu(II) and Ru(III) were easily synthesized upon exposure to microwave irradiation.
🔬Tür:Araştırma Makalesi
📍Kapsam:Genişletilmiş Akademik Örneklem
⚙️Değişkenler:Alan Parametreleri

Abstract

Abstract: In this study, microwave-assisted and conventional syntheses of Ru(III) and Cu(II) complexes with 2,4-pyridinedicarboxylic acid (L1), 3,5-pyridinedicarboxylic acid (L2), and 3,5-pyrazoledicarboxylic acid (L3) have been studied. A comparative study of microwave and conventional methods was performed to determine their differences in terms of reaction time, the amount of solvent, and reaction yield. The reaction time was reduced significantly from several hours to a few minutes, and high yields were obtained by microwave method while using considerably less amount of solvent. The synthesized complexes were characterized by FT-IR, UV-Vis, AAS, 1H-NMR, elemental analyses, and magnetic susceptibility. These studies showed that copper and ruthenium complexes have square planar and octahedral geometries, respectively. The metal complexes of Cu(II) and Ru(III) were easily synthesized upon exposure to microwave irradiation.

🔖

Bu Makaleye Atıf Yap

YILDIZ, E., AY, B. (2016). CONVENTIONAL AND MICROWAVE-ASSISTED SYNTHESIS AND CHARACTERIZATION of Ru(III)/Cu(II) COMPLEXES CONTAINING DICARBOXYLIC ACID GROUPS. Journal of the Turkish Chemical Society Section A: Chemistry, Cilt: 3 - Sayı: 2, 103–116. https://ajindex.com/articles/781722

📄 Tam Metin PDF Okuyucu

📄

PDF görüntüleyici hazırlanıyor...

Kaynakça (1)

  1. Lan A, Han L, Yuan D, Jiang F, Hong M. A blue luminescent inorganic–organic hybrid with infinite [Cd3(μ3-OH)2(μ2-Cl)2] connectivity. Inorganic Chemistry Communications. 2007 Sep;10(9):993–6. DOI: 10.1016/j.inoche.2007.05.009.S, Swami M. Microwave-assisted synthesis, characterization and biological activities of organotin (IV) complexes with some thio Schiff bases. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy. 2009 Mar;72(2):260–8. DOI: 10.1016/j.saa.2008.09.017. Liu Y, Li Y-X, Zhang S-W, Ji H-M, Cao R-G, Liu S-X. Organic–inorganic hybrid based on the molybdenum tellurite. Journal of Molecular Structure. 2009 Mar;921(1-3):114–7. DOI: 10.1016/j.molstruc.2008.12.058. Wu L, Ma H, Han Z, Li C. Synthesis, structure and property of a new inorganic–organic hybrid compound [Cu(phen)2][Cu(phen)H2O]2[Mo5P2O23]·3.5H2O. Solid State Sciences. 2009 Jan;11(1):43–8. DOI: 10.1016/j.solidstatesciences.2008.05.016. Ellsworth JM, Smith MD, zur Loye H-C. Improved synthesis of 4,4′-bipyridine-2-carboxylic acid and its use in the construction of novel metal and mixed-metal coordination polymers. Solid State Sciences. 2008 Dec;10(12):1822–34. DOI: 10.1016/j.solidstatesciences.2008.03.014. Wang R, Lu X, Yu X, Shi L, Sun Y. Acid-catalyzed solvent-free synthesis of 2-arylbenzimidazoles under microwave irradiation. Journal of Molecular Catalysis A: Chemical. 2007 Apr;266(1-2):198–201. DOI: 10.1016/j.molcata.2006.04.071. Cortijo M, Delgado-Martínez P, González-Prieto R, Herrero S, Jiménez-Aparicio R, Perles J, et al. Microwave and solvothermal methods for the synthesis of nickel and ruthenium complexes with 9-anthracene carboxylate ligand. Inorganica Chimica Acta. 2015 Jan;424:176–85. DOI: 10.1016/j.ica.2014.07.063. Bui HTB, Ha QTK, Oh WK, Vo DD, Chau YNT, Tu CTK, et al. Microwave assisted synthesis and cytotoxic activity evaluations of new benzimidazole derivatives. Tetrahedron Letters. 2016 Feb;57(8):887–91. DOI: 10.1016/j.tetlet.2016.01.042. Anderson TJ, Scott JR, Millett F, Durham B. Decarboxylation of 2,2‘-Bipyridinyl-4,4‘-dicarboxylic Acid Diethyl Ester during Microwave Synthesis of the Corresponding Trichelated Ruthenium Complex. Inorganic Chemistry. 2006 May;45(10):3843–5. DOI: 10.1021/ic060008v. Singh RV, Chaudhary P, Chauhan S, Swami M. Microwave-assisted synthesis, characterization and biological activities of organotin (IV) complexes with some thio Schiff bases. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy. 2009 Mar;72(2):260–8.