Dergiler / Journal of the Turkish Chemical Society Section A: Chemistry / 2018 / Cilt: 5 - Sayı: 1

FENTON-LIKE OXIDATION OF REACTIVE BLACK 5 IN THE PRESENCE OF LABO3 (B: Fe, Co, Mn, Ni) PEROVSKITE CATALYSTS

Sayfa
37–44
Yayın Tarihi
2017-12-15
DOI
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The most suitable reaction conditions were determined as 0.1 g/L of catalyst loading, 3 and 1 mM of H2O2, and, 96.9% degradation, and complete decolorization were achieved under these conditions.

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Amaç & Hipotez:The catalytic performances of LaBO3 (B: Fe, Co, Mn, Ni) perovskite catalysts in Fenton-like oxidation of the textile dye, Reactive Black 5 were compared, and, the optimum reaction conditions were investigated in the presence of the most efficient catalyst.
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Temel Bulgular & Veri:Reactive Black 5 was selected as the model dye due to its complex chemical structure, high water solubility and common usage in the textile industry.
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Sonuç & Katkı:The most suitable reaction conditions were determined as 0.1 g/L of catalyst loading, 3 and 1 mM of H2O2, and, 96.9% degradation, and complete decolorization were achieved under these conditions.
🔬Tür:Modelleme & Sayısal Simülasyon
📍Kapsam:Genişletilmiş Akademik Örneklem
⚙️Değişkenler:Reactive Black 5 · Fenton-like oxidation · Perovksite catalysts

Abstract

The catalytic performances of LaBO3 (B: Fe, Co, Mn, Ni) perovskite catalysts in Fenton-like oxidation of the textile dye, Reactive Black 5 were compared, and, the optimum reaction conditions were investigated in the presence of the most efficient catalyst. Reactive Black 5 was selected as the model dye due to its complex chemical structure, high water solubility and common usage in the textile industry. The performances of the catalysts in Reactive Black 5 degradation and decolorization were compared by testing different catalyst loadings. According to the catalyst screening experiments, LaFeO3 showed the highest catalytic performance whereas LaCoO3, LaMnO3, and, LaNiO3 were not effective in the degradation and decolorization of Reactive Black 5. A parametric study was carried out in the presence of LaFeO3 catalyst in order to determine the most suitable reaction conditions. In the parametric study, the effect of catalyst loading, pH and the initial H2O2 concentration were investigated. The initial dye concentration and the reaction temperature were kept constant at 100 ppm and 50℃, respectively. The most suitable reaction conditions were determined as 0.1 g/L of catalyst loading, 3 and 1 mM of H2O2, and, 96.9% degradation, and complete decolorization were achieved under these conditions.

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Bu Makaleye Atıf Yap

Palas, B., Ersöz, G., Atalay, S. (2017). FENTON-LIKE OXIDATION OF REACTIVE BLACK 5 IN THE PRESENCE OF LABO3 (B: Fe, Co, Mn, Ni) PEROVSKITE CATALYSTS. Journal of the Turkish Chemical Society Section A: Chemistry, Cilt: 5 - Sayı: 1, 37–44. https://ajindex.com/articles/781448

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  1. Akpan, U.G. and Hammed, B.H., 2009. Parameters affecting the photocatalytic degradation of dyes using TiO2-based photocatalyst, J. Hazard. Mater., 170, 520. Gan, P.P., Li and S.F.Y., 2013. Efficient removal of Rhodamine B using a rice hull-based silica supported iron catalyst by Fenton-like process, Chem. Eng. J., 229, 351. Kasiri, M.B., Aleboyeh, H. and Aleboyeh, A., 2008. Degradation of Acid Blue 74 using Fe-ZSM5 zeolite as a heterogeneous photo-Fenton catalyst, Appl. Catal. B: Environ., 84(1–2), 9. Labhasetwar, N., Saravanan, G., Megarajan, S.K., Manwar, N., Khobragade, R., Doggal, P. and Grasset. F., 2015. Perovskite-type catalytic materials for environmental applications, Sci. Technol. Adv. Mater., 16, p. 036002, 13 pp. Panda, N., Sahoo, H. and Mohapatra S., 2011. Decolourization of Methyl Orange using Fenton-like mesoporous Fe2O3–SiO2 composite, J. Hazard. Mater., 185, 359. Sun, J.H., Sun, S.P., Wang, G.L. and Qiao, L.P., 2007, Degradation of azo dye Amido black 10B in aqueous solution by Fenton oxidation process, Dyes Pigm., 74, 647. Taran, O.P., Ayusheev, A.B., Ogorodnikova, O.L., Prosvirin, I.P., Isupova, L.A. and Parmon, V.N., 2016. Perovskite-like catalysts LaBO3 (B = Cu, Fe, Mn, Co, Ni) for wet peroxide oxidation of phenol, Appl. Catal. B: Environ., 180, 86. Wu, C.-H., Kuo, C.-Y. and Chang, C.-L., 2008. Decolorization of C.I. Reactive Red 2 by catalytic ozonation processes, J. Hazard. Mater., 153 1052