Dergiler / Cankaya University Journal of Science and Engineering / 2022 / Cilt: 19 - Sayı: 2

Analysis of the Specific Heat and Calculation of the Entropy, Enthalpy, and Free Energy Close to the Lower Phase Transition in Imidazolium Perchlorate

Sayfa
95–101
Yayın Tarihi
2022-11-01
DOI
—
🏛️Bu makalenin bibliyografik verileri ve tam metin bağlantısı DergiPark üzerinden sağlanmıştır.
DergiPark Kaydı ↗
✨

Yapay Zeka Hızlı Bakış & Çıkarımlar

AI Insight
⚡ TL;DR(1 Cümlede Hızlı Çıkarım)

Moreover, the temperature dependence of some thermodynamic functions such as entropy, enthalpy, and the Gibbs free energy were calculated using the values of α and 𝐽𝐴 extracted from the observed specific heat data of Im-ClO4.

📌 3 Maddede Bu Makale

🎯
Amaç & Hipotez:The abnormal behavior of the specific heat of Imidazolium Perchlorate (Im-ClO4) was analyzed in terms of the power-law formula (including critical exponent α and fitting parameter JA) derived from the Ising model around the lower phase transition temperature of TC = 247 K.
📊
Temel Bulgular & Veri:The abnormal behavior of the specific heat of Imidazolium Perchlorate (Im-ClO4) was analyzed in terms of the power-law formula (including critical exponent α and fitting parameter JA) derived from the Ising model around the lower phase transition temperature of TC = 247 K.
💡
Sonuç & Katkı:Moreover, the temperature dependence of some thermodynamic functions such as entropy, enthalpy, and the Gibbs free energy were calculated using the values of α and 𝐽𝐴 extracted from the observed specific heat data of Im-ClO4.
🔬Tür:Modelleme & Sayısal Simülasyon
📍Kapsam:Genişletilmiş Akademik Örneklem
⚙️Değişkenler:specific heat · thermodynamic functions · Im-ClO4.

Abstract

The abnormal behavior of the specific heat of Imidazolium Perchlorate (Im-ClO4) was analyzed in terms of the power-law formula (including critical exponent α and fitting parameter JA) derived from the Ising model around the lower phase transition temperature of TC = 247 K. Moreover, the temperature dependence of some thermodynamic functions such as entropy, enthalpy, and the Gibbs free energy were calculated using the values of α and 𝐽𝐴 extracted from the observed specific heat data of Im-ClO4.

🔖

Bu Makaleye Atıf Yap

KARA, N., KİRACI, A., YURTSEVEN, H. (2022). Analysis of the Specific Heat and Calculation of the Entropy, Enthalpy, and Free Energy Close to the Lower Phase Transition in Imidazolium Perchlorate. Cankaya University Journal of Science and Engineering, Cilt: 19 - Sayı: 2, 95–101. https://ajindex.com/articles/745963

📄 Tam Metin PDF Okuyucu

📄

PDF görüntüleyici hazırlanıyor...

Kaynakça (12)

  1. E. B. Anderson, and T. E. Long, “Imidazole- and imidazolium-containing polymers for biology and material science applications,” Polymer, vol. 51, no. 12, pp. 2447–2454, 2010
  2. C. G. Hanke, S. L. Price, and R. M. Lynden-Bell. “Intermolecular potentials for simulations of liquid imidazolium salts,” Molecular Physics, vol. 99, no.10, pp. 801–809, 2001
  3. Y. Zhang, and J. Y. G. Chan, “Sustainable chemistry: imidazolium salts in biomass conversion and CO2 fixation,” Energy & Environmental Science, vol. 3, no. 4, pp. 408–417, 2010
  4. L. Zhao, C. Zhang, L. Zhuo, Y. Zhang, and J. Y. Ying. “Imidazolium Salts: A Mild Reducing and Antioxidative reagent,” Journal of the American Chemical Society, vol. 130, no. 38, pp. 12586–12587, 2008
  5. H. Ma, W. Gao, J. Wang, T. Wu, G. Yuan, J. Liu, and Z. Liu, “Ferroelectric polarization switching dynamics and domain growth of Triglycine Sulfate and Imidazolium Perchlorate,” Advanced Electronic Materials, vol. 2, p. 1600038, 2016
  6. W. Gao, L. Chang, H. Ma, L. You, J. Yin, J. Liu, Z. Liu, J. Wang, and G. Yuan, “Flexible organic ferroelectric films with a large piezoelectric response,” NPG Asia Materials, vol. 7, no. 6, p 189, 2015
  7. Y. Zhang, Y. Liu, H. Y. Ye, D. W. Fu, W. Gao, H. Ma, Z. Liu, Y. Liu, W. Zhang, J. Li, G. L. Yuan, and R. G. Xiong, “A molecular ferroelectric thin film of imidazolium perchlorate that shows superior electromechanical coupling,” Angewandte Chemie International Edition, vol. 126, pp. 5164-5168, 2014
  8. Y. Hu, Z. Guo, A. Ragonese, T. Zhu, S. Khuje, C. Li, J. C. Grossman, C. Zhou, M. Nouh, and S. A. Ren, “3Dprinted molecular ferroelectric metamaterial,” Proceedings of the National Academy of Sciences, vol. 117, no. 44, pp. 27204-27210, 2020
  9. Z. Pająk, P. Czarnecki, B. Szafrańska, H. Małuszyńska, and Z. Fojud, “Ferroelectric ordering in imidazolium perchlorate,” The Journal of Chemical Physics, vol. 124, no. 14, p. 144502, 2006
  10. Z. Czapla, S. Dacko, B. Kosturek, and A. Waskowska, “Dielectric and optical properties related to phase transitions in an imidazolium perchlorate [C3N2H5ClO4] crystal,” Physica Status Solidi (b), vol. 242, pp. 122-124, 2005
  11. J. Przesławski, and Z. Czapla, “Calorimetric studies of phase transitions in imidazolium perchlorate crystal,” Journal of Physics: Condensed Matter, vol. 18, no. 23, pp. 5517–5524, 2006
  12. N. Kara, A. Kiraci, and H. Yurtseven, “Calculation of the Relaxation Time and the Activation Energy Close to the Lower Phase Transition in