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Dergiler / Düzce Üniversitesi Bilim ve Teknoloji Dergisi / 2019 / Cilt:7 Sayı:2 (2019) (Özel Sayı)

Ruthenium(II) half-sandwich complexes containing N-substituted 5-nitrobenzimidazole: Synthesis, structures and catalytic transfer hydrogenation of ketones

Kenan BULDURUN
İsmail ÖZDEMİR
Sayfa
63–72
Yayın Tarihi
2019-03-30
DOI
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⚡ TL;DR(1 Cümlede Hızlı Çıkarım)

This complexes was found to be an active catalyst in the catalytic transfer hydrogenation of ketones.

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Amaç & Hipotez:In this study,N-substituted 5-nitrobenzimidazole ligands were reacted with [RuCl2(p-cymene)]2 and the corresponding complexes were prepared and their structure were elucidated by elemental analysis, IR and NMR spectroscopic techniques.
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Temel Bulgular & Veri:The synthesized Ru(II) complexes were tested as catalysts for the transfer hydrogenation (TH) of acetophenone to secondary alcohols in the presence of KOH using 2–propanol as a hydrogen source at 82 ºC.
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Sonuç & Katkı:This complexes was found to be an active catalyst in the catalytic transfer hydrogenation of ketones.
🔬Tür:Araştırma Makalesi
📍Kapsam:Genişletilmiş Akademik Örneklem
⚙️Değişkenler:Benzimidazole · Catalysis · Ru(II) complexes

Özet

In this study,N-substituted 5-nitrobenzimidazole ligands were reacted with [RuCl2(p-cymene)]2 and the corresponding complexes were prepared and their structure were elucidated by elemental analysis, IR and NMR spectroscopic techniques. The synthesized Ru(II) complexes were tested as catalysts for the transfer hydrogenation (TH) of acetophenone to secondary alcohols in the presence of KOH using 2–propanol as a hydrogen source at 82 ºC. This complexes was found to be an active catalyst in the catalytic transfer hydrogenation of ketones.

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Bu Makaleye Atıf Yap

BULDURUN, K., ÖZDEMİR, İ. (2019). Ruthenium(II) half-sandwich complexes containing N-substituted 5-nitrobenzimidazole: Synthesis, structures and catalytic transfer hydrogenation of ketones. Düzce Üniversitesi Bilim ve Teknoloji Dergisi, Cilt:7 Sayı:2 (2019) (Özel Sayı), 63–72. https://ajindex.com/articles/660954

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Kaynakça (12)

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