The calculated values are compared with the experimental findings collected from literature and quite satisfactory results are obtained.
📌 3 Maddede Bu Makale
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Amaç & Hipotez:Thermodynamic properties of liquids and liquid mixtures play very important role in understanding the nature of molecular interactions occurring in the system.
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Temel Bulgular & Veri:In the present work different thermodynamic properties of 15 pure liquids and 34 equimolar binary liquid mixtures of benzene, toluene, p-xylene, chlorobenzene and 1-chloronaphthalene with linear and branched alkanes have been computed with the help of Flory’s statistical theory (FST), Hard sphere equation of state (HSE) and Hole theory (HT) simultaneously.
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Sonuç & Katkı:The calculated values are compared with the experimental findings collected from literature and quite satisfactory results are obtained.
🔬Tür:Araştırma Makalesi
📍Kapsam:Genişletilmiş Akademik Örneklem
⚙️Değişkenler:Flory statistical theory · hard sphere equation of state · hole theory
Abstract
Thermodynamic properties of liquids and liquid mixtures play very important role in understanding the nature of molecular interactions occurring in the system. In the present work different thermodynamic properties of 15 pure liquids and 34 equimolar binary liquid mixtures of benzene, toluene, p-xylene, chlorobenzene and 1-chloronaphthalene with linear and branched alkanes have been computed with the help of Flory’s statistical theory (FST), Hard sphere equation of state (HSE) and Hole theory (HT) simultaneously. The calculated values are compared with the experimental findings collected from literature and quite satisfactory results are obtained.
SANGURI, V., PANDEY, J. D., CHANDRA, P., SETHI, R. (2022). Estimation of Thermodynamic Properties of Binary Liquid Mixtures on the Basis of Statistical Mechanical Theories. International Journal of Thermodynamics, Cilt: 16 - Sayı: 1, 10–19. https://ajindex.com/articles/541856
Abe, A. & Flory, P. J. (1965). The Thermodynamic Properties of Mixtures of Small, Nonpolar Molecules. J. Am. Chem. Soc., 87, 1838-1846.
Acosta, J., Acre, A., Rodil, E., & Soto, A.(2001).
Densities, Speeds of Sound, Refractive indices and the corresponding changes of Mixing at 25 atmospheric pressure for systems composed by Ethyl acetate, Hexane and Acetone. J. Chem. Eng. Data, 46(5), 1176-1180. C and Acree (Jr), W. E. (1984). Thermodynamic Properties of Nonelectrolyte Solutions, I N C London Ltd: Academic Press.
Ali, A. & Nain, A. K. (2000). Study of molecular interactions in non-aqueous binary liquid mixtures through ultrasonic measurements. J. Pure Appl. Ultrason., 22, 10-15.
Ali, A., & Nain, A.K. (2002).Ultrsonic & Volumetric Study of Binary Mixtures of Benzyl Alcohol with Amides. Bull.Chem. Soc.Japan, 75(4), 681-687.
Ali, A. & Nain, A. K. (2002). Ultrasonic study of molecular interaction in binary liquid mixtures at 30oC. Pramana 58(4), 695-701.
Ali, A., Nain, A. K., Sharma, V. K. & Ahmad, S. (2000). Acoustical studies of molecular interaction in binary liquid mixtures at 35o C. J. Acoust. Soc. India, 28, 283- 288. Ali, A., Tiwari, K., Nain, A.K., & Chakravortty, V. (2000). Ultrasonic study of molecular interaction in ternary mixtures of dimethyl sulphoxides (1) + carbon tetrachloride (2) + aromatic hydrocarbons (3) at 308.15K. Indian J. Phys., 74B, 351-355. rce., rce,. r., geitos,., odil, E., odr gue,., Soto, A. (2000). Physical and equilibrium properties of diisopropyl ether+isopropyl alcohol+water system. Fluid Phase Equilibria,170, 113- 126. Baluja, S. (2002). Ultrasonic studies of resorcinol in protic & aprotic solvents at 40o. J. Indian Chem. Soc., 79, 142- 144. Bloomfeld, V. A. & Dewan, R. K. (1971). Viscosity of liquid mixtures. J Phys. Chem., 75, 3113-3119.
Canosa, J., odr ´gue,., Tojo,. (2001). Liquid-Liquid Equilibrium and Physical Properties of the Ternary Mixture (Dimethyl Cyclohexane) at 298.15 K. J. Chem. Eng. Data, 46, 846-850. + Methanol + Carnahan, N. F., Starling, K. E. (1969). Equation of State for Nonattracting Rigid Spheres. J. Chem. Phys., 51, 635-636.
Costas, M., Tra, H. V., Patterson, D., Alonso, M. C., Tardajos, G. & Aicart, E. (1988). Liquid structure and second-order mixing functions for 1-chloronaphthalene with linear and branched alkanes. J. Chem. Soc. Faraday Trans 1, 84, 1603-1616. CRC Handbook of Chem. & Phys., (1997-98). (78th Edition) New York: CRC Press,
Boca Raton. Dewan, R. K., Bloomfeld, V. A. & Berge