Dergiler / Hacettepe Journal of Biology and Chemistry / 2008 / Cilt: 36 - Sayı: 4

Phenolics separation by molecularly imprinted monolithic CEC column

Sayfa
353–362
Yayın Tarihi
2022-10-17
DOI
—
🏛️Bu makalenin bibliyografik verileri ve tam metin bağlantısı DergiPark üzerinden sağlanmıştır.
DergiPark Kaydı ↗
✨

Yapay Zeka Hızlı Bakış & Çıkarımlar

AI Insight
⚡ TL;DR(1 Cümlede Hızlı Çıkarım)

We have combined molecular imprinting with the ability of methacryloyl based modification in CEC column between p-nitrophenol and MAAP to create CEC-monolith suitable for phenol, o- and m-cresol, pdichlorophenol and 2,6-dichlorophenol, p- and o-nitrophenol separation.

📌 3 Maddede Bu Makale

🎯
Amaç & Hipotez:Capillary electrochromatography (CEC) has investigated as a technique for the separation of the following phenolic compounds: phenol, o- and m-cresol, p-dichlorophenol and 2,6-dichlorophenol, p- and o-nitrophenol.
📊
Temel Bulgular & Veri:We have proposed novel CEC monolithic column for selective separation of phenolics by Methacrylamidoantipyrine, MAAP, as a new charge-transfer monomer via multiple interactions (both hydrogen bonding and hydrophobic interactions) and 4-nitrophenol.
💡
Sonuç & Katkı:We have combined molecular imprinting with the ability of methacryloyl based modification in CEC column between p-nitrophenol and MAAP to create CEC-monolith suitable for phenol, o- and m-cresol, pdichlorophenol and 2,6-dichlorophenol, p- and o-nitrophenol separation.
🔬Tür:Araştırma Makalesi
📍Kapsam:Genişletilmiş Akademik Örneklem
⚙️Değişkenler:Alan Parametreleri

Abstract

Capillary electrochromatography (CEC) has investigated as a technique for the separation of the following phenolic compounds: phenol, o- and m-cresol, p-dichlorophenol and 2,6-dichlorophenol, p- and o-nitrophenol. We have proposed novel CEC monolithic column for selective separation of phenolics by Methacrylamidoantipyrine, MAAP, as a new charge-transfer monomer via multiple interactions (both hydrogen bonding and hydrophobic interactions) and 4-nitrophenol. We have combined molecular imprinting with the ability of methacryloyl based modification in CEC column between p-nitrophenol and MAAP to create CEC-monolith suitable for phenol, o- and m-cresol, pdichlorophenol and 2,6-dichlorophenol, p- and o-nitrophenol separation.

🔖

Bu Makaleye Atıf Yap

ERSÖZ, A. (2022). Phenolics separation by molecularly imprinted monolithic CEC column. Hacettepe Journal of Biology and Chemistry, Cilt: 36 - Sayı: 4, 353–362. https://ajindex.com/articles/529359

📄 Tam Metin PDF Okuyucu

📄

PDF görüntüleyici hazırlanıyor...

Kaynakça (22)

  1. S. Rengaraj, S-H. Moon, R. Sivabalan, B. Arabindoo and V. Murugesan, J. Hazardous Materials, B89 (2002) 185
  2. R.M. Alanso-Salces, E. Korta, A. Barranco, L.A. Berrueta, B. Gallo and F. Vicente, J. Chromatography A, 933 (2001) 37
  3. G. Wulff, Angew. Chem. Int. Ed. Engl., 34 (1995) 1812
  4. A.A. Özcan, R. Say, A. Denizli and A. Ersöz, Analytical Chemistry, 78 (2006) 7653
  5. E. Birlik, A. Ersöz, A. Denizli and R. Say, Anal. Chim. Acta, 565 (2006) 145
  6. S. Büyüktiryaki, R. Say, A. Denizli and A. Ersöz, Talanta, 71 (2007) 699
  7. M.A. Rodriguez-Delgado, S. Malovana, J.P. Perez, T. Borges and F.J.G. Montelongo, J. Chromatography A, 912 (2001) 249
  8. A. Escarpa and M.C. Gonzales J. Chromatogrphy A, 897 (2000) 161
  9. M. Rizz, D. Ventrice, M.A. Varone, R. Sidari and A. Caridi, Journal of Pharmaceutical and Biomedical Analysis, 42 (2006) 46
  10. M. Rubilar, M. Pinelo, C. Shene, J. Sineiro and M. Nunez, J. Agric. Food Chem., 55 (2007) 10101
  11. I. Rodriguez, M.I. Turnes, M.H. Bollain, M.C. Mejuta and R. Cela, J. Chromatography A, 778 (1997) 279
  12. A. Dermaux and P. Sandra, Electrophoresis, 20 (1999) 3027
  13. K.D. Bartle and P. Myers, J. Chromatography A, 916 (2001) 3
  14. D. Lima, A.C. Duarte and V.I. Esteves,Talanta, 72 (2007) 1404
  15. F.P. Capote, J. Rodriguez and M. Castro, Journal of Chromatography A, 1139 (2007) 301
  16. F.N. Fonseca, M. Tavares and C. Horvath, Journal of Chromatography A, 1154 (2007) 390
  17. Z-S. Liu, Y-L. Xu, C. Yan and R-Y. Gao, J. Chromatog. A., 1087 (2005) 20
  18. I. Steinke, D.C. Sherrington and I. R. Dunkin, Adv. Polym. Sci., 123 (1995) 81
  19. B. Sellergren, Techniques and Instrumentation in Analytical Chemistry, Molecularly Imprinted Polymers, 1st edn., Vol 23, Chapter 6, Elsevier, 2001
  20. A. Ersöz, A. Denizli, İ. Şener, A. Atılır, S. Diltemiz and R. Say, Sep. Purif. Technol., 38 (2004) 173
  21. E.C. Peters, M. Petro, F. Svec and J.M.C. Frechet, Anal. Chem., 69 (1997) 3646
  22. Z. Liu, H. Zou, M. Ye, J. Ni and Y. Zhang, Electrophoresis, 20 (1999) 2898.