Dergiler / Cumhuriyet Science Journal / 2020 / Cilt: 41 - Sayı: 2

Dissolution kinetics of manganese during nickel recovery from high iron grade laterite by acid leaching combined NaOH-assisted mechanochemical technology

Sayfa
397–406
Yayın Tarihi
2022-10-12
DOI
—
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⚡ TL;DR(1 Cümlede Hızlı Çıkarım)

According to the results, the mechanochemistrycontributed positively to the dissolution of manganese due to the increased leachability oflaterite at low temperature and in a short time with low acid consumption.

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Amaç & Hipotez:This study investigates the effect of the process involving a combination of sodium-basedreagent-assisted mechanochemical conversion (NaOH-MC) and leaching, which wasdeveloped to provide highly efficient nickel recovery, on the amount of dissolved manganeseduring nickel recovery.
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Temel Bulgular & Veri:Inoptimum conditions determined as 0.5 M H2SO4, 55 mL/g liquid to solid ratio, 75 ºC and 30min; dissolution amount of manganese from NaOH-MC treated laterite was achieved as97.54% ± 1.06 (N = 2) with standard deviation.
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Sonuç & Katkı:According to the results, the mechanochemistrycontributed positively to the dissolution of manganese due to the increased leachability oflaterite at low temperature and in a short time with low acid consumption.
🔬Tür:Modelleme & Sayısal Simülasyon
📍Kapsam:Genişletilmiş Akademik Örneklem
⚙️Değişkenler:Alan Parametreleri

Abstract

This study investigates the effect of the process involving a combination of sodium-basedreagent-assisted mechanochemical conversion (NaOH-MC) and leaching, which wasdeveloped to provide highly efficient nickel recovery, on the amount of dissolved manganeseduring nickel recovery. For this purpose, firstly laterite was treated with NaOH as a reagentand then leaching performed in sulphuric acid medium. Response Surface Methodology(RSM) was successfully used as a statistical approach to determine the effect of parametersfor both processes and to optimize processes conditions in terms of dissolved manganese. Inoptimum conditions determined as 0.5 M H2SO4, 55 mL/g liquid to solid ratio, 75 ºC and 30min; dissolution amount of manganese from NaOH-MC treated laterite was achieved as97.54% ± 1.06 (N = 2) with standard deviation. In addition, the dissolution behavior ofmanganese was defined by a control mechanism, a combination of chemical reaction anddiffusion based on the shrinking core kinetic model. The activation energy of manganesedissolution was found as 35.42 kJ/mol. According to the results, the mechanochemistrycontributed positively to the dissolution of manganese due to the increased leachability oflaterite at low temperature and in a short time with low acid consumption.

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Bu Makaleye Atıf Yap

ÇETİNTAŞ, S., BİNGÖL, D. (2022). Dissolution kinetics of manganese during nickel recovery from high iron grade laterite by acid leaching combined NaOH-assisted mechanochemical technology. Cumhuriyet Science Journal, Cilt: 41 - Sayı: 2, 397–406. https://ajindex.com/articles/477744

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Kaynakça (13)

  1. Xin B., Li T., Li X., Dan Z., Xu F., Duan N., Zhang Y. and Zhang H. Reductive dissolution of manganese from manganese dioxide ore by autotrophic mixed culture under aerobic conditions. J. Cleaner Prod., 92 (2015) 54-64
  2. Zhang W., Cheng C.Y. and Pranolo Y. Investigation of methods for removal and recovery of manganese in hydrometallurgical processes. Hydrometallurgy, 101 (2010) 58-63
  3. Zhang W., Cheng C.Y., Manganese metallurgy review. Part I: Leaching of ores/secondary materials and recovery of electrolytic/chemical manganese dioxide, Hydrometallurgy, 89 (2007) 137-159
  4. Zhang Y., Chen X., Chu W., Cui H. and Wang M. Removal of vanadium from petroleum coke by microwave and ultrasonic-assisted leaching. Hydrometallurgy, 191, (2020) 105168
  5. Li C., Liang B., Study on the mechanochemical oxidation of ilmenite, J. Alloys Compd., 459 (2008) 354-361
  6. Baláž P., Mechanical activation in hydrometallurgy, Int. J. Miner. Process., 72 (2003) 341-354
  7. Nayak A.K., Pal A., Statistical modeling and performance evaluation of biosorptive removal of Nile blue A by lignocellulosic agricultural waste under the application of high-strength dye concentrations. J. Environ. Chem. Eng., 8(2) (2020) 103677
  8. Çetintaş S., Bingöl D., Response surface methodology approach to leaching of nickel laterite and evaluation of different analytical techniques used for the analysis of leached solutions, Anal. Methods., 8 (2016) 3075-3087
  9. Abrouki Y., Anouzla A., Loukili H., Bennazha J., Lotfi R., Rayadh A., Bahlaoui M.A., Sebti, S., Zakarya D. and Zahouily M. Experimental designbased response surface methodology optimization for synthesis of 𝛽-mercapto carbonyl derivatives as antimycobacterial drugs catalyzed by calcium pyrophosphate. Int. J. Med. Chem., (2014) doi:
  10. Montgomery D.C., Design and analysis of experiments, 7th ed. John Wiley & Sons, New York, 2008
  11. Lundstedt T., Seifert E., Abramo L., Thelin B., Nyström Å., Pettersen J., Bergman R. Experimental design and optimization. Chemometr. Intell. Lab. Syst., 42 (1998) 3-40
  12. Çetintaş S., Yildiz U. and Bingöl D. A novel reagent-assisted mechanochemical method for nickel recovery from lateritic ore. J. Cleaner Prod., 199 (2018) 616-632
  13. MacCarthy J., Nosrati A., Skinner W. and Addai- Mensah J. Atmospheric acid leaching mechanisms and kinetics and rheological studies of a low grade saprolitic nickel laterite ore. Hydrometallurgy, 160 (2016) 26-37