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Dergiler / ARI The Bulletin of the Istanbul Technical University / 2004 / Cilt: 54 - Sayı: 2

Obtaining the ratio of termination rate constants of poly (methyl methacrylate) by the ultrasonic scission method

Öncül Ayşegül KOÇ
Ahmet GİZ
Çatalgil Huceste GİZ
Sayfa
6–11
Yayın Tarihi
2022-10-11
DOI
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The Chi square map obtained by fitting the data to Schmid's equation gives the ratio of the rate constants for termination by disproportionation and by combination as $k_{td}/k_{tc}$ = 2.6 ± 0.4.

📌 3 Maddede Bu Makale

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Amaç & Hipotez:The termination step in radical polymerization occurs either by combination or by disproportionation.
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Temel Bulgular & Veri:The termination mechanism of poly (methyl methacrylate) in sonochemical environment is studied by the ultrasonic scission method.
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Sonuç & Katkı:The Chi square map obtained by fitting the data to Schmid's equation gives the ratio of the rate constants for termination by disproportionation and by combination as $k_{td}/k_{tc}$ = 2.6 ± 0.4.
🔬Tür:Araştırma Makalesi
📍Kapsam:Genişletilmiş Akademik Örneklem
⚙️Değişkenler:Alan Parametreleri

Abstract

The termination step in radical polymerization occurs either by combination or by disproportionation. The termination mechanism of poly (methyl methacrylate) in sonochemical environment is studied by the ultrasonic scission method. The method is improved to give quantitative results by incorporating non-linear least squares analysis of the data. The Chi square map obtained by fitting the data to Schmid's equation gives the ratio of the rate constants for termination by disproportionation and by combination as $k_{td}/k_{tc}$ = 2.6 ± 0.4.

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Bu Makaleye Atıf Yap

KOÇ, Ö. A., GİZ, A., GİZ, Ç. H. (2022). Obtaining the ratio of termination rate constants of poly (methyl methacrylate) by the ultrasonic scission method. ARI The Bulletin of the Istanbul Technical University, Cilt: 54 - Sayı: 2, 6–11. https://ajindex.com/articles/448138

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