This reaction could be first example for the radical C-C bond cleavage reactions including ferrocene.
📌 3 Maddede Bu Makale
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Amaç & Hipotez:In general, Suzuki-Miyaura coupling reaction between aryl bromide and arylboronic acids form the new C-C bond in the presence of Pd-catalyst.
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Temel Bulgular & Veri:In the present study, 2-bromo-3-ferrocenyl-1,4-naphthoquinone 2 intermediate is synthesized by starting from 2,3-dibromo-1,4-naphthoquinone via Suzuki-Miyaura Coupling reaction.
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Sonuç & Katkı:This reaction could be first example for the radical C-C bond cleavage reactions including ferrocene.
In general, Suzuki-Miyaura coupling reaction between aryl bromide and arylboronic acids form the new C-C bond in the presence of Pd-catalyst. In the present study, 2-bromo-3-ferrocenyl-1,4-naphthoquinone 2 intermediate is synthesized by starting from 2,3-dibromo-1,4-naphthoquinone via Suzuki-Miyaura Coupling reaction. Then, it is investigated that the reaction between 2 and arylboronic acids give a new rearrangement reaction involving free radicals. Ferrocene structure displays critical roles for the formation of 2,3-diaryl-1,4-naphthoquinones. This reaction could be first example for the radical C-C bond cleavage reactions including ferrocene.
ERTAS, N. A., KIVRAK, A. (2020). Ferrocene as a leaving group; Unexpected rearrangement reactions for the synthesis of 2,3-diarylnapthoquinones. Manas Journal of Engineering, Cilt: 8 - Sayı: 1, 22–27. https://ajindex.com/articles/281447
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