Dergiler / Hacettepe Journal of Biology and Chemistry / 2020 / The 100 Year of Polymers

Polyurethanes: Design, synthesis and structure-property behavior of versatile materials

Sayfa
425–445
Yayın Tarihi
2020-11-01
DOI
—
🏛️Bu makalenin bibliyografik verileri ve tam metin bağlantısı DergiPark üzerinden sağlanmıştır.
DergiPark Kaydı ↗
✨

Yapay Zeka Hızlı Bakış & Çıkarımlar

AI Insight
⚡ TL;DR(1 Cümlede Hızlı Çıkarım)

We hope this article, which is prepared to celebrate the 100th anniversary of Polymer Science, will be useful to those who are newcomers to the field, but also to the experienced researchers to better understand the structure-property behavior of polyurethanes and tailor-design novel structures for various applications.

📌 3 Maddede Bu Makale

🎯
Amaç & Hipotez:Polyurethanes are one of the most important classes of polymeric materials.
📊
Temel Bulgular & Veri:In this short review, important physical and chemical factors and parameters that have a significant effect on the properties of polyurethanes are discussed.
💡
Sonuç & Katkı:We hope this article, which is prepared to celebrate the 100th anniversary of Polymer Science, will be useful to those who are newcomers to the field, but also to the experienced researchers to better understand the structure-property behavior of polyurethanes and tailor-design novel structures for various applications.
🔬Tür:Literatür & Derleme Çalışması
📍Kapsam:Genişletilmiş Akademik Örneklem
⚙️Değişkenler:Polyurethane · polyurea · PU foam

Abstract

Polyurethanes are one of the most important classes of polymeric materials. This is mainly due to the availability of a very large number of inherently different starting materials that allows the design and synthesis of polyurethane based materials with a wide range of properties for numerous applications. In this short review, important physical and chemical factors and parameters that have a significant effect on the properties of polyurethanes are discussed. Critical contribution of hydrogen bonding on the structure-morphology-property behavior of these materials was emphasized by both experimental data and molecular simulation studies. Influence of the chemical structures, solubility parameters and molecular weights of the soft and hard segments on morphology and properties were discussed. Important issues regarding the reaction chemistry, synthetic method used and thermal history on structure and performance of polyurethanes were explained. We hope this article, which is prepared to celebrate the 100th anniversary of Polymer Science, will be useful to those who are newcomers to the field, but also to the experienced researchers to better understand the structure-property behavior of polyurethanes and tailor-design novel structures for various applications.

🔖

Bu Makaleye Atıf Yap

YILGÖR, İ., YILGÖR, E. (2020). Polyurethanes: Design, synthesis and structure-property behavior of versatile materials. Hacettepe Journal of Biology and Chemistry, The 100 Year of Polymers, 425–445. https://ajindex.com/articles/255696

📄 Tam Metin PDF Okuyucu

📄

PDF görüntüleyici hazırlanıyor...

Kaynakça (17)

  1. Yilgor, I., E. Yilgor, and G.L. Wilkes, Critical parameters in designing segmented polyurethanes and their effect on morphology and properties: A comprehensive review. Polymer, 2015. 58: p. A1-A36
  2. Schollenberger, C.S., H. Scott, and G.H. Moore, Polyurethane VC, a virtually cross-linked elastomer. Rubber World, 1958. 137: p. 549-555
  3. Saunders, J.H. and K.C. Frisch, Polyurethanes: Chemistry and Technology. 1962, New York: Interscience Publishers
  4. Hepburn, C., Polyurethane elastomers. Second edition ed. 1992, London, UK: Elsevier Science Publishers
  5. Lambla, N.M.K., K.A. Woodhouse, and S.L. Cooper, Polyurethanes in Biomedical Applications. 1998, Boca Raton, FL, USA: CRC Press
  6. Krol, P., Synthesis methods, chemical structures and phase structures of linear polyurethanes. Properties and applications of linear polyurethanes in polyurethane elastomers, copolymers and ionomers. Progress in Materials Science, 2007. 52(6): p. 915-1015
  7. Delebecq, E., et al., On the Versatility of Urethane/Urea Bonds: Reversibility, Blocked Isocyanate, and Non-isocyanate Polyurethane. Chemical Reviews, 2013. 113(1): p. 80-118
  8. Herrington, R. and K. Hock, Flexible Polyurethane Foams. 1991, USA: Dow Plastics
  9. Yilgor, I. and J.E. McGrath, EFFECT OF CATALYSTS ON THE REACTION BETWEEN A CYCLOALIPHATIC DIISOCYANATE (H-MDI) AND NORMAL-BUTANOL. Journal of Applied Polymer Science, 1985. 30(4): p. 1733-1739
  10. Sato, M., The rate of reaction of isocyanates with alcohols. II. Journal of Organic Chemistry, 1962. 27(3): p. 819-825
  11. Yilgor, E., I. Yilgor, and E. Yurtsever, Hydrogen bonding and polyurethane morphology. I. Quantum mechanical calculations of hydrogen bond energies and vibrational spectroscopy of model compounds. Polymer, 2002. 43(24): p. 6551-6559
  12. Sami, S., et al., Understanding the influence of hydrogen bonding and diisocyanate symmetry on the morphology and properties of segmented polyurethanes and polyureas: Computational and experimental study. Polymer, 2014. 55(18): p. 4563-4576
  13. Bayer, O., Verfahren zur Herstellung von Polyurethanen bzw. Polyharnstoffen. 1938: Germany
  14. Bayer, O., Das Di-Isocyanat-Polyadditionsverfahren (Polyurethane). Angewandte Chemie-International Edition, 1947. 59(9): p. 257-272
  15. Hermes, M.E., Enough for One Lifetime: Wallace Carothers, Inventor of Nylon. 1996, Washington DC, USA: ACS
  16. Keifer, D.H., The Establishment of Modern Polymer Science By Wallace H. Carothers 2000, USA: ACS
  17. Hentschel, T. and H.