KaydedilenlerDerginizi ekleyin

Dergiler / TOJSAT / 2011 / Volume: 1 Issue: 1

TENSILE PROPERTIES OF POLYPROPYLENE/METAL OXIDE NANO COMPOSITES

Mirigul Altan
Huseyin Yildirim
Alper Uysal
Dergi
TOJSAT
Sayfa
—
Yayın Tarihi
2016-07-23
DOI
—
🏛️Bu makalenin bibliyografik verileri ve tam metin bağlantısı DergiPark üzerinden sağlanmıştır.
DergiPark Kaydı ↗
✨

Yapay Zeka Hızlı Bakış & Çıkarımlar

AI Insight
⚡ TL;DR(1 Cümlede Hızlı Çıkarım)

This is probably due to the better compatibility of TiO2 with SEBS-g-MA and this case induced more fine structure of TiO2 with PP while ZnO particles agglomerated in some regions of the matrix which confirms the results of lower elongation and degree of crystallization

📌 3 Maddede Bu Makale

🎯
Amaç & Hipotez:Polymers reinforced with nano metal oxides open up new pathways for engineering flexible composites that exhibit better mechanical and chemical properties.
📊
Temel Bulgular & Veri:In this study, tensile properties of the polypropylene (PP) composites filled with nano titan dioxide (TiO2) and zinc oxide (ZnO) were investigated.
💡
Sonuç & Katkı:This is probably due to the better compatibility of TiO2 with SEBS-g-MA and this case induced more fine structure of TiO2 with PP while ZnO particles agglomerated in some regions of the matrix which confirms the results of lower elongation and degree of crystallization
🔬Tür:Article
📍Kapsam:Genişletilmiş Akademik Örneklem
⚙️Değişkenler:polypropylene · nanocomposite · titan dioxide

Abstract

Polymers reinforced with nano metal oxides open up new pathways for engineering flexible composites that exhibit better mechanical and chemical properties. In this study, tensile properties of the polypropylene (PP) composites filled with nano titan dioxide (TiO2) and zinc oxide (ZnO) were investigated. Nano particles were coated with maleic anhydride grafted styrene ethylene butylene styrene (SEBS-g-MA) and silane, respectively prior melt mixing for better surface adhesion and fine dispersion. Nano composites were obtained by using twin screw extruder at TiO2 and ZnO loading of 1%, 3% and 5%. Firstly, thermal analysis was done to obtain melt temperature, crystallization temperature and degree of crystallinity. Then, tensile test was applied to obtain yield strength, tensile strength, elastic modulus and elongation of the composites. Due to the stiff structure of the metal oxides, all tensile properties except elongation were increased. On the other hand, although TiO2 has higher hardness than ZnO, the elongation of the composites with TiO2 was higher than that of with ZnO. This is probably due to the better compatibility of TiO2 with SEBS-g-MA and this case induced more fine structure of TiO2 with PP while ZnO particles agglomerated in some regions of the matrix which confirms the results of lower elongation and degree of crystallization

🔖

Bu Makaleye Atıf Yap

Altan, M., Yildirim, H., Uysal, A. (2016). TENSILE PROPERTIES OF POLYPROPYLENE/METAL OXIDE NANO COMPOSITES. TOJSAT, Volume: 1 Issue: 1. https://ajindex.com/articles/1660427

📄 Tam Metin PDF Okuyucu

📄

PDF görüntüleyici hazırlanıyor...

Kaynakça (20)

  1. Bahloul, W., Legare, V., David, L., & Cassagnau, P. (2010). Morphology and viscoleasticity of PP/TiO2 nanocomposites prepared by in situ sol-gel method. Journal of Polymer Science: Part B: Polymer Physics, 48, 1213-1222.
  2. Bao, S. P., & Tjong, S. C. (2007). Impact essential work of fracture of polypropylene/montmorillonite nano composites toughened with SEBS-g-MA elastomer, Composites: Part A, 38(3), 78-387.
  3. Breiner, J. M., & Mark, J. E. (1998). Preparation, structure, growth mechanisms and properties of siloxane composites containing silica, titania or mixed silica-titania phases. Polymer, 39, 5486-5493.
  4. Chan, C. M., Wu, J. S., Li, J. X., & Cheung, Y. K. (2002). Polypropylene/calcium carbonate nanocomposites. Polymer, 43, 2981-2992.
  5. Chandramoulesswaran, S., Mhaske, S. T., & Kathe, A. A. (2007). Functional behaviour of polypropylene/ZnO soluble starch nanocomposites. NanoTechnology, 18(38).
  6. Fuad, M. Y. A., Ismail, Z., Ishak, Z., & Omar, A. K. M. (1995). Application of rice husk ash as fillers in polypropylene: effect of titanate, zirconate and silane coupling agents. European Polymer Journal, 31, 885- 893.
  7. Garcia, M., Vliet, G. V., Jain, S., Schrauwen, B. A. G., Sarkissov, A., & Boukamp, B. (2004).
  8. Polypropylene/SiO2 nano composites with improved mechanical properties. Reviews on Advanced Materials Science, 6, 169-175.
  9. Ishak Mohd, Z. A., Chow, W. S., & Rochmadi, T. T. (2008). Compatibilizing effect of SEBS-g-MA on the mechanical properties of different types of OMMT filled polyamide 6/polypropylene composites. Composites: Part A, 39, 1802-1814.
  10. Kruenate, J., Tongpool, R., & Panyathanmaporn, T. (2004). Optical and mechanical properties of polypropylene modified by metal oxides. Surface and Interface Analysis, 36, 1044-1047.
  11. Li, Y., Wei, G. X., & Sue, H. J. (2002). Morphology and toughening mechanisms in clay-modified styrenebutadiene-styrene rubber-toughened polypropylene. Journal of Materials Science, 37(12), 2447-2459.
  12. Ma, J., Zhang, S., Qi, Z., Li, G., & Hu, Y. (2002). Crystallization behaviors of polypropylene/montmorillonite nanocomposites. Journal of Applied Polymer Science, 83, 1978-1985.
  13. McCarthy, D. W., & Mark, J. E. (1998). Synthesis, structure, and properties of hybrid organic-inorganic composites based on polysiloxanes. II. Comparisons between poly (methylphenylsiloxane) and poly (dimethylsiloxane), and between titania and silica. Journal of Polymer Science, Part B: Polymer Physics, 36(7), 1191-1200.
  14. Rong, M. Z., Zhang, M. Q., Zheng, Y. X., Zeng, H. M., & Friedrich, K. (2001). Improvement of tensile properties of nano-SiO2/PP composites in relation to percolation mechanism. Polymer, 42(7), 3301-3304.
  15. ] Scheirs, J. (2000). Compositional and failure analysis of polymers. England: John Wiley&Sons Chapter 5.
  16. Setz, S., Stricker, F., Kressler, J., Duscher, T., & Mulhaupt, P. (1996). Morphology and mechanical properties of blends of isotactic or syndioatactic polyropylene with SEBS block copolymers. Journal of Applied Polymer Science, 59, 1117-1128.
  17. Wang, Z., Wang, X., & Zhang, Z. (2009). Nucleating activation and asherical crystals morphology of LLDPE/LDPE/TiO2 nano composites prepared by non-isothermal crystallization. Journal of Dispersion Science and Technology, 30, 1231-1236.
  18. Zebarjad, S. M., Sajjadi, S. A., Tahani, M., & Lazzeri, A. (2006). A study on thermal behaviour of HDPE/CaCO3 nano composites. Journal of Achievements in Materials and Manufacturing Engineering, 17(1-2), 173-176.
  19. TOJSAT: The Online Journal of Science and Technology - January 2011, Volume 1, Issue 1 Copyri
  20. TOJSAT: The Online Journal of Science and Technology - January 2011, Volume 1, Issue 1 Copyri