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Dergiler / Marine and Life Sciences / 2025 / Cilt: 7 Sayı: 2

Su Arıtımı İçin Deniz Kaynaklı Adsorpsiyon Biyomalzemeleri: Fonksiyonel Balık Kemiği Adsorbanları Kullanılarak Tekstil Boyası Gideriminin Verimliliği ve Kinetiği

Marine-derived adsorption biomaterials for water treatment: Efficiency and kinetics of textile dye removal using functionalized fish bone adsorbents

Bayram Kızılkaya(ÇANAKKALE ONSEKİZ MART ÜNİVERSİTESİ, DENİZ BİLİMLERİ VE TEKNOLOJİSİ FAKÜLTESİ, DENİZ BİLİMLERİ BÖLÜMÜ, DENİZ BİLİMLERİ ANABİLİM DALI)0000-0002-3916-3734
Sayfa
46–55
Yayın Tarihi
2025-12-30
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Elde edilen sonuçlar, başlangıç konsantrasyonunun artmasıyla birlikte adsorpsiyon kapasitesinde (0.08–0.94 mg/g) belirgin bir artış gözlemlenirken, kinetik analizler, adsorpsiyon sürecinin Pseudo-second-order kinetik modele yüksek derecede uyum sağladığını ve kimyasal etkileşimlerin adsorpsiyonda baskın bir mekanizma olabileceğini göstermiştir.

📌 3 Maddede Bu Makale

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Amaç & Hipotez:Bu çalışma, endüstriyel atık sularda yaygın olarak bulunan toksik boyar maddelerin gideriminde düşük maliyetli, çevre dostu ve biyolojik kökenli bir adsorban alternatifi sunmaktadır.
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Temel Bulgular & Veri:Balık kemiği gibi atıkların modifikasyonu, sürdürülebilir kaynak kullanımına katkı sağlarken, tekstil, gıda ve kimya endüstrilerinden kaynaklanan boyar madde kirliliğinin azaltılmasında etkin sonuçlar vermektedir.
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Sonuç & Katkı:Elde edilen sonuçlar, başlangıç konsantrasyonunun artmasıyla birlikte adsorpsiyon kapasitesinde (0.08–0.94 mg/g) belirgin bir artış gözlemlenirken, kinetik analizler, adsorpsiyon sürecinin Pseudo-second-order kinetik modele yüksek derecede uyum sağladığını ve kimyasal etkileşimlerin adsorpsiyonda baskın bir mekanizma olabileceğini göstermiştir.
🔬Tür:Laboratuvar & Saha Deneyi
📍Kapsam:Genişletilmiş Akademik Örneklem
⚙️Değişkenler:Balık kılçığı · yüzey modifikasyonu · fuksin

Özet

Bu çalışma, endüstriyel atık sularda yaygın olarak bulunan toksik boyar maddelerin gideriminde düşük maliyetli, çevre dostu ve biyolojik kökenli bir adsorban alternatifi sunmaktadır. Balık kemiği gibi atıkların modifikasyonu, sürdürülebilir kaynak kullanımına katkı sağlarken, tekstil, gıda ve kimya endüstrilerinden kaynaklanan boyar madde kirliliğinin azaltılmasında etkin sonuçlar vermektedir. Kinetik ve difüzyon modelleriyle desteklenen adsorpsiyon mekanizması analizleri, bu tür malzemelerin tasarım ve optimizasyonu için önemli veriler sağlamaktadır. Balık kemiği partiküllerinin yüzey modifikasyonu iki aşamalı olarak gerçekleştirilmiş; ilk aşamada, kemik partikülleri (H) 3-aminopropil-trietoksisilan (S) ile silanizasyon işlemi uygulanarak HS ürünü elde edilmiş, ikinci aşamada ise aldehit (2-Ethyl-2H-pyrazole-3-carbaldehyde, A) fonksiyonel grubunun yüzeye bağlanmasıyla HSA formu oluşturulmuştur. Adsorpsiyon deneyleri, farklı başlangıç konsantrasyonlarında (6.76, 3.38, 1.69 ve 0.676 mg/L) fuksin çözeltisi kullanılarak yürütülmüş ve adsorpsiyon kapasitesi (q_e), giderim verimi (%) ile kinetik parametreler detaylı olarak değerlendirilmiştir. Elde edilen sonuçlar, başlangıç konsantrasyonunun artmasıyla birlikte adsorpsiyon kapasitesinde (0.08–0.94 mg/g) belirgin bir artış gözlemlenirken, kinetik analizler, adsorpsiyon sürecinin Pseudo-second-order kinetik modele yüksek derecede uyum sağladığını ve kimyasal etkileşimlerin adsorpsiyonda baskın bir mekanizma olabileceğini göstermiştir.

Abstract

This study provides a low-cost, environmentally friendly, and biologically derived adsorbent alternative for the removal of toxic dyes commonly found in industrial wastewater. The modification of waste materials such as fish bones contributes to sustainable resource utilization while achieving effective results in reducing dye pollution originating from the textile, food, and chemical industries. The adsorption mechanism was investigated by kinetic and diffusion models; they provide important data for the design and optimization of such materials. The surface of fish bone particles was modified in two steps. Firstly, the particles (H) were silanized with 3-aminopropyltriethoxysilane (S). In the second step, modification was made by shift base reaction between the amine on the surface and 2-Ethyl-2H-pyrazole-3-carbaldehyde (A). Adsorption experiments were conducted using fuchsine solution at different initial concentrations (6.76, 3.38, 1.69, and 0.676 mg/L) and adsorption capacity (qₑ), removal efficiency (%), and kinetic parameters were comprehensively investigated. The results showed a noticeable increase in adsorption capacity (0.08–0.94 mg/g) with increasing initial concentration, while kinetic analyses indicated that the adsorption process followed the pseudo-second-order kinetic model with a high degree of correlation, suggesting that chemical interactions may play a dominant role in the adsorption mechanism.

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Bu Makaleye Atıf Yap

Kızılkaya, B. (2025). Su Arıtımı İçin Deniz Kaynaklı Adsorpsiyon Biyomalzemeleri: Fonksiyonel Balık Kemiği Adsorbanları Kullanılarak Tekstil Boyası Gideriminin Verimliliği ve Kinetiği. Marine and Life Sciences, Cilt: 7 Sayı: 2, 46–55. https://doi.org/10.51756/marlife.1745123

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