The primary and secondary alcohols were oxidized to their corresponding aldehydes and ketones under solvent-free conditions at room temperature and MW irradiation in high to excellent yields.
📌 3 Maddede Bu Makale
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Amaç & Hipotez:The economic synthesis of quinaldinium chlorochromate(VI), C 10 H 9 NH[CrO 3 Cl], (QnCC) was performed by using a 1:1:1 stoichiometric amounts of CrO 3 , HCl (aq) and quinaldine.
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Temel Bulgular & Veri:QnCC was isolated in 99% yield as an orange crystalline solid and characterized with FT-IR, 1 H-NMR, and 13 C-NMR.
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Sonuç & Katkı:The primary and secondary alcohols were oxidized to their corresponding aldehydes and ketones under solvent-free conditions at room temperature and MW irradiation in high to excellent yields.
The economic synthesis of quinaldinium chlorochromate(VI), C 10 H 9 NH[CrO 3 Cl], (QnCC) was performed by using a 1:1:1 stoichiometric amounts of CrO 3 , HCl (aq) and quinaldine. QnCC was isolated in 99% yield as an orange crystalline solid and characterized with FT-IR, 1 H-NMR, and 13 C-NMR. An efficient, selective, and environmentally friendly oxidation of alcohols with 1.1 equiv. periodic acid (H 5 IO 6 ) catalyzed by QnCC (2 mol%) is described. The primary and secondary alcohols were oxidized to their corresponding aldehydes and ketones under solvent-free conditions at room temperature and MW irradiation in high to excellent yields.
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