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Dergiler / Journal of the Turkish Chemical Society Section A: Chemistry / 2026 / Volume: 7 Issue: 1

pH effect on hydrothermal synthesis of the coordination polymers containing pyrazine-2,3-dicarboxylate: Investigation of thermal stability, luminescence and electrical conductivity properties

Burak Ay(ÇUKUROVA UNIVERSITY SCIENCE AND ARTS FACULTY CHEMISTRY DEPARTMENT)0000-0001-7055-8139
Emel Yıldız(ÇUKUROVA UNIVERSITY SCIENCE AND ARTS FACULTY CHEMISTRY DEPARTMENT)0000-0002-3169-491X
Jon Zubieta(Syracuse University)0000-0003-2478-7867
Sayfa
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Yayın Tarihi
2020-02-15
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Their thermal stability, luminescence and electrical conductivity properties were investigated in the solid state.

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Amaç & Hipotez:Hydrothermal reactions of lanthanide(III) salt with 2,3-pyrazinedicarboxylic (2,3-pzdc) acid yielded the coordination polymers [La 2 (2,3-pzdc) 3 (H 2 O)] n .3nH 2 O (1) and [La 2 (2,3-pzdc) 3 (H 2 O)] n .2nH 2 O (2) .
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Temel Bulgular & Veri:Compounds were obtained in a three dimensional form with different pH values under subcritical water conditions.
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Sonuç & Katkı:Their thermal stability, luminescence and electrical conductivity properties were investigated in the solid state.
🔬Tür:Research Article
📍Kapsam:Genişletilmiş Akademik Örneklem
⚙️Değişkenler:pH effect · hydrothermal synthesis · lanthanum coordination polymer

Abstract

Hydrothermal reactions of lanthanide(III) salt with 2,3-pyrazinedicarboxylic (2,3-pzdc) acid yielded the coordination polymers [La 2 (2,3-pzdc) 3 (H 2 O)] n .3nH 2 O (1) and [La 2 (2,3-pzdc) 3 (H 2 O)] n .2nH 2 O (2) . Compounds were obtained in a three dimensional form with different pH values under subcritical water conditions. The structures had variable coordination numbers . In addition, pH values play an important role in the structural chemistry of these materials. Different characterization techniques (Elemental analysis, FT-IR, ICP-OES, TG/DTA, FESEM, PXRD, BET and single crystal X-ray) were carried out to confirm crystallinity, porosity, purity and chemical composition of the coordination polymers. Crystal structures of the polymers were examined in detail. Their thermal stability, luminescence and electrical conductivity properties were investigated in the solid state.

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Bu Makaleye Atıf Yap

Ay, B., Yıldız, E., Zubieta, J. (2020). pH effect on hydrothermal synthesis of the coordination polymers containing pyrazine-2,3-dicarboxylate: Investigation of thermal stability, luminescence and electrical conductivity properties. Journal of the Turkish Chemical Society Section A: Chemistry, Volume: 7 Issue: 1. https://doi.org/10.18596/jotcsa.565700

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