Dergiler / Bilge International Journal of Science and Technology Research / 2026 / Cilt: 10 Sayı: 2

Aloe Vera Ekstraktı Varlığında Hidrotermal Sentez Yöntemiyle Metilen Mavisi Boyasının Fotokatalitik Bozunması İçin CuO Nanoparçacıklarının Üretimi

Aloe Vera Extract-Assisted Hydrothermal Synthesis of CuO Nanoparticles for Photocatalytic Degradation of Methylene Blue Dye

Aleyna Akıllı(KONYA TEKNİK ÜNİVERSİTESİ)0000-0002-0490-4272
Ayşenur Özler(KONYA TEKNİK ÜNİVERSİTESİ)
Bircan Haspulat Taymaz(KONYA TEKNİK ÜNİVERSİTESİ)0000-0002-5170-322X
Handan Kamış(KONYA TECHNICAL UNIVERSITY)0000-0003-4133-7091
Sayfa
306–327
Yayın Tarihi
2026-10-14
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⚡ TL;DR(1 Cümlede Hızlı Çıkarım)

Bu çevre dostu sentez süreci, sağlıkla ilgili uygulamalar için CuO nanopartiküllerinin büyük ölçekli ticari üretimi için uygun fiyatlı ve kullanımı kolaydır.

📌 3 Maddede Bu Makale

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Amaç & Hipotez:Farklı bitki özütleri ile desteklenen hidrotermal sentez, sürdürülebilir teknolojik üretim için geleneksel yaklaşımlara çevre dostu bir alternatif sunmaktadır.
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Temel Bulgular & Veri:Fotokatalitik aktivite verimliliğini etkileyen sentez faktörleri incelenmiş ve en iyi koşullar belirlenmiştir.
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Sonuç & Katkı:Bu çevre dostu sentez süreci, sağlıkla ilgili uygulamalar için CuO nanopartiküllerinin büyük ölçekli ticari üretimi için uygun fiyatlı ve kullanımı kolaydır.
🔬Tür:Uygulamalı Anket & Alan Araştırması
📍Kapsam:Genişletilmiş Akademik Örneklem
⚙️Değişkenler:Aloe vera özü · CuO nanopartikülleri · yeşil sentez

Özet

Farklı bitki özütleri ile desteklenen hidrotermal sentez, sürdürülebilir teknolojik üretim için geleneksel yaklaşımlara çevre dostu bir alternatif sunmaktadır. Araştırmamız, Aloe Vera özütünden üretilen bakır oksit nanopartiküllerini (CuO NP'ler) sunarak bu çevreye faydalı alanı incelemektedir. Bu çalışma, sentez parametrelerini ve işletme parametrelerini kapsamlı bir şekilde inceleyerek CuO NP'lerin ekonomik ve çevre dostu yeşil sentezine katkıda bulunmaktadır. Model boya olarak metilen mavisi (MB) kullanılarak, elde edilen nanopartiküllerin fotokatalitik özellikleri incelenmiştir. Fotokatalitik aktivite verimliliğini etkileyen sentez faktörleri incelenmiş ve en iyi koşullar belirlenmiştir. Optimal koşullar altında geliştirilen CuO fotokatalizörü kullanıldığında, 90 dakikalık reaksiyon süresi için MB boyasının bozunma verimliliği karanlıkta %18,39, UV'de %98,53 ve görünür ışıkta %83,46 olmuştur. Daha sonra katalizör miktarı, boya konsantrasyonu ve tekrar kullanılabilirliğin işletme parametreleri üzerindeki etkisi araştırılmıştır. Bu çevre dostu sentez süreci, sağlıkla ilgili uygulamalar için CuO nanopartiküllerinin büyük ölçekli ticari üretimi için uygun fiyatlı ve kullanımı kolaydır.

Abstract

Different plant extract-assisted hydrothermal synthesis offers an eco-friendly alternative to traditional approaches for sustainable technological production. Our research explores this environmentally beneficial terrain by presenting copper oxide nanoparticles (CuO NPs) created from Aloe Vera extract. This study contributes to the economical and environmentally friendly green synthesis of CuO NPs by thoroughly investigating synthesis parameters and operating parameters. Using methylene blue (MB) as a model dye, the photocatalytic characteristics of the resulting nanoparticles were examined. The synthesis factors influencing photocatalytic activity efficiency were examined, and the best circumstances were established. When the CuO photocatalyst developed under optimal conditions was used, the degradation efficiency of MB dye was 18.39%, 98.53%, and 83.46% for dark, UV, and visible light, respectively for 90 min reaction time. The influence of catalyst quantity, dye concentration, and reusability on operational parameters was then investigated. This environmentally friendly synthesis process is affordable and simple to utilize for commercial production of CuO NP on a large scale for applications connected to health.

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Bu Makaleye Atıf Yap

Akıllı, A., Yaman, R. T., Özler, A., Taymaz, B. H., Kamış, H. (2026). Aloe Vera Ekstraktı Varlığında Hidrotermal Sentez Yöntemiyle Metilen Mavisi Boyasının Fotokatalitik Bozunması İçin CuO Nanoparçacıklarının Üretimi. Bilge International Journal of Science and Technology Research, Cilt: 10 Sayı: 2, 306–327. https://doi.org/10.30516/bilgesci.1925330

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Kaynakça (37)

  1. Ahmaruzzaman, M. (2022). Ecofriendly biosynthetic route for production of Cu nanoparticles and evaluation of their photocatalytic activities for degradation of organic compounds. Journal of the Iranian Chemical Society, 19(2), 645–654. https://doi.org/10.1007/s13738-021-02325-6
  2. Alhalili, Z. (2022). Green synthesis of copper oxide nanoparticles CuO NPs from Eucalyptus Globulus leaf extract: Adsorption and design of experiments. Arabian Journal of Chemistry, 15(5), 103739. https://doi.org/10.1016/j.arabjc.2022.103739
  3. Ali, S. G., Haseen, U., Jalal, M., Khan, R. A., Alsalme, A., Ahmad, H., & Khan, H. M. (2023). Green Synthesis of Copper Oxide Nanoparticles from the Leaves of Aegle marmelos and Their Antimicrobial Activity and Photocatalytic Activities. Molecules, 28(22), 7499. https://doi.org/10.3390/molecules28227499
  4. Aminuzzaman, M., Kei, L. M., & Liang, W. H. (2017). Green synthesis of copper oxide (CuO) nanoparticles using banana peel extract and their photocatalytic activities. AIP Conference Proceedings, 1828, 020016. https://doi.org/10.1063/1.4979387
  5. Assaouka, H. T., Daawe, D. M., Fomekong, R. L., Nsangou, I. N., & Kouotou, P. M. (2022). Inexpensive and easily replicable precipitation of CuO nanoparticles for low temperature carbon monoxide and toluene catalytic oxidation. Heliyon, 8(9), e10689. https://doi.org/10.1016/j.heliyon.2022.e10689
  6. Beheshtkhoo, N., Kouhbanani, M. A. J., Savardashtaki, A., Amani, A. M., & Taghizadeh, S. (2018). Green synthesis of iron oxide nanoparticles by aqueous leaf extract of Daphne mezereum as a novel dye removing material. Applied Physics A: Materials Science and Processing, 124(5), 363. https://doi.org/10.1007/s00339-018-1782-3
  7. de Moraes, N. P., Silva, F. N., da Silva, M. L. C. P., Campos, T. M. B., Thim, G. P., & Rodrigues, L. A. (2018). Methylene blue photodegradation employing hexagonal prism-shaped niobium oxide as heterogeneous catalyst: Effect of catalyst dosage, dye concentration, and radiation source. Materials Chemistry and Physics, 214, 95–106. https://doi.org/10.1016/j.matchemphys.2018.04.063
  8. Dharmraj Khairnar, S., Patil, R., & Shrivastava, V. S. (2018). Hydrothermally synthesized nanocrystalline Nb2O5 and its visible-light photocatalytic activity for the degradation of congo red and methylene blue. Iranian Journal of Catalysis, 8(2), 143–150.
  9. Gnanavel, V., Palanichamy, V., & Roopan, S. M. (2017). Biosynthesis and characterization of copper oxide nanoparticles and its anticancer activity on human colon cancer cell lines (HCT-116). Journal of Photochemistry and Photobiology B: Biology, 171, 133–138. https://doi.org/10.1016/j.jphotobiol.2017.05.001
  10. Gunalan, S., Sivaraj, R., & Venckatesh, R. (2012). Aloe barbadensis Miller mediated green synthesis of mono-disperse copper oxide nanoparticles: Optical properties. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 97, 1140–1144. https://doi.org/10.1016/j.saa.2012.07.096
  11. Halder, M., Islam, M. M., Ansari, Z., Ahammed, S., Sen, K., & Islam, S. M. (2017). Biogenic Nano-CuO-Catalyzed Facile C-N Cross-Coupling Reactions: Scope and Mechanism. ACS Sustainable Chemistry and Engineering, 5(1), 648–657. https://doi.org/10.1021/acssuschemeng.6b02013
  12. Hanafi, M. F., & Sapawe, N. (2020). Effect of initial concentration on the photocatalytic degradation of remazol brilliant blue dye using nickel catalyst. Materials Today: Proceedings, 31, 318–320. https://doi.org/10.1016/j.matpr.2020.06.066
  13. Jabeen, S., Siddiqui, V. U., Bala, S., Mishra, N., Mishra, A., Lawrence, R., Bansal, P., Khan, A. R., & Khan, T. (2024). Biogenic Synthesis of Copper Oxide Nanoparticles from Aloe vera: Antibacterial Activity, Molecular Docking, and Photocatalytic Dye Degradation. ACS Omega, 9(28), 30190–30204. https://doi.org/10.1021/acsomega.3c10179
  14. Jin, R., Easa, J., & O’Brien, C. P. (2021). Highly Active CuOx/SiO2 dot Core/Rod Shell Catalysts with Enhanced Stability for the Reverse Water Gas Shift Reaction. ACS Applied Materials and Interfaces, 13(32), 38213–38220. https://doi.org/10.1021/acsami.1c06979
  15. Khan, M. A., Nayan, N., Shadiullah, Ahmad, M. K., & Soon, C. F. (2020). Surface study of CuO nanopetals by advanced nanocharacterization techniques with enhanced optical and catalytic properties. Nanomaterials, 10(7), 1–18. https://doi.org/10.3390/nano10071298
  16. Kitadai, N., Sawai, T., Tonoue, R., Nakashima, S., Katsura, M., & Fukushi, K. (2014). Effects of ions on the OH stretching band of water as revealed by ATR-IR spectroscopy. Journal of Solution Chemistry, 43(6), 1055–1077. https://doi.org/10.1007/s10953-014-0193-0
  17. Kumar, P. P. N. V., Shameem, U., Kollu, P., Kalyani, R. L., & Pammi, S. V. N. (2015). Green Synthesis of Copper Oxide Nanoparticles Using Aloe vera Leaf Extract and Its Antibacterial Activity Against Fish Bacterial Pathogens. BioNanoScience, 5(3), 135–139. https://doi.org/10.1007/s12668-015-0171-z
  18. Labanni, A., Nasir, M., & Arief, S. (2023). Research progress and prospect of copper oxide nanoparticles with controllable nanostructure, morphology, and function via green synthesis. Materials Today Sustainability, 24, 100526. https://doi.org/10.1016/j.mtsust.2023.100526
  19. Md Ishak, N. A. I., Kamarudin, S. K., & Timmiati, S. N. (2019). Green synthesis of metal and metal oxide nanoparticles via plant extracts: an overview. Materials Research Express, 6(11), 112004. https://doi.org/10.1088/2053-1591/ab4458
  20. Mohagheghian, A., Karimi, S. A., Yang, J. K., & Shirzad-Siboni, M. (2015). Photocatalytic degradation of a textile dye by illuminated tungsten oxide nanopowder. Journal of Advanced Oxidation Technologies, 18(1), 61–68. https://doi.org/10.1515/jaots-2015-0108
  21. Mouele, E. S. M., Dinu, M., Cummings, F., Fatoba, O. O., Myint, M. T. Z., Kyaw, H. H., Parau, A. C., Vladescu, A., Francesconi, M. G., Pescetelli, S., Di Carlo, A., Agresti, A., Al-Abri, M., Dobretsov, S., Braic, M., & Petrik, L. F. (2020). Effect of calcination time on the physicochemical properties and photocatalytic performance of carbon and nitrogen co-doped TiO2 nanoparticles. Catalysts, 10(8), 847. https://doi.org/10.3390/catal10080847
  22. Naika, H. R., Lingaraju, K., Manjunath, K., Kumar, D., Nagaraju, G., Suresh, D., & Nagabhushana, H. (2015). Green synthesis of CuO nanoparticles using Gloriosa superba L. extract and their antibacterial activity. Journal of Taibah University for Science, 9(1), 7–12. https://doi.org/10.1016/j.jtusci.2014.04.006
  23. Nalimu, F., Oloro, J., Kahwa, I., & Ogwang, P. E. (2021). Review on the phytochemistry and toxicological profiles of Aloe vera and Aloe ferox. Future Journal of Pharmaceutical Sciences, 7(1), 145. https://doi.org/10.1186/s43094-021-00296-2
  24. Narasaiah, P., Mandal, B. K., & Sarada, N. C. (2017). Biosynthesis of Copper Oxide nanoparticles from Drypetes sepiaria Leaf extract and their catalytic activity to dye degradation. IOP Conference Series: Materials Science and Engineering, 263(2), 022012. https://doi.org/10.1088/1757-899X/263/2/022012
  25. Nazarath Begum, S., Esakkiraja, A., & Asan, S. M. (2019). Green synthesis, characterization and antibacterial activity of copper oxide nanoparticles synthesized using Catharanthus roseus leaf extract. Journal of Applied Science and Computations, 6, 3228.
  26. Nzilu, D. M., Madivoli, E. S., Makhanu, D. S., Wanakai, S. I., Kiprono, G. K., & Kareru, P. G. (2023). Green synthesis of copper oxide nanoparticles and its efficiency in degradation of rifampicin antibiotic. Scientific Reports, 13(1), 14030. https://doi.org/10.1038/s41598-023-41119-z
  27. Palani, M., Kalaiselvan, S., Martin Mark, J. A., Chandran, K., & Ekhambaram, V. (2024). Green synthesis of CuO nanoparticles: A promising role of antioxidant and antimicrobial activity by using Tribulus terrestris L. Aspects of Molecular Medicine, 4, 100049. https://doi.org/10.1016/j.amolm.2024.100049
  28. Parekh, Z. R., Chaki, S. H., Hirpara, A. B., Patel, G. H., Kannaujiya, R. M., Khimani, A. J., & Deshpande, M. P. (2021). CuO nanoparticles – Synthesis by wet precipitation technique and its characterization. Physica B: Condensed Matter, 610, 412950. https://doi.org/10.1016/j.physb.2021.412950
  29. Qamar, H., Rehman, S., Chauhan, D. K., Tiwari, A. K., & Upmanyu, V. (2020). Green synthesis, characterization and antimicrobial activity of copper oxide nanomaterial derived from Momordica charantia. International Journal of Nanomedicine, 15, 2541–2553. https://doi.org/10.2147/IJN.S240232
  30. Rani, R., Kumar Rana, R., Khokhar, S., & Dangi, D. (2022). Synthesis of copper oxide nanoparticles by co-precipitation method using different concentrations of precursor at different pH values. NeuroQuantology, 20, 2369–2373. https://doi.org/10.14704/nq.2022.20.9.NQ44277
  31. Roškarič, M., Žerjav, G., Finšgar, M., Zavašnik, J., & Pintar, A. (2023). Influence of the calcination duration of g-C3N4/TiO2 “veggie-toast-like” photocatalyst on the visible-light triggered photocatalytic oxidation of bisphenol A. Journal of Alloys and Compounds, 947, 169575. https://doi.org/10.1016/j.jallcom.2023. 169585.
  32. Saruchi, Thakur, P., & Kumar, V. (2019). Kinetics and thermodynamic studies for removal of methylene blue dye by biosynthesize copper oxide nanoparticles and its antibacterial activity. Journal of Environmental Health Science and Engineering, 17(1), 367–376. https://doi.org/10.1007/s40201-019-00354-1
  33. Siddique, M., Khan, R., Farooq, R., & Khan, A. F. (2014). Improved photocatalytic activity of TiO2 coupling ultrasound for Reactive Blue 19 degradation. Journal of the Chemical Society of Pakistan, 36(1), 37–42.
  34. Uma, B., Anantharaju, K. S., Renuka, L., Malini, S., More, S. S., Vidya, Y. S., & Meena, S. (2021). Synthesis of CuO samples by co-precipitation and green mediated combustion routes: Comparison of their structural, optical properties, photocatalytic, antibacterial, haemolytic and cytotoxic activities. Ceramics International, 47(7), 10355–10369. https://doi.org/10.1016/j.ceramint.2020.10.223
  35. Vishveshvar, K., Aravind Krishnan, M. V., Haribabu, K., & Vishnuprasad, S. (2018). Green Synthesis of Copper Oxide Nanoparticles Using Ixora coccinea Plant Leaves and its Characterization. BioNanoScience, 8(2), 554–558. https://doi.org/10.1007/s12668-018-0508-5
  36. Zheng, X., Lian, Q., Zhou, L., Jiang, Y., & Gao, J. (2021). Peroxidase Mimicking of Binary Polyacrylonitrile-CuO Nanoflowers and the Application in Colorimetric Detection of H2O2 and Ascorbic Acid. ACS Sustainable Chemistry and Engineering, 9(20), 7030–7043. https://doi.org/10.1021/acssuschemeng.1c00723
  37. Zhou, X., Alotaibi, F. M., Kamal, M. S., & Kokal, S. L. (2020). Effect of Conformance Control Patterns and Size of the Slug of in Situ Supercritical CO2 emulsion on Tertiary Oil Recovery by Supercritical CO2 miscible Injection for Carbonate Reservoirs. ACS Omega, 5(51), 33395–33405. https://doi.org/10.1021/acsomega.0c05356