Dergiler / Journal of the Turkish Chemical Society Section B: Chemical Engineering / 2026 / Volume: 8 Issue: 1

Novel Solid Contact Ion Selective Sensor for Potentiometric Analysis of Barium Ions

Oğuz Özbek(TOKAT GAZIOSMANPASA UNIVERSITY)0000-0001-5185-9681
Onur Cem Altunoluk(TOKAT GAZİOSMANPAŞA ÜNİVERSİTESİ)0000-0003-3558-3499
Ömer Işıldak(TOKAT GAZİOSMANPAŞA ÜNİVERSİTESİ)0000-0003-4690-4323
Sayfa
—
Yayın Tarihi
2025-03-11
🏛️Bu makalenin bibliyografik verileri ve tam metin bağlantısı DergiPark üzerinden sağlanmıştır.
DergiPark Kaydı ↗
✨

Yapay Zeka Hızlı Bakış & Çıkarımlar

AI Insight
⚡ TL;DR(1 Cümlede Hızlı Çıkarım)

The sensors prepared simply and economically were able to determine barium ions in various samples with very high recoveries.

📌 3 Maddede Bu Makale

🎯
Amaç & Hipotez:Barium as an alkaline earth metal is widely used in multiple industries.
📊
Temel Bulgular & Veri:In this study, polymer membrane barium–selective potentiometric sensors were prepared in which 4-aminobenzoic acid 2-diethylaminoethyl ester was used as an ionophore.
💡
Sonuç & Katkı:The sensors prepared simply and economically were able to determine barium ions in various samples with very high recoveries.
🔬Tür:Research Article
📍Kapsam:Genişletilmiş Akademik Örneklem
⚙️Değişkenler:Barium(II) · sensor · potentiometry

Abstract

Barium as an alkaline earth metal is widely used in multiple industries. Due to its widespread use, it is toxic to living things in high concentrations. In this study, polymer membrane barium–selective potentiometric sensors were prepared in which 4-aminobenzoic acid 2-diethylaminoethyl ester was used as an ionophore. The prepared sensors exhibited selective and stable behavior towards barium ions. The novel barium–selective potentiometric sensor had a low detection limit of 4.23×10-6 M over a wide linear concentration range from 1.0×10-5 to 1.0×10-1 M. The sensor proposed in the present study had good repeatability, short response time (8s) and could work over a wide range of pH. The sensors prepared simply and economically were able to determine barium ions in various samples with very high recoveries.

🔖

Bu Makaleye Atıf Yap

Özbek, O., Altunoluk, O. C., Işıldak, Ö. (2025). Novel Solid Contact Ion Selective Sensor for Potentiometric Analysis of Barium Ions. Journal of the Turkish Chemical Society Section B: Chemical Engineering, Volume: 8 Issue: 1. https://doi.org/10.58692/jotcsb.1536261

📄 Tam Metin PDF Okuyucu

📄

PDF görüntüleyici hazırlanıyor...

Kaynakça (34)

  1. Abedi, M. R., & Zamani, H. A. (2008). Barium (II)-PVC membrane sensor based on 4-4′-methylenediantipyrine as a neutral carrier. Analytical Letters, 41(12), 2251-2266. https://doi.org/10.1080/00032710802238077
  2. Abu-Shawish, H. M., Ghalwa, N. A., Al-Kashef, I. D., Saadeh, S. M., & Almonem, K. I. A. (2020). Extraordinary enhancement of a 5-fluorouracil electrode by praepagen HY micellar solutions. Microchemical Journal, 152, 104316. https://doi.org/10.1016/j.microc.2019.104316
  3. Abu-Shawish, H. M., Almonem, K. I. A., Saadeh, S. M., & Al-lham, W. S. (2016). Determination of haloperidol drug in ampoules and in urine samples using a potentiometric modified carbon paste electrode. Measurement, 78, 180-186. https://doi.org/10.1016/j.measurement.2015.10.008
  4. Altunoluk, O. C., Özbek, O., Kalay, E., Tokalı, F. S., & Aslan, O. N. Surface characterization of barium (II)‐selective potentiometric sensor based on a newly synthesized derivative molecule. Electroanalysis, e202300407. https://doi.org/10.1002/elan.202300407
  5. Ardianrama, A. D., Pradyasti, A., Woo, H. C., & Kim, M. H. (2020). Colorimetric sensing of barium ion in water based on polyelectrolyte-induced chemical etching of silver nanoprisms. Dyes and Pigments, 181, 108578. https://doi.org/10.1016/j.dyepig.2020.108578
  6. Berkel, C., & Özbek, O. (2024). Green electrochemical sensors, their applications and greenness metrics used: A review. Electroanalysis, 36(11) e202400286. https://doi.org/10.1002/elan.202400286
  7. Bisergaeva, R. A., & Sirieva, Y. N. (2020, November). Determination of calcium and magnesium by atomic absorption spectroscopy and flame photometry. In Journal of Physics: Conference Series, 1691, 012055. https://doi.org/10.1088/1742-6596/1691/1/012055
  8. Buck, R. P., & Lindner, E. (1994). Recommendations for nomenclature of ion-selective electrodes. Pure and Applied Chemistry, 66(12), 2527-2536. https://doi.org/10.1351/pac199466122527
  9. de Oliveira, W., de Carvalho, M. D. F. B., de Almeida, E., Menegario, A. A., Domingos, R. N., Brossi-Garcia, A. L.,. & Santelli, R. E. (2012). Determination of labile barium in petroleum-produced formation water using paper-based DGT samplers. Talanta, 100, 425-431. https://doi.org/10.1016/j.talanta.2012.08.013
  10. Erol, S., Özel, A. D., Yilmaz, M., & Κiliç, E. (2009). New Silver Ion-selective PVC Membrane and Coated-Graphite Electrodes based on a Novel Calix|4| arene Derivative. Reviews in Analytical Chemistry, 28(1), 27-50. https://doi.org/10.1515/REVAC.2009.28.1.27
  11. Gad, S.C. (2014). Barium, Encyclopedia of Toxicology (3th Editon), 368–370. https://doi.org/10.1016/B978-0-12-386454-3.00819-8
  12. Grajeda, B. A. G., Acosta, S. G. S., Aguila, S. A., Guevara, H. P., Díaz-García, M. E., Enríquez, A. C., & Campos-Gaxiola, J. J. (2017). Selective and colorimetric detection of Ba 2+ ions in aqueous solutions using 11-mercaptoundecylphosphonic acid functionalized gold nanoparticles. RSC Advances, 7(50), 31611-31618. https://doi.org/10.1039/c7ra03861e
  13. Huelga-Suarez, G., Fernández, B., Moldovan, M., & Alonso, J. I. G. (2013). Detection of transgenerational barium dual-isotope marks in salmon otoliths by means of LA-ICP-MS. Analytical and Bioanalytical Chemistry, 405, 2901-2909. https://doi.org/10.1007/s00216-012-6452-2
  14. Isildak, Ö., & Özbek, O. (2021). Application of potentiometric sensors in real samples. Critical Reviews in Analytical Chemistry, 51(3), 218-231. https://doi.org/10.1080/10408347.2019.1711013
  15. Kravchenko, J., Darrah, T. H., Miller, R. K., Lyerly, H. K., & Vengosh, A. (2014). A review of the health impacts of barium from natural and anthropogenic exposure. Environmental geochemistry and health, 36, 797-814. https://doi.org/10.1007/s10653-014-9622-7
  16. Llugany, M., Poschenrieder, C., & Barceló, J. (2000). Assessment of barium toxicity in bush beans. Archives of Environmental Contamination and Toxicology, 39, 440-444. https://doi.org/10.1007/s002440010125
  17. Modi, R. P., Mehta, V. N., & Kailasa, S. K. (2014). Bifunctionalization of silver nanoparticles with 6-mercaptonicotinic acid and melamine for simultaneous colorimetric sensing of Cr3+ and Ba2+ ions. Sensors and Actuators B: Chemical, 195, 562-571. https://doi.org/10.1016/j.snb.2014.01.059
  18. Othman, A. M., El-Shahawi, M. S., & Abdel-Azeem, M. (2006). A novel barium polymeric membrane sensor for selective determination of barium and sulphate ions based on the complex ion associate barium (II)–Rose Bengal as neutral ionophore. Analytica Chimica Acta, 555(2), 322-328. https://doi.org/10.1016/j.aca.2005.09.016
  19. Ören, S., Özbek, O., & Isildak, Ö. (2024). The use of thiazole derivative molecules as sensor materials: Potentiometric determination of Cu (II) ions. Vietnam Journal of Chemistry, 62(4), 486-492. https://doi.org/10.1002/vjch.202300295
  20. Özbek, O., & Isildak, Ö. (2022). Potentiometric PVC membrane sensor for the determination of anti‐epileptic drug levetiracetam in pharmaceutical formulations. ChemistrySelect, 7(3), e202103988. https://doi.org/10.1002/slct.202103988
  21. Özbek, O., Çetin, A., Koç, E., & Isildak, Ö. (2022a). Synthesis and sensor properties of a phenol derivative molecule: potentiometric determination of silver (I) ions. Electrocatalysis, 13(4), 486-493.
  22. Özbek, O., Gezegen, H., Cetin, A., & Isildak, Ö. (2022b). A potentiometric sensor for the determination of Pb (II) ions in different environmental samples. ChemistrySelect, 7(33), e202202494. https://doi.org/10.1002/slct.202202494
  23. Özbek, O. (2023). A potentiometric sensor for the determination of potassium in different baby follow–on milk, water, juice and pharmaceutical samples. Journal of Food Composition and Analysis, 115, 104937. https://doi.org/10.1016/j.jfca.2022.104937
  24. Özbek, O., & Altunoluk, O. C. (2023). Recent advances in nanoparticle–based potentiometric sensors. Advanced Sensor and Energy Materials, 3, 100087. https://doi.org/10.1016/j.asems.2023.100087
  25. Özbek, O., & Altunoluk, O. C. (2024). Potentiometric determination of the local anesthetic procaine in pharmaceutical samples. Analytical Biochemistry, 695, 115657. https://doi.org/10.1016/j.ab.2024.115657
  26. Özbek, O., Ugur, Ö. B., Ören, S., Gürdere, M. B., & Kocabas, S. (2024a). New solid state contact potentiometric sensor based on a thiosemicarbazone derivative molecule for determination of copper (II) ions in environmental samples. Polyhedron, 252, 116878. https://doi.org/10.1016/j.poly.2024.116878
  27. Özbek, O., Altunoluk, O. C., & Isildak, Ö. (2024b). Surface characterization and electroanalytical applications of the newly developed copper (II)-selective potentiometric sensor. Analytical Sciences, 40(1), 141-149. https://doi.org/10.1007/s44211-023-00436-z
  28. Saleh, M. B. (2000). Neutral bidentate organophosphorus compounds as novel ionophores for potentiometric membrane sensors for barium (II). Fresenius Journal of Analytical Chemistry, 367, 530-534. https://doi.org/10.1007/s002160000374
  29. Singh, A. K., Singh, R., Singh, R. P., & Saxena, P. (2005). Novel potentiometric sensor for monitoring barium (II) based on 2, 3, 4-pyridine-1, 3, 5, 7, 12-pentaazacyclopentadeca-3-ene. Sensors and Actuators B: Chemical, 106(2), 779-783. https://doi.org/10.1016/j.snb.2004.09.030
  30. Umezawa, Y., Buhlmann, P., Umezawa, K., Tohda, K., & Amemiya, S. (2000). Potentiometric Selectivity Coefficients of Ion-Selective Electrodes. Part I. Inorganic Cations. Pure Appl. Chem, 72, 1851-2082. https://doi.org/10.1351/pac200072101851
  31. Verma, S., Sharma, A. K., & Shukla, S. K. (2023). Self-fuelled nickel oxide encapsulated sodium alginate-grafted-polypyrrole for potentiometric sensing of lead ions. Materials Science and Engineering: B, 293, 116469. https://doi.org/10.1016/j.mseb.2023.116469
  32. Wu, Y., Qileng, A., & Bakker, E. (2023). Self-powered optical ion sensor array based on potentiometric probes coupled to electronic paper. Sensors and Actuators B: Chemical, 396, 134561. https://doi.org/10.1016/j.snb.2023.134561
  33. Zamani, H. A., Hamed-Mosavian, M. T., Aminzadeh, E., Ganjali, M. R., Ghaemy, M., Behmadi, H., & Faridbod, F. (2010). Construction of barium (II) PVC membrane electrochemical sensor based on 3-deoxy-d-erythro-hexos-2-ulose bis (thiosemicarbazone) as a novel ionophore. Desalination, 250(1), 56-61. https://doi.org/10.1016/j.desal.2009.09.014
  34. de Oliveira, W., de Carvalho, M. D. F. B., de Almeida, E., Menegario, A. A., Domingos, R. N., Brossi-Garcia, A. L.,. & Santelli, R. E. (2012). Determination of labile barium in petroleum-produced formation water using paper-based DGT samplers. Talanta, 100, 425-431. https://doi.org/10.1016/j.talanta.2012.08.013