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Dergiler / Dicle Üniversitesi Fen Bilimleri Enstitüsü Dergisi / 2020 / Cilt: 9 - Sayı: 1

Catalytic activity of two Ru(II) complexes in transfer hydrogenation reaction of simple ketones

Nevin ARSLAN
Sayfa
9–16
Yayın Tarihi
2020-06-10
DOI
—
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Notably, 2 exhibits a good catalytic activity and affords the respective alcohols with good conversions up to 98 % (TOF: 392 h-1).

📌 3 Maddede Bu Makale

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Amaç & Hipotez:Öz Hydrogen transfer reduction reactions have been attracted significant attention in organic synthesis due to their operational easiness.
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Temel Bulgular & Veri:For this purpose, two Ru(II) complexes of P-N-P ligand were prepared starting from [Ru(η6-p-cymene) (μ-Cl)Cl]2.
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Sonuç & Katkı:Notably, 2 exhibits a good catalytic activity and affords the respective alcohols with good conversions up to 98 % (TOF: 392 h-1).
🔬Tür:Araştırma Makalesi
📍Kapsam:Genişletilmiş Akademik Örneklem
⚙️Değişkenler:Anahtar Kelimeler Transfer hydrogenation · Ruthenium · Catalysis

Özet

Öz Hydrogen transfer reduction reactions have been attracted significant attention in organic synthesis due to their operational easiness. For this purpose, two Ru(II) complexes of P-N-P ligand were prepared starting from [Ru(η6-p-cymene) (μ-Cl)Cl]2. Then, their catalytic activity was investigated in the transfer hydrogenation of different simple alkyl and aryl alkyl ketones to respective alcohols in the existence of isopropanol as the hydrogen source. Notably, 2 exhibits a good catalytic activity and affords the respective alcohols with good conversions up to 98 % (TOF: 392 h-1).

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Bu Makaleye Atıf Yap

ARSLAN, N. (2020). Catalytic activity of two Ru(II) complexes in transfer hydrogenation reaction of simple ketones. Dicle Üniversitesi Fen Bilimleri Enstitüsü Dergisi, Cilt: 9 - Sayı: 1, 9–16. https://ajindex.com/articles/134342

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Kaynakça (11)

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