Dergiler / Uludağ Üniversitesi Mühendislik Fakültesi Dergisi / 2026 / Cilt: 24 Sayı: 2

DOĞAL VE KALSİNE YUMURTA KABUKLARININ Cr(III) GİDERİMİNDE DEĞERLENDİRİLMESİ

Sayfa
405–418
Yayın Tarihi
2019-08-30
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⚡ TL;DR(1 Cümlede Hızlı Çıkarım)

Bu çalışma atıksularda bulunan Cr(III) iyonlarının gideriminde doğal ve kalsine tavuk yumurtası kabuklarının kullanılabileceğini göstermiştir.

📌 3 Maddede Bu Makale

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Amaç & Hipotez:Bu çalışmada Cr(III)’ün tavuk yumurtası kabuklarına adsorpsiyonu araştırılmıştır.
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Temel Bulgular & Veri:Bu amaçla kalsine edilmiş (900°C ve 3 saat) ve doğal yumurta kabukları adsorplayıcı olarak kullanılmıştır.
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Sonuç & Katkı:Bu çalışma atıksularda bulunan Cr(III) iyonlarının gideriminde doğal ve kalsine tavuk yumurtası kabuklarının kullanılabileceğini göstermiştir.
🔬Tür:Modelleme & Sayısal Simülasyon
📍Kapsam:Genişletilmiş Akademik Örneklem
⚙️Değişkenler:Tavuk yumurtası kabuğu · Cr (III) · Adsorpsiyon

Özet

Bu çalışmada Cr(III)’ün tavuk yumurtası kabuklarına adsorpsiyonu araştırılmıştır. Bu amaçla kalsine edilmiş (900°C ve 3 saat) ve doğal yumurta kabukları adsorplayıcı olarak kullanılmıştır. Yumurta kabuğu miktarı (0,6-2,0 g/L), Cr(III) derişimi (50-350 mg/L) ve sıcaklığın (25-55 °C) Cr(III) adsorpsiyonuna etkisi incelenmiştir. Kalsine edilmiş ve doğal yumurta kabukları X-ışını kırınım (XRD) cihazında analiz edilmiştir. Doğal yumurta kabukları ile Cr(III) adsorpsiyonunda 25°C’de, 50-350 mg/g Cr(III) derişimi aralığında % 100-16,6 giderim ve 38,23-46,31 mg/g giderim kapasitesi elde edilmiştir. Kalsine edilmiş yumurta kabukları ile Cr(III) giderimi çöktürmeyle gerçekleştirilmiştir. Langmuir, Freundlich ve Temkin adsorpsiyon modelleri deneysel verilere uygulanmış ve her üç modelinde uygun olduğu belirlenmiştir. Cr(III) adsorpsiyon kinetiğinin Yalancı ikinci derece kinetik ile daha iyi ifade edildiği bulunmuştur. Bu çalışma atıksularda bulunan Cr(III) iyonlarının gideriminde doğal ve kalsine tavuk yumurtası kabuklarının kullanılabileceğini göstermiştir.

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Bu Makaleye Atıf Yap

Okur, M., Ak, Ç., Tümtürk, U. (2019). DOĞAL VE KALSİNE YUMURTA KABUKLARININ Cr(III) GİDERİMİNDE DEĞERLENDİRİLMESİ. Uludağ Üniversitesi Mühendislik Fakültesi Dergisi, Cilt: 24 Sayı: 2, 405–418. https://doi.org/10.17482/uumfd.383572

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Kaynakça (41)

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  2. Chatterjee, N., Luo, Z., Malghani, S., Lian, J.J., Zheng, W.L. (2009) Uptake and distribution of chromium in Saccharomyces cerevisae exposed to Cr (III)-organic compounds, Chemical Speciation & Bioavailability, 21(4), 245-255. Doi: 10.3184/095422909X12554538843778
  3. Chojnacka, K. (2005) Biosorption of Cr (III) ions by eggshells, Journal of Hazardous Materials, 121(1), 167-173. Doi: 10.1016/j.jhazmat.2005.02.004
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  12. Mahmoud, M.S., Mohamed, S.A., (2017) Calcium alginate as an eco-friendly supporting material for Baker's yeast strain in chromium bioremediation, HBRC Journal, 13 (3), 245-254. Doi: 10.1016/j.hbrcj.2015.06.003
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  15. Park, H.J., Jeong, S.W., Yang, J.K., Kim, B.G., Lee, S.M. (2007) Removal of heavy metals using waste eggshell, Journal of Environmental Sciences, 19(12), 1436-1441. Doi: 10.1016/S1001-0742(07)60234-4
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  17. Tan, C., Zeyu, Z., Sai, X., Hongtao, W., Wenjing, L. (2015) Adsorption behavior comparison of trivalent and hexavalent chromium on biochar derived from municipial sludge, Bioresource Technology, 190, 388-394. Doi: 10.1016/j.biortech.2015.04.115
  18. Turan, P., Doğan, M., Alkan, M. (2007) Uptake of trivalent chromium ions from aqueous solutions using kaolinite, Journal of Hazardous Materials, 148, 56-63. Doi: 10.1016/j.jhazmat.2007.02.007
  19. Wang, D., He,S., Shan, C., Ye, Y., Ma, H., Zhang, X., Zhang, W., Pan, B. (2016) Chromium speciation in tannery effluent after alkaline precipitation: Isolation and characterization, Journal of Hazardous Materials, 316, 169-177. Doi: 10.1016/j.jhazmat.2016.05.021
  20. Wang, D., Ye,Y., Liu, H., Ma, H., Zhang, W. (2018) Effect of alkaline precipitation on Cr species of Cr(III)-bearing complexes typically used in the tannery industry, Chemosphere, 193, 42-49. Doi: 10.1016/j.chemosphere.2017.11.006
  21. Yang, Z.H., Xiong, S., Wang, B., Li, Q., Yang, W.C. (2013) Cr(III) adsorption by sugarcane pulp residue and biochar, Journal of Central South University, 20 (5), 1319–1325. Doi: 10.1007/s11771-013-1618-4
  22. Zou, J., Guo, C., Zhou, X., Sun, Y., Yang, Z. (2018) Sorption capacity and mechanism of Cr+3 on tobermorite derived from fly ash acid residue and carbide slag, Colloids and Surfaces A, 538, 825-833. Doi: 10.1016/j.colsurfa.2017.11.073
  23. Ali, A., Saeed, K., Mabood, F. (2016) Removal of chromium (VI) from aqueous medium using chemically modified banana peels as efficient low-cost adsorbent, Alexandria Engineering Journal, 55(3), 2933-2942. Doi: 10.1016/j.aej.2016.05.011
  24. Chatterjee, N., Luo, Z., Malghani, S., Lian, J.J., Zheng, W.L. (2009) Uptake and distribution of chromium in Saccharomyces cerevisae exposed to Cr (III)-organic compounds, Chemical Speciation & Bioavailability, 21(4), 245-255. Doi: 10.3184/095422909X12554538843778
  25. Chojnacka, K. (2005) Biosorption of Cr (III) ions by eggshells, Journal of Hazardous Materials, 121(1), 167-173. Doi: 10.1016/j.jhazmat.2005.02.004
  26. Daraei, H., Mittal, A., Noorisepehr, M., Mittal, J. (2015) Separation of chromium from water samples using eggshell powder as a low-cost sorbent: Kinetic and thermodynamic studies, Desalination and Water Treatment, 53(1), 214-220. Doi: 10.1080/19443994.2013.837011
  27. Elabbas, S., Mandi, L., Berrekhis, F., Pons, M.N., Leclerc, J.P., Ouazzani, N. (2016) Removal of Cr (III) from chrome tanning wastewater by adsorption using two natural carbonaceous materials: Eggshell and powdered marble, Journal of Environmental Management, 166, 589-595. Doi: 10.1016/j.jenvman.2015.11.012
  28. Fonseca-Correa, R., Giraldo, L., Moreno-Pirajan, J.C. (2013) Trivalent Chromium removal from aqueous solution with physically and chemical modified corncob waste, Journal of Analytical and Applied Pyrolysis, 101, 132-141. Doi: 10.1016/j.jaap.2013.01.019
  29. Juvera-Espinosa, J., Morales-Barrera, L., Cristiani-Urbina, E. (2006) Isolation and characterization of a yeast strain capable of removing Cr (VI), Enzyme and Microbial Technology, 40(1), 114-121. Doi: 10.1016/j.enzmictec.2005.10.045
  30. Long, M., Zhou, C., Xia, S., Guadiea, A. (2017) Concominant Cr(VI) reduction and Cr(III) precipitation with nitrate in a methane/oxygen-based membrane biofilm reactor, Chemical Engineering Journal, 315, 58-65. Doi: 10.1016/j.cej.2017.01.018
  31. Mahmoud, M.S., Mohamed, S.A., (2017) Calcium alginate as an eco-friendly supporting material for Baker's yeast strain in chromium bioremediation, HBRC Journal, 13 (3), 245-254. Doi: 10.1016/j.hbrcj.2015.06.003
  32. Mohan, D., Pittman Jr, C.U. (2006) Activated carbons and low cost adsorbents for remediation of tri and hexavalent chromium from water, Journal of Hazardous Materials, 137(2), 762-811. Doi: 10.1016/j.jhazmat.2006.06.060
  33. Pan, J., Jiang, J., Xu, R., (2013) Adsorption of Cr(III) from acidic solutions by crop straw derived biochars, Journal of Environmental Sciences, 25(10), 1957-1965. Doi: 10.1016/S1001-0742(12)60305-2
  34. Park, H.J., Jeong, S.W., Yang, J.K., Kim, B.G., Lee, S.M. (2007) Removal of heavy metals using waste eggshell, Journal of Environmental Sciences, 19(12), 1436-1441. Doi: 10.1016/S1001-0742(07)60234-4
  35. Rajendran, A., Mansiya, C. (2011) Extraction of Chromium from Tannery Effluents Using Waste Egg Shell Material as an Adsorbent, British Journal of Environment and Climate Change, 1(2), 44-52. Doi: 10.9734/BJECC/2011/262
  36. Tan, C., Zeyu, Z., Sai, X., Hongtao, W., Wenjing, L. (2015) Adsorption behavior comparison of trivalent and hexavalent chromium on biochar derived from municipial sludge, Bioresource Technology, 190, 388-394. Doi: 10.1016/j.biortech.2015.04.115
  37. Turan, P., Doğan, M., Alkan, M. (2007) Uptake of trivalent chromium ions from aqueous solutions using kaolinite, Journal of Hazardous Materials, 148, 56-63. Doi: 10.1016/j.jhazmat.2007.02.007
  38. Wang, D., He,S., Shan, C., Ye, Y., Ma, H., Zhang, X., Zhang, W., Pan, B. (2016) Chromium speciation in tannery effluent after alkaline precipitation: Isolation and characterization, Journal of Hazardous Materials, 316, 169-177. Doi: 10.1016/j.jhazmat.2016.05.021
  39. Wang, D., Ye,Y., Liu, H., Ma, H., Zhang, W. (2018) Effect of alkaline precipitation on Cr species of Cr(III)-bearing complexes typically used in the tannery industry, Chemosphere, 193, 42-49. Doi: 10.1016/j.chemosphere.2017.11.006
  40. Yang, Z.H., Xiong, S., Wang, B., Li, Q., Yang, W.C. (2013) Cr(III) adsorption by sugarcane pulp residue and biochar, Journal of Central South University, 20 (5), 1319–1325. Doi: 10.1007/s11771-013-1618-4
  41. Zou, J., Guo, C., Zhou, X., Sun, Y., Yang, Z. (2018) Sorption capacity and mechanism of Cr+3 on tobermorite derived from fly ash acid residue and carbide slag, Colloids and Surfaces A, 538, 825-833. Doi: 10.1016/j.colsurfa.2017.11.073