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Dergiler / Balıkesir Üniversitesi Fen Bilimleri Enstitüsü Dergisi / 2022 / Cilt: 24 Sayı: 2

Yeni [Piridin-4-boronik asit metil ester ve Nikel(II) ditiooksalat] bileşiğinin sentezi ve kristal yapısı

Synthesis and crystal structure of new [Pyridine-4-boronic acid methyl ester and Nickel(II) dithiooxalate] compound

Hülya Kara Subasat(MUĞLA SITKI KOÇMAN ÜNİVERSİTESİ)0000-0002-2032-8930
Elif Güngör(BALIKESİR ÜNİVERSİTESİ)0000-0002-7158-9604
Sayfa
750–756
Yayın Tarihi
2022-07-08
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Yapay Zeka Hızlı Bakış & Çıkarımlar

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⚡ TL;DR(1 Cümlede Hızlı Çıkarım)

Bu etkileşimler ab düzleminde c ekseni boyunca paketlenir ve 3 boyutlu bir ağ oluşturur.

📌 3 Maddede Bu Makale

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Amaç & Hipotez:Bu çalışmada yeni bir bileşik [HNC5H4B(OH)(OCH3)-4]2[Ni(S2C2O2)2], [Piridin-4-boronik asit metil ester ve Nikel(II) ditiooksalat] sentezlendi ve onun kristal yapısı tek kristal X-ışını difraktometresi metodu ile belirlendi.
📊
Temel Bulgular & Veri:Bileşik P21/n uzay grubunda monoklinik kristal sisteminde kristallendi.
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Sonuç & Katkı:Bu etkileşimler ab düzleminde c ekseni boyunca paketlenir ve 3 boyutlu bir ağ oluşturur.
🔬Tür:Araştırma Makalesi
📍Kapsam:Genişletilmiş Akademik Örneklem
⚙️Değişkenler:Kristal yapı · 4-pridin boronik asit · hidrojen bağ etkileşimleri.

Özet

Bu çalışmada yeni bir bileşik [HNC5H4B(OH)(OCH3)-4]2[Ni(S2C2O2)2], [Piridin-4-boronik asit metil ester ve Nikel(II) ditiooksalat] sentezlendi ve onun kristal yapısı tek kristal X-ışını difraktometresi metodu ile belirlendi. Bileşik P21/n uzay grubunda monoklinik kristal sisteminde kristallendi. NiII iyonu dört koordinasyonlu ve hafifçe bozulmuş kare düzlem geometriye sahiptir. Kristal yapıda, NH⋯O, OH⋯O ve CH⋯O hidrojen bağ etkileşimleri vardır. Bu etkileşimler ab düzleminde c ekseni boyunca paketlenir ve 3 boyutlu bir ağ oluşturur.

Abstract

In this study, a new compound [HNC5H4B(OH)(OCH3)-4]2[Ni(S2C2O2)2], [Pyridine-4-boronic acid methyl ester and Nickel(II) dithiooxalate] was synthesized and its crystal structure was determined by the single-crystal X-ray diffraction method. The compound crystallized in the monoclinic crystal system in the P21/n space group. The NiII ion is four-coordinated and has a slightly distorted square-plane geometry. There is NH⋯O, OH⋯O and CH⋯O hydrogen bond interactions in the crystal structure. These interactions form a 3-dimension network stacked along the c axis in the ab plane.

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Bu Makaleye Atıf Yap

Subasat, H. K., Güngör, E. (2022). Yeni [Piridin-4-boronik asit metil ester ve Nikel(II) ditiooksalat] bileşiğinin sentezi ve kristal yapısı. Balıkesir Üniversitesi Fen Bilimleri Enstitüsü Dergisi, Cilt: 24 Sayı: 2, 750–756. https://doi.org/10.25092/baunfbed.1070259

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