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Dergiler / Erzincan Üniversitesi Fen Bilimleri Enstitüsü Dergisi / 2026 / Cilt: 19 Sayı: 2

Highly Selective Direct Determination of Sunset Yellow Using a Novel Polymeric Membrane Sensor Containing Metal Organic Framework Material

Nurcan Kaya(VAN YUZUNCU YIL UNIVERSITY)0000-0002-8178-1878
Gülşah Saydan Kanberoğlu(VAN YÜZÜNCÜ YIL ÜNİVERSİTESİ)0000-0003-4231-6217
Cihan Topcu(Samsun Üniversitesi)0000-0003-0613-5873
Sayfa
224–241
Yayın Tarihi
2026-08-31
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⚡ TL;DR(1 Cümlede Hızlı Çıkarım)

Ayrıca, sensörün analitik uygulamalarda kullanılabilirliği, standart sunset yellow eklemesi yapılmış farklı su örneklerinde ve bazı farmasötik ilaç formülasyonlarında test edildi.

📌 3 Maddede Bu Makale

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Amaç & Hipotez:Öz Bu çalışmada, sunset yellow’un doğrudan tayini için metal organik framework temelli yeni bir polimerik membran potansiyometrik sensör sunulmuştur.
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Temel Bulgular & Veri:Sensör, metal organik framework (MIL-101), polivinilklorür, nitrofeniloktileter, bis-2-etilhegzilsebekat, dibutilftalat ve potasyum tetrakisklorofenilborat içeren sensör bileşenlerinin farklı oranları kullanılarak üretildi.
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Sonuç & Katkı:Ayrıca, sensörün analitik uygulamalarda kullanılabilirliği, standart sunset yellow eklemesi yapılmış farklı su örneklerinde ve bazı farmasötik ilaç formülasyonlarında test edildi.
🔬Tür:Araştırma Makalesi
📍Kapsam:Genişletilmiş Akademik Örneklem
⚙️Değişkenler:Sunset yellow · ∙metal organik framework · elektrokimya

Özet

Öz Bu çalışmada, sunset yellow’un doğrudan tayini için metal organik framework temelli yeni bir polimerik membran potansiyometrik sensör sunulmuştur. Sensör, metal organik framework (MIL-101), polivinilklorür, nitrofeniloktileter, bis-2-etilhegzilsebekat, dibutilftalat ve potasyum tetrakisklorofenilborat içeren sensör bileşenlerinin farklı oranları kullanılarak üretildi. Sensör bileşenleri en iyi potansiyometrik cevabı elde etmek için optimize edildi ve en arzu edilen cevap özelliklerine % 6,0 iyonofor (MIL-101), % 26,0 polivinilklorür, % 67,0 dibutilftalat ve % 1,0 potasyum tetra-p-kloro-fenilborat içeren sensör bileşimi ile ulaşıldı. Optimize edilen sensör, 35,7±0,5 mV’luk Nernstian eğimi ile 1,0×10-6 ˗ 1,0×10-1 molL-1 (R2=0,9993) konsantrasyon aralığında sunset yellow’a karşı doğrusal bir cevap sergiledi ve tayin limiti 1,7×10-7 molL-1 olarak belirlendi. Sensör cevabı oldukça tekrarlanabilirdi ve sensörün cevap zamanı ortalama 5 saniye olarak ölçüldü. Sensörün potansiyel cevabı, pH=5,40-9,55 arasında çözeltideki hidronyum iyonlarının değişiminden etkilenmedi ve sensörün kullanım ömrü 14 hafta olarak belirlendi. Sensör, senset yellow’un gümüş nitrat çözeltisi ile titrasyonunda indikatör elektrot olarak kullanıldı. Ayrıca, sensörün analitik uygulamalarda kullanılabilirliği, standart sunset yellow eklemesi yapılmış farklı su örneklerinde ve bazı farmasötik ilaç formülasyonlarında test edildi.

Abstract

In this study, a novel polymeric membrane potentiometric sensor based on metal organic framework was presented for the direct determination of sunset yellow. The sensor was fabricated using different ratios of sensor components containing metal organic framework (MIL-101), polyvinylchloride, nitrophenyloctylether, bis-2-ethylhegzylsebecate, dibutylphthalate, and potassiumtetrakischlorophenylborate. The sensor components were optimized to obtain the best potentiometric response and the most desired response characteristics were achieved with the sensor composition including 6.0% ionophore (MIL-101), 26.0% polyvinylchloride, 67.0% dibutylphthalate and 1.0% potassiumtetra-p-chloro-phenylborate. The optimized sensor showed a linear response to sunset yellow over the concentration range of 1.0×10-6 ˗ 1.0×10-1 molL-1 (R2=0.9993) with a Nernstian slope of 35.7±0.5 mV/decade and the detection limit was calculated as 1.7×10-7 molL-1. The sensor response was highly repeatable, and its response time was measured as 5s on average. The sensor’s potential response was not affected by the change of hydronium ions in the solution between pH=5.40-9.55 and its lifetime was evaluated as 14 weeks. The sensor was used as an indicator electrode in the titration of sunset yellow with silver nitrate solution. Additionally, the usefulness for the analytical applications of the sensor were tested using the sunset yellow spiked different water samples and some pharmaceutical drug formulations.

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Bu Makaleye Atıf Yap

Kaya, N., Kanberoğlu, G. S., Topcu, C. (2026). Highly Selective Direct Determination of Sunset Yellow Using a Novel Polymeric Membrane Sensor Containing Metal Organic Framework Material. Erzincan Üniversitesi Fen Bilimleri Enstitüsü Dergisi, Cilt: 19 Sayı: 2, 224–241. https://doi.org/10.18185/erzifbed.1623266

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