KaydedilenlerDerginizi ekleyin

Dergiler / Celal Bayar Üniversitesi Fen Bilimleri Dergisi / 2018 / Cilt: 14 - Sayı: 1

Transfer Hydrogenation of Ketones Using Pyridine-Aminoalcohol Ligands

Serpil Denizaltı
Sayfa
113–117
Yayın Tarihi
2018-03-30
DOI
—
🏛️Bu makalenin bibliyografik verileri ve tam metin bağlantısı DergiPark üzerinden sağlanmıştır.
DergiPark Kaydı ↗
✨

Yapay Zeka Hızlı Bakış & Çıkarımlar

AI Insight
⚡ TL;DR(1 Cümlede Hızlı Çıkarım)

It was found that the ligand I was more active than II.

📌 3 Maddede Bu Makale

🎯
Amaç & Hipotez:Pyridine-aminoalcohol ligands were synthesized and evaluated as catalyst generated in situ from RuCl2(PPh3)3 for transfer hydrogenation of aromatic ketones.
📊
Temel Bulgular & Veri:Pyridine-aminoalcohol ligands were synthesized and evaluated as catalyst generated in situ from RuCl2(PPh3)3 for transfer hydrogenation of aromatic ketones.
💡
Sonuç & Katkı:It was found that the ligand I was more active than II.
🔬Tür:Araştırma Makalesi
📍Kapsam:Genişletilmiş Akademik Örneklem
⚙️Değişkenler:Transfer hydrogenation · Aminoalcohol · Ruthenium

Abstract

Pyridine-aminoalcohol ligands were synthesized and evaluated as catalyst generated in situ from RuCl2(PPh3)3 for transfer hydrogenation of aromatic ketones. It was found that the ligand I was more active than II.

🔖

Bu Makaleye Atıf Yap

Denizaltı, S. (2018). Transfer Hydrogenation of Ketones Using Pyridine-Aminoalcohol Ligands. Celal Bayar Üniversitesi Fen Bilimleri Dergisi, Cilt: 14 - Sayı: 1, 113–117. https://ajindex.com/articles/111205

📄 Tam Metin PDF Okuyucu

📄

PDF görüntüleyici hazırlanıyor...

Kaynakça (13)

  1. Hashiguchi, S, Fujii, A, Takehara, J, Ikariya, T, Noyori, R, Asymmetric Transfer Hydrogenation of Aromatic Ketones Catalyzed by Chiral Ruthenium(II) Complexes, Journal of American Chemical Society, 1995, 117, 7562-7563
  2. Ikariya, T, Blacker, A.J, Asymmetric Transfer Hydrogenation of Ketones with Bifunctional Transition Metal-Based Molecular Catalysts, Accounts of Chemical Research., 2007, 40, 1300-1308
  3. Denizaltı, S, Mercan, D, Şen, B, Gökçe, A.G, Çetinkaya, B, Asymmetric Transfer Hydrogenation Reaction in Water: Comparison of Chiral Proline Amide/Amine Ruthenium(II) Complexes, Journal of Organometallic Chemistry, 2015, 779, 62-66
  4. Denizaltı, S, Şen, B, Gökçe, A.G, Çetinkaya, B, Ruthenium(II) Complexes Derived from 2-phenylthiazoline-4-carboxylic acid: Structure and Catalytic Activity for Transfer Hydrogenation Reaction, Applied Organometallic Chemistry, 2016, 30, 373-377
  5. Foubelo, F, Najera, C, Yus, M, Catalytic Asymmetric Transfer Hydrogenation of Ketones: Recent Advances, Tetrahedron: Asymmetry, 2015, 26, 769-790
  6. Wang, D, Astruc, D, The Golden Age of Transfer Hydrogenation, Chemical. Reviews., 2015, 115, 6621-6686
  7. Wu, Y, Yun, H, Wu, Y, Ding, K, Zhou, Y, Synthesis of N-α-pyridylmethyl Amino Alcohols and Application in Catalytic Asymmetric Addition of Diethylzinc to Aromatic Aldehydes, Tetrahedron: Asymmetry, 2000, 11, 3543-3552
  8. Yun, H, Wu, Y, Wu, Y, Ding, K, Zhou, Y, Chiral Ligands for Asymmetric Synthesis: Enantioselective Addition of Diethylzinc to Aromatic Aldehydes Catalyzed by Chiral N-α-pyridylmethyl Amino Alcohols, Tetrahedron Letters, 2000, 41, 10263-10266
  9. Grach, G, Dinut, A, Marque, S, Marrot, J, Gil, R, Prim, D, Enantioselective Friedel-Crafts Alkylation of Indole Derivatives Catalyzed by New Yb(OTf)3-pyridylalkylamine Complexes as Chiral Lewis Acids, Organic and Biomolecular Chemistry, 2011, 9, 497-503
  10. Xu, F, Lei, C, Yan, L, Tu, J, Li, G, Copper-Chiral Camphor β-Amino Alcohol Complex Catalyzed Asymmetric Henry Reaction, Chirality, 2015, 27, 761-765
  11. Deshpande, S.H, Kelkar, A.A, Gonnade, R.G, Shingote, S.K, Chaudhari, R.V, Catalytic Asymmetric Transfer Hydrogenation of Ketones Using [Ru(p-cymene)Cl2]2 with Chiral Amino Alcohol Ligands, Catalysis Letters, 2010, 138, 231-238
  12. Pastó, M, Riera, A, Pericàs, M.A, Fine-Tuning of Modular Amino Alcohol Ligands for the Enantioselective Transfer Hydrogenation of Ketones, European Journal of Organic Chemistry, 2002, 2337-2341
  13. Han, M.-L, Hub, X.-P, Huang, J.-D