KaydedilenlerDerginizi ekleyin

Dergiler / Gazi Üniversitesi Mühendislik Mimarlık Fakültesi Dergisi / 2025 / Cilt: 40 Sayı: 4

Kalkon azo boyasının boya duyarlı katıhal perovskite güneş hücrelerinin verim ve kararlılığı üzerine etkileri

Effects of chalcone azo dye on the efficiency and stability of dye-sensitized solid-state perovskite solar cells

Murat Ebiç(KARAMANOĞLU MEHMETBEY ÜNİVERSİTESİ, FEN BİLİMLERİ ENSTİTÜSÜ)0000-0002-1280-4052
Muhittin Ünal(NECMETTİN ERBAKAN ÜNİVERSİTESİ, MÜHENDİSLİK VE MİMARLIK FAKÜLTESİ)0000-0003-2431-6870
Seçkin Akın(NECMETTİN ERBAKAN ÜNİVERSİTESİ, MÜHENDİSLİK VE MİMARLIK FAKÜLTESİ)0000-0001-9852-7246
Sayfa
2807–2816
Yayın Tarihi
2025-12-31
🏛️Bu makalenin bibliyografik verileri ve tam metin bağlantısı DergiPark üzerinden sağlanmıştır.
DergiPark Kaydı ↗
✨

Yapay Zeka Hızlı Bakış & Çıkarımlar

AI Insight
⚡ TL;DR(1 Cümlede Hızlı Çıkarım)

Sonuç olarak %0,5 kalkon azo boya katkısı ile kabul edilebilir faz kararlılığı ve %18,11'lık bir güç dönüşüm verimliliği (PCE) elde edilirken, saf PSC ile yalnızca %17,01 oranında PCE elde edildi.

📌 3 Maddede Bu Makale

🎯
Amaç & Hipotez:Son yıllarda perovskit güneş hücrelerinin (PSC'ler) performansındaki kayda değer ve hızlı ilerlemeler fotovoltaik topluluğunun ilgisini üzerine toplamıştır.
📊
Temel Bulgular & Veri:Kusur pasivasyonu, PSC'lerinin fotovoltaik özelliklerini büyük ölçüde etkileyen, çözeltiyle işlenmiş soğurucu perovskit tabakaların film özelliklerini yönetmek için çok önemli bir stratejidir.
💡
Sonuç & Katkı:Sonuç olarak %0,5 kalkon azo boya katkısı ile kabul edilebilir faz kararlılığı ve %18,11'lık bir güç dönüşüm verimliliği (PCE) elde edilirken, saf PSC ile yalnızca %17,01 oranında PCE elde edildi.
🔬Tür:Uygulamalı Anket & Alan Araştırması
📍Kapsam:Genişletilmiş Akademik Örneklem
⚙️Değişkenler:Perovskit güneş hücreleri · katkılama · kusur pasivasyonu

Özet

Son yıllarda perovskit güneş hücrelerinin (PSC'ler) performansındaki kayda değer ve hızlı ilerlemeler fotovoltaik topluluğunun ilgisini üzerine toplamıştır. Kusur pasivasyonu, PSC'lerinin fotovoltaik özelliklerini büyük ölçüde etkileyen, çözeltiyle işlenmiş soğurucu perovskit tabakaların film özelliklerini yönetmek için çok önemli bir stratejidir. Bununla birlikte, PSC’nin kararlılığını ve fotoelektrik performansını olumsuz etkileyen soğurucu perovskit filmlerin polikristal özelliklerinden dolayı düzgün olmayan morfoloji ile yüzey ve tane sınırlarındaki yüksek kusur yoğunluğundan muzdariptir. Bu çalışmada, kalkon azo boya malzemesini, soğurucu perovskit tabakası içerisine farklı konsantrasyonlarda (% x: 0, 0,1, 1,3, 0,5 ve 1) katkılayarak kusur durumları ve hücre performansı üzerindeki etkisini araştırdık. Katkılama işlemi, perovskit tabakanın yüzey ve tane sınırlarındaki kusurları pasif hale getirebilir ve taşıyıcı ömrünü önemli ölçüde uzatabilir. Ayrıca kalkon azo boya perovskit filmlerin büyüme kinetiğinde umut verici bir rol oynamaktadır. Sonuç olarak %0,5 kalkon azo boya katkısı ile kabul edilebilir faz kararlılığı ve %18,11'lık bir güç dönüşüm verimliliği (PCE) elde edilirken, saf PSC ile yalnızca %17,01 oranında PCE elde edildi. Bu çalışma, PSC'lerin ticari ölçeklenebilirliğine önemli engeller teşkil eden kararsızlık ve tane sınırındaki kusurların pasifleştirilmesi sorunlarını ele almak için umut verici bir çözüm sunmaktadır.

Abstract

In recent years, the significant and rapid advancements in the performance of perovskite solar cells (PSCs) have garnered substantial attention from the photovoltaic sector. Defect passivation is a crucial strategy for managing the optoelectronic properties of solution-based absorber perovskite layers, which greatly influence the photovoltaic characteristics of PSCs. However, PSCs suffer from high defect densities at the surface and grain boundaries of the absorber perovskite films, which stem from their polycrystalline structure and adversely affect stability and photoelectric performance. In this study, the effects of incorporating calcon azo dye material into the absorber perovskite layer at various concentrations (0.1, 0.3, 0.5, and 1.0%) on defect states and cell performance were investigated. The incorporation process significantly passivated the defects at the surface and grain boundaries of the perovskite layer, thereby extending the carrier lifetime. Additionally, calcon azo dye plays a promising role in the growth kinetics of perovskite films. Consequently, an acceptable phase stability and a power conversion efficiency (PCE) of 18.3% were achieved with a 0.5% calcon azo dye incorporation, while the PCE of the pristine PSC was only 17.3%. This study presents a promising solution to address the issues of instability and grain boundary defects passivation, which are significant barriers to the commercial scalability of PSCs

🔖

Bu Makaleye Atıf Yap

Ebiç, M., Ünal, M., Akın, S. (2025). Kalkon azo boyasının boya duyarlı katıhal perovskite güneş hücrelerinin verim ve kararlılığı üzerine etkileri. Gazi Üniversitesi Mühendislik Mimarlık Fakültesi Dergisi, Cilt: 40 Sayı: 4, 2807–2816. https://doi.org/10.17341/gazimmfd.1540685

📄 Tam Metin PDF Okuyucu

📄

PDF görüntüleyici hazırlanıyor...

Kaynakça (46)

  1. Ozkaya V., Sadegh F., Unal M., Alkan B., Ebic M., Ozturk T.,. & Akin, S., Eco-friendly boost for perovskite photovoltaics: harnessing cellulose-modified SnO2 as a high-performance electron transporting material. ACS Applied Materials & Interfaces, 15 (49), 57338-57349, 2023.
  2. Ünal, M., Akın, S., Ebic, M., & Baynal, B., Optimization of Li-TFSI Doped TiO2 Electron Transfer Layer in Perovskite Solar Cells, Afyon Kocatepe University Journal of Science & Engineering, 24 (4), 921-930, 2024.
  3. Çevik Bektaş, S., Altaş, İ., Multipurpose day-ahead optimum energy planning for a grid-connected distribution network consisting of renewable energy sources and storage units. Journal of the Faculty of Engineering & Architecture of Gazi University, 40 (2), 1335-1346, 2025.
  4. Gündüz, A. H., Cimsit, C., SF analysis of solar-powered absorption cooling systems. Journal of the Faculty of Engineering & Architecture of Gazi University, 39 (4), 2103-2112, 2024.
  5. Ebic M., Low-Temperature Fabrication and Optimization of EMIMBF4 Ionic Liquid Doped SnO2 Electron Transfer Layer for Perovskite Solar Cells. Journal of the Institute of Science and Technology, 13 (3), 2130-2142, 2023.
  6. Wagner, J., Chavan, R. D., Kruszyńska, J., Ans, M., Mahapatra, A., Mrkyvkova, N.,. & Prochowicz, D., T-shaped-N-doped polycyclic aromatic hydrocarbons: A new concept of dopant-free organic hole-transporting materials for perovskite solar cells. ACS Applied Materials & Interfaces, 16 (47), 64940-64950, 2024.
  7. Akin S., Hysteresis-free planar perovskite solar cells with a breakthrough efficiency of 22% and superior operational stability over 2000 h. ACS applied materials & interfaces, 11 (43), 39998-40005, 2019.
  8. Ebic, M., Akar, S., Akman, E., Ozel, F., & Akin, S., The production and optimization of SnO2 electron transporting layer by Slot-Die technique. Int. J. Innov. Eng. Appl, 6, 170-182, 2022.
  9. Xiang W., Wang Z, Kubicki DJ, Tress W, Luo J, Prochowicz D., Hagfeldt A., Europium-doped CsPbI2Br for stable and highly efficient inorganic perovskite solar cells. Joule, 3 (1), 205-214, 2019.
  10. Kruszynska J., Sadegh F., Pate, MJ., Akman E., Yadav P., Tavakoli MM., Prochowicz D., Effect of 1, 3-disubstituted urea derivatives as additives on the efficiency and stability of perovskite solar cells. ACS Applied Energy Materials, 5 (11), 13617-13626, 2022.
  11. Tavakoli MM., Fazel Z., Tavakoli R., Akin S., Satapathi S., Prochowicz D., Yadav P., Efficient and Less‐Toxic Indium‐Doped MAPbI3 Perovskite Solar Cells Prepared by Metal Alloying Technique. Solar RRL, 6 (9), 2200106, 2022.
  12. Sadegh F., Akin S., Moghadam M., Mirkhani V., Ruiz‒Preciado MA., Wang Z., Tress W., Highly efficient, stable and hysteresis‒less planar perovskite solar cell based on chemical bath treated Zn2SnO4 electron transport layer. Nano Energy, 75, 105038, 2020.
  13. Ebic, M., TEOS modification for improved performance in perovskite solar cells: addressing the interface defects and charge transfer issues of SnO2 ETL. Nanotechnology, 36 (4), 045202, 2024.
  14. National Renewable Energy Laboratory. Best Research-Cell Efficiency Chart Photovoltaic Research | NREL. https://www.nrel.gov/pv/cell-efficiency.html 2024. (Erişim tarihi 22.05.2024).
  15. Chen H., Teale S., Chen B., Hou Y., Grater L., Zhu T., Sargent EH., Quantum-size-tuned heterostructures enable efficient and stable inverted perovskite solar cells. Nature Photonics, 16 (5), 352-358, 2022.
  16. Ebic M., Sadegh F., Ans M., Prochowicz D., Yadav P., Satapathi S., Akin S., Pseudohalide‐Based Ionic Liquids: Advancing Crystallization Kinetics and Optoelectronic Properties in All‐Inorganic Perovskite Solar Cells. Small, 2404190, 2024.
  17. Yoo J.J., Seo G., Chua MR., Park TG., Lu Y., Rotermund F., Seo J., Efficient perovskite solar cells via improved carrier management. Nature, 590 (7847), 587-593, 2021.
  18. Akin S., Boosting the efficiency and stability of perovskite solar cells through facile molecular engineering approaches. Solar Energy, 199, 136-142, 2020.
  19. Wu Y., Zhu H., Yu BB., Akin S., Liu Y., Shen Z., Cai H., Interface modification to achieve high-efficiency and stable perovskite solar cells. Chemical Engineering Journal, 433, 134613, 2022.
  20. Zhao P., Kim BJ., Jung HS., Passivation in perovskite solar cells: A review. Materials today energy, 7, 267-286, 2018.
  21. Lan ZR., Wang YD., Shao JY., Ma DX., Liu Z., Li D., Zhong YW., Surface Passivation with Diaminopropane Dihydroiodide for p‐i‐n Perovskite Solar Cells with Over 25% Efficiency. Advanced Functional Materials, 34 (12), 2312426, 2024.
  22. Seo J., Matsui T., Luo J., Correa-Baena JP., Giordano F., Saliba M., Abate A., Ionic liquid control crystal growth to enhance planar perovskite solar cells efficiency. Advanced Energy Materials, 6 (20), 1600767, 2016.
  23. Lee JW., Kim HS., Park NG., Lewis acid–base adduct approach for high efficiency perovskite solar cells. Accounts of chemical research, 49 (2), 311-319, 2016.
  24. Zhang Y., Gao P., Oveisi E., Lee Y., Jeangros Q., Grancini G., Nazeeruddin MK., PbI2–HMPA complex pretreatment for highly reproducible and efficient CH3NH3PbI3 perovskite solar cells. Journal of the American Chemical Society, 138 (43), 14380-14387, 2016.
  25. Guo Y., Sato W., Shoyama K., Nakamura E., Sulfamic acid-catalyzed lead perovskite formation for solar cell fabrication on glass or plastic substrates. Journal of the American Chemical Society, 138 (16), 5410-5416, 2016.
  26. Fei C., Guo L., Li B., Zhang, R., Fu H., Tian J., Cao G., Controlled rowth of textured perovskite films towards high-performance solar cells. Nano Energy, 27, 17-26, 2016.
  27. De Marco N., Zhou H., Chen Q., Sun P., Liu Z., Meng L., Yang Y., Guanidinium: a route to enhanced carrier lifetime and open-circuit voltage in hybrid perovskite solar cells. Nanoletters, 16 (2), 1009-1016, 2016.
  28. Wang JTW., Wang Z., Pathak S., Zhang W., deQuilettes DW., Wisnivesky-Rocca-Rivarola F., Snaith HJ., Efficient perovskite solar cells by metal ion doping. Energy & Environmental Science, 9 (9), 2892-2901, 2016;
  29. Zhao W., Yang D., Liu SF., Organic–inorganic hybrid perovskite with controlled dopant modification and application in photovoltaic device. Small, 13 (25), 1604153, 2017.
  30. Bag S., Durstock MF., Large perovskite grain growth in low-temperature solution-processed planar pin solar cells by sodium addition. ACS applied materials & interfaces, 8 (8), 5053-5057., 2016.
  31. Wu CG., Chiang CH., Tseng ZL., Nazeeruddin MK., Hagfeldt A., Grätzel M., High efficiency stable inverted perovskite solar cells without current hysteresis. Energy & Environmental Science, 8 (9), 2725-2733, 2015.
  32. Câmara Cardozo J., da Silva DR., Martínez-Huitle CA., Quiroz MA., Dos Santos EV., Photovoltaic electrochemically driven degradation of calcon dye with simultaneous green hydrogen production. Materials, 15 (21), 7445, 2022.
  33. Fat'hi MR., Nasab SJH., Synthesis of calcon-imprinted magnetic chitosan nanoparticles as a novel adsorbent and its application in selective removal of calcon dye from aqueous solutions. International journal of biological macromolecules, 114, 1151-1160, 2018.
  34. Basumatary P., Agarwal P., Photocurrent transient measurements in MAPbI 3 thin films. Journal of Materials Science: Materials in Electronics, 31, 10047-10054, 2020.
  35. Fan P., Gu D., Liang GX., Luo JT., Chen JL., Zheng ZH., Zhang DP., High-performance perovskite CH3NH3PbI3 thin films for solar cells prepared by single-source physical vapour deposition. Scientific reports, 6 (1), 29910, 2016.
  36. Wen Y., Zhu G., Shao Y., Improving the power conversion efficiency of perovskite solar cells by adding carbon quantum dots. Journal of Materials Science, 55 (7), 2937-2946, 2020.
  37. Zhao N., Wang J., Solar full spectrum management in low and medium temperature light-driven chemical hydrogen synthesis-A review. Renewable and Sustainable Energy Reviews, 196, 114368, 2024.
  38. Arora N., Dar MI., Akin S., Uchida R., Baumeler T., Liu Y., Grätzel M., Low‐cost and highly efficient carbon‐based perovskite solar cells exhibiting excellent long‐term operational and UV stability. Small, 15 (49), 1904746, 2019.
  39. Akin S., Hysteresis-free planar perovskite solar cells with a breakthrough efficiency of 22% and superior operational stability over 2000 h. ACS applied materials & interfaces, 11 (43), 39998-40005, 2019.
  40. Zhu Z., Bai Y., Lee HKH., Mu C., Zhang T., Zhang L., Yang S., Polyfluorene derivatives are high‐performance organic hole‐transporting materials for inorganic-organic hybrid perovskite solar cells. Advanced Functional Materials, 24 (46), 7357-7365, 2014.
  41. Zhao W., Yao Z., Yu F., Yang D., Liu S., Alkali metal doping for improved CH3NH3PbI3 perovskite solar cells. Advanced science, 5 (2), 1700131, 2018.
  42. Bu T., Liu X., Zhou Y., Yi J., Huang X., Luo L., Zhong J., A novel quadruple-cation absorber for universal hysteresis elimination for high efficiency and stable perovskite solar cells. Energy & Environmental Science, 10 (12), 2509-2515, 2017.
  43. Shen Z., Han Q., Luo X., Shen Y., Wang T., Zhang C., Han L., Crystal-array-assisted growth of a perovskite absorption layer for efficient and stable solar cells. Energy & Environmental Science, 15 (3), 1078-1085, 2022.
  44. Kim BJ., Kim DH., Lee YY., Shin HW., Han GS., HonG JS., Jung HS., Highly efficient and bending durable perovskite solar cells: toward a wearable power source. Energy & Environmental Science, 8 (3), 916-921, 2015.
  45. Ozkaya V., Sadegh F., Unal M., Alkan B., Ebic M., Ozturk T.,. & Akin, S., Eco-friendly boost for perovskite photovoltaics: harnessing cellulose-modified SnO2 as a high-performance electron transporting material. ACS Applied Materials & Interfaces, 15 (49), 57338-57349, 2023.
  46. Wagner, J., Chavan, R. D., Kruszyńska, J., Ans, M., Mahapatra, A., Mrkyvkova, N.,. & Prochowicz, D., T-shaped-N-doped polycyclic aromatic hydrocarbons: A new concept of dopant-free organic hole-transporting materials for perovskite solar cells. ACS Applied Materials & Interfaces, 16 (47), 64940-64950, 2024.