Dergiler / Journal of the Turkish Chemical Society Section A: Chemistry / 2023 / Cilt: 10 Sayı: 4

Improvement of corrosion resistance for brass in 3.5% NaCl media by using 4- fluorophenyl-2, 5-dithiohydrazodicarbonamide

Sayfa
869–876
Yayın Tarihi
2023-11-11
DOI
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The results confirmed that the compound FTSC can be used as a corrosion inhibitor for brass in 3.5% NaCl.

📌 3 Maddede Bu Makale

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Amaç & Hipotez:Corrosion poses a significant challenge for numerous industries.
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Temel Bulgular & Veri:In the present study, the compound 4- fluorophenyl-2,5- dithiohydrazodicarbonamide (FTSC) was used as a corrosion inhibitor for brass in 3.5% NaCl solution.
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Sonuç & Katkı:The results confirmed that the compound FTSC can be used as a corrosion inhibitor for brass in 3.5% NaCl.
🔬Tür:Araştırma Makalesi
📍Kapsam:Genişletilmiş Akademik Örneklem
⚙️Değişkenler:corrosion inhibition · electrochemistry · brass

Abstract

Corrosion poses a significant challenge for numerous industries. The use of corrosion inhibitors is essential within these industries. The efficacy of environmentally friendly corrosion inhibitors should remain high even when used at low concentrations. In the present study, the compound 4- fluorophenyl-2,5- dithiohydrazodicarbonamide (FTSC) was used as a corrosion inhibitor for brass in 3.5% NaCl solution. The inhibitor efficiency was determined by using a series of electrochemical techniques such as open circuit potential (OCP), potential dynamic polarisation (PDP), linear polarisation resistance (LPR), and electrochemical impedance spectroscopy (EIS). All experimental tests have been done in stagnant conditions. The findings of the experiments revealed that the compound FTSC looked to be of the cathodic type. Furthermore, the maximum inhibitor efficiency was reached at 98.28% at 1 × 10-3 and at an immersion time of 1 h. The current density was reduced from 16.5 to 0.284 A.cm-2. The adsorption of compound on the brass surface in 3.5% NaCl solution obeyed the Langmuir isotherm with a low negative value of the standard Gibbs free energy of adsorption (-33.8 kJ/mol ΔGads (chemisorption and physisorption). The results confirmed that the compound FTSC can be used as a corrosion inhibitor for brass in 3.5% NaCl.

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Bu Makaleye Atıf Yap

ALFALAH, M. G. K., ELID, A., ALİ, A. A. A., KAMBERLİ, E., NAZLI, B., KOYUN, S., TOSUN, A., KADİRLİOĞLU, M., ELKASSUM, F., SALEH, S. Q., OBIED, A., KANDEMİRLİ, F. (2023). Improvement of corrosion resistance for brass in 3.5% NaCl media by using 4- fluorophenyl-2, 5-dithiohydrazodicarbonamide. Journal of the Turkish Chemical Society Section A: Chemistry, Cilt: 10 Sayı: 4, 869–876. https://ajindex.com/articles/1018401

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Kaynakça (9)

  1. Fan H., Li S., Zhao Z., Wang H., Shi Z., Zhang L., Inhibition of brass corrosion in sodium chloride solutions by self-assembled silane films. Corrosion Science [Internet]. 2011 Dec [cited 2022 Sep 4];53:4273–4281. Available from:
  2. Ravichandran R., Nanjundan S., Rajendran N., Effect of benzotriazole derivatives on the corrosion and dezincification of brass in neutral chloride solution. Journal of Applied Electrochemistry [Internet]. 2004 Mar 3 [cited 2022 Sep 4];34:1171–1176. Available from:
  3. Radovanović M.B., Tasić Ž.Z., Mihajlović M.B.P., Simonović A.T., Antonijević M.M., Electrochemical and DFT studies of brass corrosion inhibition in 3% NaCl in the presence of environmentally friendly compounds [Internet]. Scientific Reports [Internet]. 2019 Nov 6 [cited 2022 Sep 4];9:1–16. Available from:
  4. Ebrahimzadeh M., Gholami M., Momeni M., Kosari A., Moayed M.H., Davoodi A., Theoretical and experimental investigations on corrosion control of 65Cu-35Zn brass in nitric acid by two thiophenol derivatives. Applied Surface Science [Internet]. 2015 Mar 30 [cited 2022 Sep 4];332:384–392. Available from:
  5. Rbaa M., Ouakki M., Galai M., Berisha A., Lakhrissi B., Jama C., Warad I., Zarrouk A., Simple preparation and characterization of novel 8-Hydroxyquinoline derivatives as effective acid corrosion inhibitor for mild steel: Experimental and theoretical studies. Colloids and Surfaces A: Physicochemical and Engineering Aspects [Internet]. 2020 Oct 5 [cited 2022 Sep 4];602:125094. Available from:
  6. Şahin E.A., Solmaz R., Gecibesler İ.H., Kardaş G., Adsorption ability, stability and corrosion inhibition mechanism of phoenix dactylifera extrat on mild steel. Materials Research Express [Internet]. 2020 Jan 27 [cited 2022 Sep 4];7:016585. Available from:
  7. Xu Y., Zhou Q., Liu L., Zhang Q., Song S., Huang Y., Exploring the corrosion performances of carbon steel in flowing natural sea water and synthetic sea waters. Corrosion Engineering, Science and Technology [Internet]. 2020 May 3 [cited 2022 Sep 4];55:579–588. Available from:
  8. Olasunkanmi L.O., Ebenso E.E., Experimental and computational studies on propanone derivatives of quinoxalin-6-yl-4,5-dihydropyrazole as inhibitors of mild steel corrosion in hydrochloric acid. Journal of Colloid and Interface Science [Internet]. 2020 Mar 1 [cited 2022 Sep 4];561:104–116. Available from:
  9. Guo L., Obot I.B., Zheng X., Shen X., Qiang Y., Kaya S., Kaya C., Theoretical insight into an empirical rule about orga