Journals / Communications Faculty of Sciences University of Ankara Series B Chemistry and Chemical Engineering / 1974 / Cilt: 21 #86254
Detennination of k^/kjin the Polymerization of Methyl Acrylate and the Eguation of Rate of Termination
- Journal
- Communications Faculty of Sciences University of Ankara Series B Chemistry and Chemical Engineering
- Pages
- 1–1
- DOI
- —
Abstract
The values of k2p/kt for methyl acrylate polymerization initiated by benzöyl peroxide and azo-bis izobutyronitrile have been determined. By using Matheson’s values for kpand kt, k2p /kt has been calculated. From these results, it is seen that the eguation of rate of termination must be given without the factor 2 which is used by some poly- mer chemists.