Journals / Turkish Journal of Physics / 1998 / Cilt: 22 - Sayı: 1
Fine Structure Analysis of 4702 oA Band of the Molecule
- Journal
- Turkish Journal of Physics
- Pages
- 21–28
- DOI
- —
Abstract
The emission spectrum of the cobalt monochloride molecule has been excited in a high frequency discharge tube source and the (0,0) band of H-system at 4702 \AA was photo-graphed at an inverse dispersion of 0.973 \AA/mm in the 5th order of a two meter plane grating spectrograph (Carl-Zeiss). The fine structure analysis of the band has been carried out and the molecular constants are reported for the first time. Rotational isotopic shift due to 37Cl support the analysis. The electronic transition involved is of the type 0------ 0- of case (c) which is equivalent of 3\sum+-----3\sum+ or 5\sum+-----5\sum+.
Özet
The emission spectrum of the cobalt monochloride molecule has been excited in a high frequency discharge tube source and the (0,0) band of H-system at 4702 \AA was photo-graphed at an inverse dispersion of 0.973 \AA/mm in the 5th order of a two meter plane grating spectrograph (Carl-Zeiss). The fine structure analysis of the band has been carried out and the molecular constants are reported for the first time. Rotational isotopic shift due to 37Cl support the analysis. The electronic transition involved is of the type 0------ 0- of case (c) which is equivalent of 3\sum+-----3\sum+ or 5\sum+-----5\sum+.