Journals / Turkish Journal of Physics / 2008 / Cilt: 32 - Sayı: 3

Heat Capacity Anomalies of TlInS2 and TlGaS2 Single Crystals Detected by Differential Scanning Calorimetry (DSC)

Pages
145–150
DOI
—

Abstract

Specific heat capacity Cp anomalies of layered single crystals TlInS2 and TlGaS2 have been investigated using differential scanning calorimetry (DSC) as a new technique for such crystals. Special features of Cp have been revealed in the temperature range of the possible phase transitions of both crystals. A sequence of maximum values of Cp is obtained at 163, 174, 184, 193, 201, 212, 224, 254, and 259 K for TlInS2. In the case of TlGaS2, the temperatures of the obtained maximum Cp values at 177 and 241 K agree well with the intervals of the phase transition temperatures reported in the published data of TlGaS2. As a result, it is remarked that DSC technique might have a particular potential for the thermal measurements of layered semiconductors.

Özet

Specific heat capacity Cp anomalies of layered single crystals TlInS2 and TlGaS2 have been investigated using differential scanning calorimetry (DSC) as a new technique for such crystals. Special features of Cp have been revealed in the temperature range of the possible phase transitions of both crystals. A sequence of maximum values of Cp is obtained at 163, 174, 184, 193, 201, 212, 224, 254, and 259 K for TlInS2. In the case of TlGaS2, the temperatures of the obtained maximum Cp values at 177 and 241 K agree well with the intervals of the phase transition temperatures reported in the published data of TlGaS2. As a result, it is remarked that DSC technique might have a particular potential for the thermal measurements of layered semiconductors.

Keywords: Ternary compounds, layered crystal, heat capacity, DSC, phase transition