Journals / Iğdır Üniversitesi Fen Bilimleri Enstitüsü Dergisi / 2022 / Cilt: 12 - Sayı: 3
Synthesis, Characterization and Thermal Studies of New Carboxamide Ligand and Co(II), Ni(II), Cu(II) and Fe(II) Metal Complexes Containing Sulfonamide Group
- Pages
- 1723–1733
- DOI
- —
Abstract
The new N-carboxamide ligand 2-benzoyl-N-(4-(aminosulfonyl)phenyl)-3-oxo-3-phenylpropanamide (HL) was synthesized from the reaction of dibenzoylacetic acid-Ncarboxyethylamide and sulfonylamide. Then, metal complexes were synthesized from the reaction of ligand with Cu(OAc)2·H2O, Co(OAc)2·4H2O, Ni(OAc)2·4H2O and Fe(OAc)2 metal salts in a 1:2 metal:ligand cytochiometric ratio, respectively. The synthesized carboxamide ligand and its metal complexes were characterized by various techniques such as UV-Vis, FT-IR, NMR, elemental analysis, TGA-DTA.
Özet
Yeni N-karboksamit ligandı 2-benzoil-N-(4-(aminosülfonil)fenil)-3-okso-3-fenilpropanamit (HL), dibenzoilasetik asit-N-karboksietilamit ve sülfonilamitin reaksiyonundan sentezlendi. Daha sonra ligandın sırasıyla Cu(OAc)2·H2O, Co(OAc)2·4H2O, Ni(OAc)2·4H2O ve Fe(OAc)2 metal tuzları ile 1:2 metal:ligand sitokiyometrik oranında reaksiyonundan metal kompleksleri sentezlendi. Sentezlenen karboksamid ligandı ve metal kompleksleri, UV-Vis, FT-IR, NMR, elementel analiz, TGA-DTA gibi çeşitli tekniklerle karakterize edildi.