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Journals / Turkish Journal of Chemistry / 1996 / Cilt: 20 - Sayı: 3

The facile synthesis of cyclopentanoid antibiotic kjellmanianone

Cihangir TANYELİ, Hülya AKGÜL, Volkan GÜLBEYAZ, Ayhan S. DEMİR

Pages
244–248
DOI
—

Abstract

The synthesis of cyclopentanoid antibiotic Kjellmanianone is described in this study. The C-acylation of lithium enolates of 3-Methoxycyclopentenone by N-carbomethoxyimidazole or methylcyanoformate b-ketoester, which when oxidized with Mn(III) acetate produces kjellmanianone in good yield.